• Title/Summary/Keyword: Diffusion Flux

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Effects of Nickel Supports on Hydrogen Permeability of Vanadium based Membrane (니켈 지지체를 이용한 바나듐기 분리막의 수소 투과특성)

  • Cho, Kyoungwon;Choi, Jaeha;Jung, Seok;Kim, Raymundk.I.;Hong, Taewhan;Ahn, Joongwoo
    • Journal of Hydrogen and New Energy
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    • v.24 no.3
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    • pp.200-205
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    • 2013
  • The separation of hydrogen depends on porosity, diffusivity and solubility in permeation membrane. Dense membrane is always showing a solution diffusion mechanism but porous membrane is not showing. Therefore, porous membrane has a good hydrogen flux due to pore is carried out transferred media. This mechanism is named as the Knudsen diffusion. Hydrogen molecules or hydrogen atoms are diffused along pore that is a mean free path. In this study, complex layer hydrogen permeation membrane was fabricated by hot press process. And then, it was evaluated and calculated to relationship between hydrogen permeability and membrane porosity.

Use of the Stratum Corneum Reservoir for the Prediction of Skin Penetration

  • Cholee, Ae-Ri;Tojo, Kakuji
    • Journal of Pharmaceutical Investigation
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    • v.23 no.3
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    • pp.1-8
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    • 1993
  • A simple and quick method based on the transient diffusion theory for predicting the steady state rate of penetration of a drug after transdermal drug administration was proposed. The amount of drug entering the stratum corneum was determined by 20 strippings with an adhesive tape. From the profile of the amount of drug as a function of the number of strippings, the quantity of drug on the surface of stratum corneum was extrapolated. Based on the amounts of drug entering the stratum corneum during two time intervals $(t_1\;and\;t_2)$ within 1 hour after the application, the diffusion and partition coefficient were determined. Once the diffusion coefficient of the drug in the stratum corneum and the partition coefficient (stratum corneum/vehicle) were determined from the present approach, the steady-state flux of penetration across the stratum corneum was calculated. The steady-state rates of penetration of ascorbic acid and estradiol across hairless mouse skin were evaluated from this approach and compared with those obtained from ill vitro penetration experiment using excised hairless mouse skin. The data confirmed that the proposed method can predict the steady-state rate of penetration of these drugs across the stratum corneum.

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Morphology control in PVDF membranes using PEG/PVP additives and mixed solvents

  • Rajabi, Shima;Khodadadi, Foroogh;Mohammadi, Toraj;Tavakolmoghadam, Maryam;Rekabdar, Fatemeh
    • Membrane and Water Treatment
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    • v.11 no.4
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    • pp.237-245
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    • 2020
  • The effects of the mixed two solvents, Dimethylacetamide (DMAc) and Dimethylformamide (DMF), and Polyethylene glycol (PEG) and Polyvinylpyrrolidone (PVP) as additives on performance of Polyvinylidene fluoride (PVDF) membranes were studied. Initially, PEG200 was used as a primary additive at fixed percentage of 5% wt. PVP was then blended with PEG200 in different concentrations. PVDF and DMAc were used as polymer and solvent in the casting solutions, respectively. To control the diffusion rate of PVP in the presence of PEG200 and PVP blend, mixtures of DMAc and DMF were used as the mixed solvent in the casting solutions. Asymmetric PVDF membranes were prepared via phase inversion process in a water bath and the effects of two additives and two solvents on the membrane morphology, pure water flux (PWF), hydrophilicity and rejection (R) were investigated. Attenuated Total Reflection Fourier Transform Infrared Spectra (ATR-FTIR) analysis was used to show the residual PVP on the surface of the membranes. Atomic Force Microscopy (AFM) was utilized to determine roughness of membrane surface. The use of mixed solvents in the casting solution resulted in reduction of PVP diffusion rate and increment of PEG diffusion rate. Eventually, PWF and R values reduced, while porosity and hydrophilicity increased.

A Three-Dimensional Nodal Diffusion Code Based on the AFEN Methodology (해석함수전개 노달방법에 기초한 3차원 노달확산 코드)

  • Hong, Ser-Gi;Cho, Nam-Zin;Noh, Jae-Man
    • Nuclear Engineering and Technology
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    • v.27 no.6
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    • pp.870-876
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    • 1995
  • In this paper, a new three-dimensional nodal diffusion code which is based on the AFEN methodology is described and tested. The method expands the homogeneous flux within a node in ter-ms of eighteen analytic basis functions satisfying the diffusion equation at any point of the node. And the nodal coupling equations are derived such that nodal balance, current continuity and leakage balance within an infinitesimally small box around the edge are satisfied. To verify its accuracy, the code was applied to the well-known static LMW benchmark problem and a small core benchmark problem that has the same material properties as the three-dimensional IAEA benchmark problem and compared with two other codes (QUANDRY, VENTURE). The results show that the code provides good accuracy both in the power distribution and in the effective multiplication factor.

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Development of Galerkin Finite Element Method Three-dimensional Computational Code for the Multigroup Neutron Diffusion Equation with Unstructured Tetrahedron Elements

  • Hosseini, Seyed Abolfazl
    • Nuclear Engineering and Technology
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    • v.48 no.1
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    • pp.43-54
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    • 2016
  • In the present paper, development of the three-dimensional (3D) computational code based on Galerkin finite element method (GFEM) for solving the multigroup forward/adjoint diffusion equation in both rectangular and hexagonal geometries is reported. Linear approximation of shape functions in the GFEM with unstructured tetrahedron elements is used in the calculation. Both criticality and fixed source calculations may be performed using the developed GFEM-3D computational code. An acceptable level of accuracy at a low computational cost is the main advantage of applying the unstructured tetrahedron elements. The unstructured tetrahedron elements generated with Gambit software are used in the GFEM-3D computational code through a developed interface. The forward/adjoint multiplication factor, forward/adjoint flux distribution, and power distribution in the reactor core are calculated using the power iteration method. Criticality calculations are benchmarked against the valid solution of the neutron diffusion equation for International Atomic Energy Agency (IAEA)-3D and Water-Water Energetic Reactor (VVER)-1000 reactor cores. In addition, validation of the calculations against the $P_1$ approximation of the transport theory is investigated in relation to the liquid metal fast breeder reactor benchmark problem. The neutron fixed source calculations are benchmarked through a comparison with the results obtained from similar computational codes. Finally, an analysis of the sensitivity of calculations to the number of elements is performed.

Effects of Swirl/Shear-coaxial Injector on the Dynamic Behavior of Gaseous Methane-Gaseous Oxygen Diffusion Flame (스월/전단 동축형 인젝터가 기체메탄-기체산소 확산화염의 동역학적 거동에 미치는 영향)

  • Hong, Joon Yeol;Bae, Dae Seok;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.1
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    • pp.1-8
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    • 2019
  • To analyze the dynamic behavior and the structure of the gaseous methane-gaseous oxygen diffusion flame formed by a swirl/shear-coaxial injector, combustion experiments were carried out under different propellant injection conditions. As a result, the OH radical emission intensity of the diffusion flame visualized through chemiluminescence was observed to increase as the propellant mass flow and the momentum flux ratio increased. And flames with swirl showed a more high radical emission intensity than those without swirl.

A hybrid neutronics method with novel fission diffusion synthetic acceleration for criticality calculations

  • Jiahao Chen;Jason Hou;Kostadin Ivanov
    • Nuclear Engineering and Technology
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    • v.55 no.4
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    • pp.1428-1438
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    • 2023
  • A novel Fission Diffusion Synthetic Acceleration (FDSA) method is developed and implemented as a part of a hybrid neutronics method for source convergence acceleration and variance reduction in Monte Carlo (MC) criticality calculations. The acceleration of the MC calculation stems from constructing a synthetic operator and solving a low-order problem using information obtained from previous MC calculations. By applying the P1 approximation, two correction terms, one for the scalar flux and the other for the current, can be solved in the low-order problem and applied to the transport solution. A variety of one-dimensional (1-D) and two-dimensional (2-D) numerical tests are constructed to demonstrate the performance of FDSA in comparison with the standalone MC method and the coupled MC and Coarse Mesh Finite Difference (MC-CMFD) method on both intended purposes. The comparison results show that the acceleration by a factor of 3-10 can be expected for source convergence and the reduction in MC variance is comparable to CMFD in both slab and full core geometries, although the effectiveness of such hybrid methods is limited to systems with small dominance ratios.

Gamma-Ray and Neutrino Emissions from Starburst Galaxies

  • Ha, Ji-Hoon;Ryu, Dongsu;Kang, Hyesung
    • The Bulletin of The Korean Astronomical Society
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    • v.45 no.1
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    • pp.37.1-37.1
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    • 2020
  • Cosmic-ray protons (CRp) are efficiently produced at starburst galaxies (SBGs), where the star formation rate (SFR) rate is high. In this talk, we present estimates of gamma-ray and neutrino emissions from nearby SBGs, M82, NGC253, and Arp220. Inside the starburst nucleus (SBN), CRp are accelerated at supernova remnant (SNR) shocks as well as at stellar wind (SW) termination shocks, and their transport is governed by the advection due to starburst-driven wind and diffusion mediated by turbulence. We here model the momentum distributions of SNR and SW-produced CRp with single or a double power-law forms. We also employ two different diffusion models, where CRp are resonantly scattered off large-scale turbulence in SBN or self-excited waves driven by CR streaming instability. We then calculate gamma-ray/neutrino fluxes. The observed gamma-ray fluxes by Fermi-LAT, Veritas, and H.E.S.S are well reproduced with double power-law distribution for SNR-produced CRp and the CRp diffusion by self-excited turbulence. The estimated neutrino fluxes are <~10-3 of the atmospheric neutrino flux in the energy range of Eneutrino <~100 GeV and <~10-1 of the IceCube point source sensitivity in the energy range of Eneutrino >~60 TeV.

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Calcitonin Transport through Skin Using Iontophoresis

  • Kim, Kyung-Min;Oh, Seaung-Youl
    • Journal of Pharmaceutical Investigation
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    • v.41 no.1
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    • pp.9-17
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    • 2011
  • The objective of this work is to study transdermal delivery of calcitonin using iontophoresis and to evaluate various factors which affect the transdermal transport. We have studied the effect of polarity, current density, drug concentration, penetration enhancers (isopropyl myristate [IPM] and ethanol) and laser treatment on transdermal flux and the results were compared. We also investigated the iontophoretic flux from microemulsions containing calcitonin together with oleic acid (OA) or IPM. In vitro flux study was performed at $33^{\circ}C$, using side-by-side diffusion cell and full thickness hairless mouse skin. Anodal delivery at pH 3.0 was much larger than cathodal and passive delivery, due to the positive charge of calcitonin. Cumulative amount delivered (CUM) by cathodal or passive delivery was close to zero for 10 hours. The pretreatment of skin by neat IPM markedly increased the CUM anodically. CUM increased as the current density, drug concentration or the duration of IPM treatment increased. Microemulsion containing IPM or oleic acid was prepared and the phase diagram was constructed. CUM also increased when IPM was incorporated into a microemulsion. OA microemulsion showed similar enhancing effect to IPM microemulsion. The delivery of calcitonin from 70% (v/v) ethanol aqueous solution showed a large increase in flux. Laser treatment of skin before flux experiment exhibited about 2 fold increase in total calcitonin amount transported for 12 hours, when compared to that delivered by IPM microemulsion. Based on these results, we have evaluated the possibility of delivering enough amount of calcitonin to reach the therapeutic level. The data suggest that it is highly possible to deliver clinically effective amount of calcitonin using iontophoresis patch with small area (<10 $cm^2$).

Estimation of Surface Layer Heat Flux Using the UHF Sensor Installed on UAV (UHF 센서 탑재 UAV를 이용한 지표층 열 플럭스 산출)

  • Kim, Min-Seong;Kwon, Byung Hyuk;Yoon, Hong-Joo
    • The Journal of the Korea institute of electronic communication sciences
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    • v.13 no.1
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    • pp.265-276
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    • 2018
  • Observation and data analysis techniques have been developed for observational blind areas in the lower atmosphere that are difficult to be monitored with fixed equipment on the ground. The vertical data of temperature and relative humidity are remotely collected by the UHF radiosonde installed on UAV and compared with the data measured in the 10 m weather tower. From the validated vertical profile, extrapolated surface temperature and the bulk transfer method were used to estimate the sensible heat flux depending on the atmospheric stability. Compared with the sensible heat flux measured by the 3-dimensional ultrasonic anemometer on the ground, the error of the sensible heat flux estimated was 23% that is less than the range of 30% allowed in the remote sensing. Estimated atmospheric boundary layer height from UAV sensible heat fluxes can provide useful data for air pollution diffusion models in real time and economically.