• Title/Summary/Keyword: Diffusion Coefficient for Chloride Ion

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Experimental Study on Chloride Penetration into Concrete under Combined Exposure Conditions of Chlorides and High Concentrated Sulfates (고농도 황산염 이온이 함께 존재하는 경우의 염소이온 침투특성에 관한 실험 연구)

  • Oh, Byung-Hwan;Jung, Sang-Hwa;Jiang, Yi-Rong;Kim, Jee-Sang
    • Journal of the Korea Concrete Institute
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    • 제15권2호
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    • pp.173-182
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    • 2003
  • Recently, the durability of concrete structures has received great attention as the number of sea-side structures, such as new airport, bridges, and nuclear power plants, increases continuously. In this regards, many studies have been done on the chloride attack in concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the effects of combined deterioration due to chlorides and sulfates in concrete structures. To this end, comprehensive experimental program has been set up to observe the chloride penetration behavior for various test series. The test results indicate that the chloride penetration is more pronounced for the case of combined attack than the case of single chloride attack. The surface chloride content is found to increase with time and the diffusion coefficient for chloride is found to decrease with time. The prediction equations for surface chloride content and diffusion coefficient were proposed according to test results. The equations for chloride penetration considering the time-dependent diffusion coefficients and surface chlorides were also suggested. The present study allows more realistic assessment of durability for such concrete structures which are subjected to combined attacks of chlorides and high concentration sulfates but the future studies for combined environment will assure the precise assessment.

Estimation on the Durability of High-Strength Concrete using Metakaolin (Metakaolin 혼합 고강도콘크리트의 내구특성 평가)

  • Moon Han Young;Yum Jun Hwan;Moon Su Dong;Lee Sang Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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    • pp.217-220
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    • 2004
  • Metakaolin is a cementitious material for producing high-strength concrete. This material is now used as substitute for silica-fume. In this paper, we did the durability test such as chloride ion diffusion, chemical attack. repeated freezing and thawing, carbonation. In the chloride ion diffusion test, according to the increase of substitute of metakaolin & silica-fume for binder, the diffusion coefficient is more reduced. And in the chemical attack test, according to the increase of substitute, the resistance is more excellent. In the other durability test, the concrete using metakaolin is also compared with those of the portland cement concrete and silica fume concrete. According to these tests, we recognized that metakaolin is able to be used as a substitute for silica-fume.

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Estimation on the Durability of Metakaolin Concrete According to the W/B Ratio (물결합재비를 달리하여 제작한 메타카올린 혼입 콘크리트의 내구성능 평가)

  • Kim, Chun-Ho;Kim, Nam-Wook
    • Journal of the Korea institute for structural maintenance and inspection
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    • 제18권4호
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    • pp.84-91
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    • 2014
  • In this study, in order to find the improvement effect of metakaolin for using improvement of strength in concrete structures, it is investigated the diffusion coefficient of chloride ions and adiabatic temperature rise test. As a result, due to the mixing of metakaolin, it has been confirmed reducing diffusion coefficient of chloride ions and could prevent down of slump for use of adding fly ash. Therefore, ensuring resistance to chloride ion penetration into concrete, it is possible to enlarge the W/B ratio and reduce the adiabatic temperature rise by mixing of metakaolin. So, it is confirmed that the durability of concrete structures is increased.

Chloride penetration in anchorage concrete of suspension bridge during construction stage

  • Yang, In-Hwan;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Advances in concrete construction
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    • 제10권1호
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    • pp.13-20
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    • 2020
  • Steel corrosion in embedded steel causes a significant durability problems and this usually propagates to structural degradation. Large-scaled concrete structures, PSC (Pre-stressed Concrete) or RC (Reinforced Concrete) structures, are usually constructed with mass concrete and require quite a long construction period. When they are located near to sea shore, chloride ion penetrates into concrete through direct or indirect exposure to marine environment, and this leads durability problems. Even if the structures are sheltered from chloride ingress outside after construction, the chloride contents which have been penetrated into concrete during the long construction period are differently evaluated from the initially mixed chloride content. In the study, chloride profiles in cores extracted from anchorage concrete block in two large-scaled suspension bridge (K and P structure) are evaluated considering the exposure periods and conditions. Total 21 cores in tendon room and chamber room were obtained, and the acid-soluble chlorides and compressive strength were evaluated for the structures containing construction period around 3 years. The test results like diffusion coefficient and surface chloride content from the construction joint and cracked area were also discussed with the considerations for maintenance.

Evaluation on Long-term Mechanical Performance and Durability of Recycled Coarse Aggregate Concrete Produced by Two-stage Mixing Approach (2단계 배합방법으로 제조된 순환굵은골재 콘크리트의 장기재령 역학적 성능 및 내구성 평가)

  • Seong-Uk, Heo;Jeong Jin, Son;Chul-Woo, Chung;Young Chan, Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • 제10권4호
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    • pp.475-481
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    • 2022
  • Recycled aggregates show high water absorption rate compared to natural aggregates due to microcrack developed during production process and adhered cement pastes at the surface of recycled aggregates. This leads to the deterioration of mechanical properties and slow work flow. Currently it is getting hard to satisfy high demand for natural aggregates. Utilizing recycled aggregate more widely may be a substitutable countermeasure for the shortage of natural resources. In this study, two-stage mixing approach(TSMA) suggested by Tam et al. is used to produce recycled aggregate concrete(RAC) with 100 % replacement of coarse natural aggregate and tests for compressive strength, elastic modulus, and chloride ion diffusion coefficient are conducted to find out the effect of TSMA compared to normal mixing method. According to experimental result compressive strength and elastic modulus of RAC with TSMA was superior to those of RAC with normal mixing irrespective of water-cement ratio, and in some cases mechanical properties of RAC with TSMA approached to those of natural aggregate concrete(NAC). However, chloride ion diffusion coefficient of RAC was higher than that of NAC. This illustrates that TSMA is not an appropriate method in reducing chloride ion diffusion coefficient, resulting in inconsequential contribution of TSMA to the durability of RAC.

An Evaluation on the Chloride Resistance of Concrete Footing at Coastal Area -Comparision of Performance in Korea Building Code(KBC)- (해안인접지역 기초 구조물콘크리트의 내염해 성능 평가 -건축구조기준과의 성능비교-)

  • Park, Yong-Kyu;Yoon, Gi-Won;Kim, Hyun-Woo;Kim, Yong-Ro;Song, Young-Chan
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 한국건축시공학회 2016년도 추계 학술논문 발표대회
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    • pp.148-149
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    • 2016
  • In this paper, the increase in chloride resistance of footing concrete at coastal area was evaluated by replacement of Mineral Admixture. In KBC 2009, the footing concrete's minimum specific concrete strength at coastal area is determined to 35MPa. However, this is criteria only based on the strength aspect. Thus, it is not considered to increase the chloride resistance by replacement of Mineral Admixture. According to the test results of chloride ions penetration resistance, 35MPa class concrete with OPC 100% shown inaccessible state. Low-strength (24~30MPa class) concretes with Mineral Admixture, however, presented better performances. In addition, chloride diffusion coefficient tests showed identical appearance. Therefore, the current KBC's chloride resistance criteria based on only concrete strength has to review for the reason it can cause many problems (ex. cost increases by growing concrete strength and the environmental issues by a lot of cement use).

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Resistance against Chloride Ion and Sulfate Attack of Cementless Concrete (무시멘트 콘크리트의 염소이온 침투 및 황산염 침투 저항성)

  • Lee, Hyun-Jin;Bae, Su-Ho;Kwon, Soon-Oh;Lee, Kwang-Myong;Jeon, Jun-Tai
    • Journal of the Korean Society for Advanced Composite Structures
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    • 제6권2호
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    • pp.63-69
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    • 2015
  • It has been well known that concrete structures exposed to chloride and sulfate attack environments lead to significant deterioration in their durability due to chloride ion and sulfate ion attack. The purpose of this experimental research is to evaluate the resistance against chloride ion and sulfate attack of the cementless concrete replacing the cement with ground granulated blast furnace slag. For this purpose, the cementless concrete specimens were made for water-binder ratios of 40%, 45%, and 50%, respectively and then this specimens were cured in the water of $20{\pm}3^{\circ}C$ and immersed in fresh water, 10% sodium sulfate solution for 28 and 91 days, respectively. To evaluate the resistance to chloride ion and sulfate attack for the cementless concrete specimens, the diffusion coefficient for chloride ion and compressive strength ratio, mass change ratio, and length change ratio were measured according to the NT BUILD 492 and JSTM C 7401, respectively. It was observed from the test results that the resistance against chloride ion and sulfate attack of the cemetntless concrete were comparatively largely increased than those of OPC concrete with decreasing water-binder ratio.

Rapid Chloride Penetration Test for Concrete Based on the Electrochemical Method (전기 영동법에 기초한 콘크리트의 급속 염소이온 확산 특성 평가)

  • Oh, Sang-Gyun;Park, Dong-Cheon
    • Journal of Navigation and Port Research
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    • 제34권10호
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    • pp.787-792
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    • 2010
  • It is necessary to predict the penetration of chloride ions for designing RC construction in marine environments. However, it takes a long time to obtain chloride migration coefficients. Therefore, the rapid chloride penetration test (RCPT) is generally used to shorten the test time. But there is a difference between chloride migration coefficients determined by rapid chloride penetration tests and those based on exposure in marine environments. In this study, we evaluated the effect on the chloride ion migration coefficient caused by a change in voltage and NaCl concentration. We also compared the relationship between the chloride ion migration coefficient by RCPT and that by exposure in marine environments. As a result of the experiments, we found that there is only a small change in the experimental factors based on changes in voltage and NaCl concentration and since they are so small, we can conclude that they are in the range of experimental error and test results from chloride ion migration coefficients by RCPT and exposure were very different from each other. In the exposure experiments, when the water-cement ratio was increased, the smaller fine air gaps in concrete affected the chloride ion migration coefficient.

Durability Evaluation of RC Structures subjected. to Chloride Attack (철근콘크리트 구조물의 염해 내구성 평가)

  • 백승우;남진원;송하원;변근주
    • Proceedings of the Korea Concrete Institute Conference
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    • 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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    • pp.663-668
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    • 2003
  • In this paper, an environmental factor and a durability resistance factor which adapts the concept of the Load Resistance Factor Design for safety design of RC structures is derived and a basic principle of a durability evaluation for RC structures using the factors is proposed. It is shown that durability of RC structures can be evaluated by comparing predicted value of chloride ion concentration with limit value of concentration for steel corrosion generation in reinforcement steel position and the durability of concrete manufactured for the RC structures can be also evaluated by comparing characteristic diffusion coefficient of concrete with predicted diffusion coefficient during mixture design.

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A Study on the Quality Deviation of High-Strength Concrete from Multiple Ready Mixed Concrete Companies (다수 레미콘사에서 납품된 콘크리트 품질 편차에 관한 연구)

  • Park, Dong-Cheon;Seok, Won-Kyun;Jeon, Hyun-Soo;Kim, Young-Sun
    • Journal of the Korea Institute of Building Construction
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    • 제22권6호
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    • pp.577-583
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    • 2022
  • On large-scale sites, concrete is often delivered from a number of ready-mixed concrete companies, but even if the same concrete mixture table is used, it is thought that there will be a difference in quality due to differences in materials and manufacturing equipment. Due to a lack of previous research in this area, this study measured the properties of fresh concrete, compressive strength, and chlorine ion diffusion coefficient using the concrete supplied by 12 ready-mixed companies in Busan. The fresh concrete properties met the criteria. The compressive strength increased by 137% for 30MPa, 131% for 45MPa, and 117% for 80MPa by specified compressive strength. For the chlorine ion diffusion coefficient, the average value for each specified compressive strength could be derived without significant variation. The higher the compressive strength, the greater the deviation , and the lower the compressive strength, the greater the deviation in the chlorine ion diffusion coefficient.