• Korean Chemical Engineering Research
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• v.53 no.6
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• pp.723-729
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• 2015

The moment analysis of cyclic adenosine monophosphate (cAMP) was performed using chromatograms that were obtained with the pulse input method from an octadecyl silica (ODS) high-performance liquid chromatography (HPLC) column. The general rate (GR) model was employed to calculate the first absolute moment and the second central moment. Three important coefficients for moment analysis, which are molecular diffusivity ($D_m$), external mass transfer coefficient ($k_f$), and intra-particle diffusivity ($D_e$), were estimated by the Wilke-Chang equation, Wilson-Geankoplis equation, and comparing van Deemter equation to theoretical plate number equation, respectively. Experiments were conducted by various conditions of flow rates, methanol volume ratio of the mobile phase, and solute concentration. After the moment analysis, results were organized by van Deemter plots. Also van Deemter coefficients were compared each other to effect $H_{ax}$, $H_f$, and $H_d$ on height equivalent to a theoretical plate (HETP, $H_{total}$). The value of intraparticle diffusion ($H_d$) was the primary factor which makes for HETP whereas external mass transfer ($H_f$) was disregardable factor.

• Journal of Microbiology and Biotechnology
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• v.26 no.12
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• pp.2171-2178
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• 2016

Polyester cloth (PC) was selected as a prospective inexpensive substitute separator material for microbial fuel cells (MFCs). PC was compared with a traditional Nafion proton exchange membrane (PEM) as an MFC separator by analyzing its physical and electrochemical properties. A single layer of PC showed higher mass transfer (e.g., for $O_2/H^+/ions$) than the Nafion PEM; in the case of oxygen mass transfer coefficient ($k_o$), a rate of $50.0{\times}10^{-5} cm{\cdot}s^{-1}$ was observed compared with a rate of $20.8{\times}10^{-5}cm/s$ in the Nafion PEM. Increased numbers of PC layers were found to reduce the oxygen mass transfer coefficient. In addition, the diffusion coefficient of oxygen ($D_O$) for PC ($2.0-3.3{\times}10^{-6}cm^2/s$) was lower than that of the Nafion PEM ($3.8{\times}10^{-6}cm^2/s$). The PC was found to have a low ohmic resistance ($0.29-0.38{\Omega}$) in the MFC, which was similar to that of Nafion PEM ($0.31{\Omega}$); this resulted in comparable maximum power density and maximum current density in MFCs with PC and those with Nafion PEMs. Moreover, a higher average current generation was observed in MFCs with PC ($104.3{\pm}15.3A/m^3$) compared with MFCs with Nafion PEM ($100.4{\pm}17.7A/m^3$), as well as showing insignificant degradation of the PC surface, during 177 days of use in swine wastewater. These results suggest that PC separators could serve as a low-cost alternative to Nafion PEMs for construction of cost-effective MFCs.

• Journal of the Korean Wood Science and Technology
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• v.47 no.6
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• pp.732-750
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• 2019

Air drying was carried out on 15 Korean red pine logs to provide a prediction model of the moisture content (MC) change in the wood during drying. The final MC was 17.4% after 880 days since the beginning of air drying in the summer for 6 Korean red pine logs with 68.7% initial MC. The final MC was 16.0% after 760 days since the beginning of air drying in the winter for 9 Korean red pine logs with 35.8% initial MC. A regression model with R-squared of 0.925 was obtained as a result of multiple regression analyses with initial MC, top diameter, temperature, relative humidity, and wind speed as independent variable and and MC change during air drying as dependent variable. The initial MC and top diameter, which is the characteristic of Korean red pine, have greater effect on the MC decrease during air drying compared to meteorological factors such as the temperature, relative humidity, and wind speed. Two-dimensional mass transfer analysis was performed to predict the MC distribution of Korean red pine logs during air drying. Two prediction models with different air drying days and different meteorological factors for the determination of the diffusion coefficient and surface emission coefficient were presented. The error between the different two methods ranged from 0.1 to 0.8% and the difference from the measured value ranged from 2.2 to 3.6%. By measuring the internal MC during air drying of Korean pine logs with various initial MC and diameter, and calculating the moisture transfer coefficient in wood for each meteorological condition, the error of the prediction model can be reduced.

• KSBB Journal
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• v.6 no.3
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• pp.241-247
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• 1991

The Poly (4-vinyipyridine-co-styrene) membrane containing Pyridine as fixed carrier was synthesized and characterized. And the active transport mechanism of Cl- and $CCl_3COO^-$ with changing concentration of $H^+$ and $OH^-$ was investigated. $CCl_3COO^-$ was transported not only by a symport mechanism with $H^+$ transfer but also by an antiport mechanism with $OH^-$transfer, while $Cl^-$ was transported only by a symport mechanism with $H^+$ transfer. Observing the initial flux of anions, salt formation constant between ions and membrane (K), and diffusion coefficient in membrane (D) were calculated as follows: for $Cl^-, \;K=4.60{\times}10^2\;mol^{-1}{\cdot}\textrm{cm}^3, \;D=1.57{\times}10^{-3}{\textrm{cm}^2/h$ and for $CCl_3COO^-, \;K=1.l0{\times}10^4\;mol^{-1}{\cdot}\textrm{cm}^3, \;D=1.14{\times}10^{-4}{\textrm{cm}^2}/h$.

• Applied Chemistry for Engineering
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• v.9 no.6
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• pp.889-893
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• 1998

In this research, mathematical models for predicting the shelf life of packaged tofu in a polyethylene container were developed. Transfer of oxygen in air through the package and then diffusion of oxygen into the filled water and the tofu with the simultaneous oxygen consumption by micoorganisms were studied. The results of simulation showed that the increase of microorganisms in the filled water was more than that in tofu. As a result, it turns out that the shelf life of packaged tofu was not determined by the number of microorganisms in the tofu, but by that in the filled water. Additionally, the effects of physical properties of packaging material and packaged materials, such as the oxygen permeability of packaging material, oxygen diffusion coefficient and the initial oxygen concentration in filled water, and the depth of the filled water, on the shelf life of packaged tofu, were observed.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.4
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• pp.600-609
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• 2001

WSGGM based low-resolution spectral model for calculating radiation transfer in combustion gases is applied to estimate self-absorption of radiation energy in one-dimensional opposed flow flames. Development of such a model is necessary in order to enable detailed chemistry-radiation interaction calculations including self-absorption. Database of band model parameters which can be applied to various one-dimensional opposed flow diffusion and partially premixed flames is created. For the validation of the model and database, low resolution spectral intensities at fuel exit side are calculated and compared with the results of a narrow band model with those based on the Curtis-Godson approximation. Good agreements have been found between them. The resulting radiation model is coupled to the OPPDIF code to calculate the self-absorption of radiant energy and compared with the results of an optically thin calculation and the results of a discrete ordinates method in conjunction with the statistical narrow band model. Significant self-absorption of radiation is found for the flames considered here particularly for the fuel side of the reacting zone. However, the self-absorption does not have significant effects on the flame structure in this case. Even in the case of the low velocity diffusion flame and the partially premixed flame of low equivalence ratio, the effects of self-absorption of radiation on the flame temperature and production of minor species are not significant.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.1B
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• pp.137-147
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• 2008

Soil Vapor Extraction (SVE) has been extensively used to remove volatile organic compounds (VOCs) from the vadoze zone. In order to investigate the removal mechanism during SVE operation, laboratory modeling experiments were carried out and tailing effect could be observed in later stage of the experiment. Tailing effect means that removal rate of contaminants gets significantly to decrease in later stage of SVE operation. Also, mathematical model simulating the tailing effect was used, which considers rate-limited diffusion in a water film during mass transfer among gas, liquid, and solid phases. Measurement data obtained through the experiment was used as input data of the numerical analyses. Sensitivity analysis was performed to examine the effect of each parameter on required time to reach final target concentration. Finally, it was found that the concentration in the soil phase decreased significantly with a liquid and gas diffusion coefficient larger, actual path length shorter, and water saturation smaller.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.11
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• pp.772-779
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• 2012

For improving performance of conical air diffuser generating fine bubble, both experimental and numerical simulation method were used. After adapting diffusers inner real scale bubble column, suitable for various diffuser submergence, the effect of diffuser submergence on oxygen transfer performance such as Oxygen Transfer Coefficient ($K_{L}a_{20}$) and Standard Oxygen Transfer Efficiency (SOTE) was investigated empirically. As flow patterns for various diffuser number and submergence were revealed throughout hydrodynamic simulation for 2-phase fluid flow of air-water, the cause of the change for oxygen transfer performance was cleared up. As results of experimental performance, $K_{L}a_{20}$ was increased slightly by 7% and SOTE was increased drastically by 39~72%, 5.6% per meter. As results of numerical analysis, air volume fraction, air and water velocity in bioreactor were increased with analogous flow tendency by increasing diffuser number. As diffuser submergence increased, air volume fraction, air and water velocity were decreased slightly. Because circulative co-flow is determinant factor for bubble diffusion and rising velocity, excessive circulation intensity can result to worsen oxygen transfer by shortening bubble retention time and amount.

• Toxicological Research
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• v.13 no.1_2
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• pp.49-54
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• 1997

PCBs are classified as B2 (Probable human carcinogen) based on the induction of hepatocellular carcinomas in rats and mice from IRIS (Integrated Risk Information System). About 20 years ago, PCBs were phased out for electrical use in Korea, but PCBs were continuously used in the other field. Lately, there has been increasing concern on possible effects of contaminated soil to the other environment and human health. The purpose of this study is to determine PCBs level in soil at some site and to assess the human exposure doses according to exposure routes for people living within sites which expected to be exposed to PCBs. Pollution level of PCBs on the site was monitored using gas liquid chromatography. To assess the transport of PCBs in soil to plant and to air, various transfer factors(diffusion coefficient, bioconcentration factor etc.) were considered in simple calculations. To calculate the residential exposure doses by routes, some equations were considered using assumption value, which define inhalation, ingestion (soil, plant) and derreal uptake pathway. Computated results will be used as risk assessment information for human health evaluation on contaminated soil.

• Bulletin of the Korean Chemical Society
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• v.35 no.9
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• pp.2679-2683
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• 2014

Mechanisms underlying the impacts of interactions between carbon nanoparticles (CNPs) and ionic liquids (ILs) on the physicochemical behavior of CNPs need to be more full worked out. This manuscript describes a theoretical investigation at multiple levels on the interactions of fullerene $C_{60}$ with 21 imidazolium-based ILs of varying alkyl side chain lengths and anionic types and their impacts on $C_{60}$ dispersion behavior. Results show that ${\pi}$-cation interaction contributed to mechanism of the $C_{60}$-IL interaction more than ${\pi}$-anion interaction. The calculated interaction energy ($E_{INT}$) indicates that $C_{60}$ can form stable complex with each IL molecule. Moreover, the direction of charge transfer occurred from IL to $C_{60}$ during the $C_{60}$-IL interaction. Quantitative models were developed to evaluate the self-diffusion coefficient of $C_{60}$ ($D_{fullerene}$) in bulk ILs. Three interpretative molecular descriptors (heat of formation, $E_{INT}$, and charge) that describe the $C_{60}$-IL interactions and the alkyl side chain length were found to be determinants affecting $D_{fullerene}$.