• Title/Summary/Keyword: Diffusion Term

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Durability Characteristics of Concrete Containing Lightly Burnt MgO Powder (저온 소성한 MgO 분말을 혼입한 콘크리트의 내구 특성)

  • Choi, Seul-Woo;Kim, Joo-Hyung;Lee, Kwang-Myong;Kwon, Yong-Gil;Jang, Bong-Seok
    • Journal of the Korea Concrete Institute
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    • v.23 no.5
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    • pp.609-615
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    • 2011
  • MgO concrete containing lightly burnt MgO powder at $850{\sim}1,000^{\circ}C$ may have a long-term expansibility characteristic. Such expansibility of MgO concrete can compensate the shrinkage at later ages since the hydration of the MgO is very slow. However, the addition of MgO delays the initial hydration of cement and increases the setting time of cement. Also, the porosity and pore-size distribution of the MgO concrete are different from OPC concrete. Therefore, in order to use MgO in practice, both mechanical and durability properties of MgO concrete should be carefully examined. In this study, durability tests on carbonation, freezing-thawing, and diffusion of chloride were carried out after 56 days of underwater curing at $20^{\circ}C$ to compare durability characteristics of 5% MgO-mixed concrete with those of OPC concrete. The results showed that MgO concrete shows a greater durability than the concrete with no MgO, because the micro structure in the MgO concrete is much denser due to its expansibility characteristic.

Effect of Hydrogen Purge Mode on the Polymer Electrolyte Membrane Fuel Cell (PEMFC) Performance under Dead-ended Anode Operation (양극 닫힌계 작동에서 수소 배출 방법에 의한 고분자전해질 연료전지 성능 영향)

  • Kim, Junseob;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.30 no.6
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    • pp.687-693
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    • 2019
  • As the hydrogen fuel cell market is expanded starting from hydrogen electric vehicle and power generation field, the demand for fuel cells and hydrogen increases recently. Therefore, research works on fuel cell durability and fuel efficiency are required in order to activate the fuel cell market and commercialization. A dead-ended anode system was used in this study to optimize the fuel cell performance and fuel efficiency. The effect of purge condition according to the applied current and hydrogen supply pressure on the fuel cell performance were evaluated. In addition, the influence of water back diffusion on the different electrolyte membrane thickness was analyzed. The accumulated water was purged with a solenoid valve in the case of 3% voltage decrease in the dead-ended anode system. The experiment was performed with the hydrogen supply pressure of 0.1~0.5 bar and purge duration of 0.1~1 second. A maximum fuel efficiency of 98.9% was achieved under the purge duration of 0.1 s and hydrogen supply pressure of 0.1 bar with a NR 211 (25.4 um) membrane. However, the fuel cell performance decreased in a long-term operation due to some frequent flooding. The fuel efficiency and purge interval increased due to decreased back diffusion rates of the water and nitrogen with a NR 212 (50.8 um) membrane.

Real-Time Hierarchical Techniques for Rendering of Translucent Materials and Screen-Space Interpolation (반투명 재질의 렌더링과 화면 보간을 위한 실시간 계층화 알고리즘)

  • Ki, Hyun-Woo;Oh, Kyoung-Su
    • Journal of Korea Game Society
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    • v.7 no.1
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    • pp.31-42
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    • 2007
  • In the natural world, most materials such as skin, marble and cloth are translucent. Their appearance is smooth and soft compared with metals or mirrors. In this paper, we propose a new GPU based hierarchical rendering technique for translucent materials, based on the dipole diffusion approximation, at interactive rates. Information of incident light, position, normal, and irradiance, on the surfaces are stored into 2D textures by rendering from a primary light view. Huge numbers of pixel photons are clustered into quad-tree image pyramids. Each pixel, we select clusters (sets of photons), and then we approximate multiple subsurface scattering term with the clusters. We also introduce a novel hierarchical screen-space interpolation technique by exploiting spatial coherence with early-z culling on the GPU. We also build image pyramids of the screen using mipmap and pixel shader. Each pixel of the pyramids is stores position, normal and spatial similarity of children pixels. If a pixel's the similarity is high, we render the pixel and interpolate the pixel to multiple pixels. Result images show that our method can interactively render deformable translucent objects by approximating hundreds of thousand photons with only hundreds clusters without any preprocessing. We use an image-space approach for entire process on the GPU, thus our method is less dependent to scene complexity.

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Economic Impact Analysis of Hydrogen Energy Deployment Applying Dynamic CGE Model (동태 CGE 모형을 활용한 수소에너지 보급의 경제적 영향 추정)

  • Bae, Jeong-Hwan;Cho, Gyeong-Lyeob
    • Environmental and Resource Economics Review
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    • v.16 no.2
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    • pp.275-311
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    • 2007
  • Hydrogen energy is emphasized as a substitutable energy of carbon-based energy system in the future, since it is non-depletable and clean energy. Long term vision of Korean government on the national energy system is to promote hydrogen energy by 15% of final energy demand until 2040. This study analyzes economic impacts of hydrogen energy development employing a dynamic CGE model for Korea. Frontier technology such as hydrogen energy is featured as slow diffusion at the initial stage due to the learning effect and energy complementarity. Without government intervention, hydrogen energy would be produced upto 6.5% of final energy demand until 2040. However, if government subsidizes sales price of hydrogen energy by 10%, 20%, and 30%, share of hydrogen energy would increase 9.2%, 15.2%, and 37.7% of final energy demand. This result shows that the slow diffusion problem of hydrogen energy as frontier technology could be figured out by market incentive policy. On the other hand, production levels of transportation sector would increase while growth rate of oil and electricity sectors would decline. Household consumption would be affected negatively since increase of consumption due to the price decrease would be overwhelmed by income reduction owing to the increase of tax. Overall, GDP would not decrease or increase significantly since total production, investment, and export would increase even if household consumption declines.

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Evaluation of Chloride Behavior and Service Life in Long-Term Aged FA Concrete through Probabilistic Analysis (장기재령 FA 콘크리트에 대한 염화물 거동 및 확률론적 염해 내구수명 평가)

  • Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.276-285
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    • 2020
  • In this study, accelerated chloride diffusion tests were performed on OPC(Ordinary Portland Cement) and FA(Fly Ash) concrete considering three levels o f W/B(Water to Binder) ratio o n 1,095 curing days. The accelerated chloride diffusion coefficient and the passed charge were evaluated in accordance with Tang's method and ASTM C 1202, and the resistance performance to chloride attack improved over time. FA concrete showed excellent resistance performance against chloride penetration with help of pozzolanic reaction. As the result of the passed charge, FA concrete showed durability improvement, "low" grade to "very low" grade, but OPC concrete changed "moderate" grade to "low" grade at 1,095 curing days. After assuming the design variables used for durability design as normal distribution functions, the service life of each case was evaluated by the probabilistic analysis method based on MCS(Monte Carlo Simulation). In FA concrete, the increase of probability of durability failure was lower than that of OPC concrete with increasing time, because the time-dependent coefficient of FA concrete was up to 3.2 times higher than OPC concrete. In addition, the service life by probabilistic analysis was evaluated lower than the service life by deterministic analysis, since the target probability of durability failure was set to 10%. It is considered that more economical durability design will be possible if the mo re suitable target probability of durability failure is set for various structures through researches on actual conditions and indoor tests under various circumstances.

The Reclamation of Tidal Land and the Making-Group of Landscape in Naepo Area, Korea" - Centering around the Garorim Bay from the $19^{th}C$ to 1960s - (내포지역 해만개척의 전개와 경관변화의 사회적 주체 -조선후기~1960년대 가로림만 일대를 중심으로 -)

  • 전종한
    • Journal of the Korean Geographical Society
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    • v.38 no.2
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    • pp.206-223
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    • 2003
  • Bays and caps represent the physical characteristics of Naepo area in Korea. And reclamation of tidal land presents a clue toward the understanding of regional identities and landscape changes in this area. Reclamation of tidal land in the Garorim bay that is representative of the physical geographies of Naepo area had trended toward 'the diffusion of salt ponds' during Joseon dynasty. Hereafter the Japanese imperialism, the reclamation had tumed to 'the reclamation of arable lands' by drainage. But, at the same time the land use of salt pond that had been the most appropriate strategy of adaptation for the ecological environments of this area has showed a sort of the geographical long-term durability. And the great landlords that had emerged during Japanese imperialism were the Yeom-han(鹽漢, laborers who engaged in salt production) in former times. They as a new local elites have played a leading role in the reclamation of tidal land and the making of regional landscape.

A Bed Level Change Model(SED-FLUX) by Suspended Sediment Flux and Bed Load Flux in Wave-Current Co-existing Fields (파-흐름 공존장에서 부유사와 소류사 flux에 의한 지형변화모델)

  • Lee, Jong Sup;Yoon, Eun Chan;Park, Seok Hee
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.3B
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    • pp.311-319
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    • 2006
  • A bed level change model(SED-FLUX) is introduced based on the realistic sediment transport process including bed load and suspended load behaviours at the bottom boundary layer. The model SED-FLUX includes wave module, hydrodynamic module and sediment transport and diffusion module that calculate suspended sediment concentration, net sediment erosion flux($Q_s$) and bed load flux. Bed load transport rate is evaluated by the van Rijn's TRANSPOR program which has been verified in wave-current fields. The net sediment erosion flux($Q_s$) at the bottom is evaluated as a source/sink term in the numerical sediment diffusion model where the suspended sediment concentration becomes a verification parameter of the $Q_s$. Bed level change module calculates a bed level change amount(${\Delta}h_{i,j}$) and updates a bed level. For the model verification the limit depth of the bed load transport is compared with the field experiment data and some formula on the threshold depth for the bed load movement by waves and currents. This model is applied to the beach profile changes by waves, then the model shows a clear erosion and accumulation profile according to the incident wave characteristics. Finally the beach evolution by waves and wave-induced currents behind the offshore breakwater is calculated, where the model shows a tombolo formation in the landward area of the breakwater.

Application of Micro Porous Layer (MPL) for Enhance of Electrode Performance in Phosphoric Acid Fuel Cells (PAFCs) (인산형 연료전지(PAFC)의 전극 성능 향상을 위한 미세다공층(MPL)의 적용)

  • Jihun Ha;Sungmin Kang;You-Kwan Oh;Dong-Hyun Peck
    • Journal of the Korean Electrochemical Society
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    • v.27 no.1
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    • pp.32-39
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    • 2024
  • The key components of a Phosphoric acid fuel cell (PAFC) are an electrode catalyst, an electrolyte matrix and a gas diffusion layer (GDL). In this study, we introduced a microporous layer on the GDL of PAFC to enhance liquid electrolyte management and overall electrochemical performance of PAFC. MPL is primarily used in polymer electrolyte membrane fuel cells to serve as an intermediate buffer layer, effectively managing water within the electrode and reducing contact resistance. In this study, electrodes were fabricated using GDLs with and without MPL to examine the influence of MPL on the performance of PAFC. Internal resistance and polarization curves of the unit cell were measured and compared to each other to assess the impact of MPL on PAFC electrode performance. As the results, the application of MPL improved power density from 170.2 to 192.1 mW/cm2. MPL effectively managed electrolyte and water within the matrix and electrode, enhancing stability. Furthermore, the application of MPL reduced internal resistance in the electrode, resulting in sustained and stable performance even during long-term operation.

Leukoaraiosis on Magnetic Resonance Imaging Is Related to Long-Term Poor Functional Outcome after Thrombolysis in Acute Ischemic Stroke

  • Choi, Jae-Hyung;Bae, Hyo-Jin;Cha, Jae-Kwan
    • Journal of Korean Neurosurgical Society
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    • v.50 no.2
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    • pp.75-80
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    • 2011
  • Objective : Leukoaraiosis (LA) has been suggested to be related to the poor outcome or the occurrence of symptomatic intracerebral hemorrhage (sICH) after acute ischemic stroke. We retrospectively investigated the influences of LA on long-term outcome and the occurrence of sICH after thrombolysis in acute ischemic stroke (AIS). Methods : In this study, we recruited 164 patients with AIS and magnetic resonance image (MRI)-detected thrombolysis. The presence and extent of LA were assessed using the Fazekas grading system. The National Institutes of Health Stroke Scale score was used to assess the baseline measure of neurologic severity, and the modified Rankin Scale score assessment was used up to 1 year after thrombolysis. Results : Of 164 subjects, 56 (34.2%) showed LA on MRI. Compared to the 108 patients without LA, the patients with LA were of much older age (p<0.01), had a higher prevalence of hypertension (p<0.01), and had a much poorer outcome at 90 days (p=0.05) and 1 yr (p=0.01) after thrombolysis. There were no significant differences in sICH between patients with and without LA on MRI. In univariate analysis for the occurrence of poor outcome at 90 days after thrombolysis, the size of ischemic lesion on diffusion weighted images (DWI), [odds ratio (OR), 1.03; 95% confidence interval (95% CI), 1.01-1.04; p<0.01], recanalization (OR, 0.03; 95% CI, 0.01-0.10; p<0.01), sICH (OR, 12.2; 95% CI, 1.54-95.8), neurologic severity (OR, 1.17; 95% CI, 1.09-1.25; p<0.01), blood glucose level (OR, 1.01; 95% CI, 1.00-1.02; p=0.03), and the presence of LA on MRI (OR, 2.01; 95% CI, 1.04-3.01; p=0.04) were statistically significant. In multivariate analysis, neurologic severity (OR, 1.14; 95% CI, 1.04-1.24; p<0.01), recanalization (OR, 0.03; 95% CI, 0.01-0.11; p<0.01), lesion size on DWI (OR, 1.02; 95% CI, 1.01-1.03; p=0.02), serum glucose level (OR, 1.01; 95% CI; 1.01-1.02; p=0.03), and the presence of LA on MRI (OR, 3.2; 95% CI, 1.22-8.48; p<0.01) showed statistically significant differences. These trends persisted up to 1 yr after thrombolysis. Conclusion : In this study, we demonstrated that the presence of LA on MRI might be related to poor outcome after use of intravenous tissue plasminogen activator in AIS.

Analysis on Korean Public Rental Housing Market based on System Thinking (시스템사고를 이용한 국민임대주택 공급시장분석)

  • Kim, Tae-Young;Kim, Jae-Jun;Lee, Chan-Sik;Ahn, Hee-Jin
    • Korean Journal of Construction Engineering and Management
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    • v.7 no.5
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    • pp.115-127
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    • 2006
  • Although the Korean government have made a plan of housing market with supply and concentrated on the welfare of the people, there are still a lot of problem in housing market for lack of a long-term vision and consistent policy of the government. The plan of 115% of housing diffusion in 2012 is in progress after its acquisition of 100% in 2002, but there are no changes in the rental housing rate of 43% in 2003. In addition, there are getting worse circumstances in the instability of housing market and the low-income bracket, because of the Korean construction firms' bankruptcy with an increase of unsold hosing and a rapid increase of housing prices. The government have made the strategy of revitalizing the economy and regional development by means of a million public rental housing plan for the low-income bracket and welfare. This paper introduces the basic information of the subjective strategy establishment with the analysis of the reciprocal action of influence factors for public rental housing by system dynamics theory and the effect of public rental housing in housing supply market which has a long-term dynamic form.