• 제목/요약/키워드: Differential diffusion

검색결과 285건 처리시간 0.023초

기계적합금화법에 의해 제조된 NiAl 나노금속간화합물 소결체의 인성 및 제진특성 (Toughness and Damping Properties of Nanostructured Ni-Al Alloys Produced by Mechanical Alloying Methods)

  • 안인섭;김형범;김영도;김지순
    • 한국분말재료학회지
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    • 제7권3호
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    • pp.143-148
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    • 2000
  • NiAl alloy powders were prepared by mechanical alloying method and bulk specimens were produced using hot isostatic pressing techniques. This study focused on the transformation behavior and properties of Ni-Al mechanically alloyed powders and bulk alloys. Transformation behavior was investigated by differential scanning calorimeter (DSC), XRD and TEM. Particle size distribution and microstructures of mechanically alloyed powders were studied by particle size analyzer and scanning electron microscope (SEM). After 10 hours milling, XRB peak broadening appeared at the alloyed powders with compositions of Ni-36at%Al to 40at%Al. The NiAl and $Ni_3Al$ intermetallic compounds were formed after water quenching of solution treated powders and bulk samples at $1200^{\circ}C$, but the martensite phase was observed after liquid nitrogen quenching of solution treated powders. However, the formation of $Ni_3Al$ intermetallic compounds were not restricted by fast quenching into liquid nitrogen. It is considered to be caused by fast diffusion of atoms for the formation of stable $\beta$(NiAl) phase and $Ni_3Al$ due to nano sized grains during quenching. Amounts of martensite phase increased as the composition of aluminium component decreased in the Ni-Al alloy, which resulted in the increasing damping properties.

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방화문용 연기/열 차단막의 변위-열응력 해석에 관한 연구 (A Study on the Displacements-Thermal Stress Analysis of Smoke/Heat Interception Screen in Eire Door)

  • 이동명
    • 한국화재소방학회논문지
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    • 제18권2호
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    • pp.73-78
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    • 2004
  • 본 연구는 화재가 발생할 때 방화문과 바닥 면의 하부 틈새를 박아 연기와 열의 누설 또는 확산을 막을 수 있는 연기/열 차단막에 대하여 연구하였다. 본 연구에서는 제연구역의 차압과 화재발생 시 발생하는 연기의 유체부력에 의한 역학적인 힘과 열기류를 고려하여 유한요소 해석코드인 $ANSYS^{\circledR}$ 을 이용하여 해석하였다. 연구결과로부터 하중조건을 최소화할 수 있는 연기/열 차단막의 최적설계의 방향을 제시하였고, 연기/열 차단막의 형상설계에 활용함으로서 연기/열 차단 시스템의 엔지니어링 데이터를 구축하는데 도움이 되었다.

Bacteriocin을 생산하는 장내 유산균의 분리 및 Bacteriocin 특성조사 (Isolation of Bacteriocin-producing Lactic Acid Bacteria from Human Intestines and the Characteristics of their Bacteriocins)

  • 김정환;맹길재;김정상;지근억
    • 한국식품영양과학회지
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    • 제26권6호
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    • pp.1228-1236
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    • 1997
  • Lactobacillus strains were isolated from volunteer's feces, including from newly-born infants and adults in their 20's, by using differential MRS-BPB plates. Total 56 presumptive Lactobacillus strains were isolated and the bacteriocin productions by the isolates were examined by agar diffusion method. Six bacteriocin-producing strains were confirmed. Among them, two isolates, HU-1 and H22-3, showed the most outstanding antimicrobial activities, which were not affected by pH adjustments or catalase treatments of culture. HU-1 was originated from a two-years old boy and H22-3 was originated from a newly-born infant. HU-1 and H22-3 had the same morphology(short rod) when examined by scanning electron microscope, and the same biochemical traits including growth temperature range, salt tolerance and sugar-fermenting abilities. But the growth-inhibition spectrum and plasmid profiles of HU-1 and H22-3 were different. Both strains inhibited the growth of various Gram (+) microorganisms including Listeria monocytogenes. Micrococcus luteus, and Staphylococcus aureus in addition to many species of lactic acid bacteria, indicating the production of broad-spectrum bacteriocins. Bacteriocins produced by HU-1 and H22-3 were stable up to 90℃, 15 min heat treatments. Their activities were not affected by pepsin or trypsin treatments but destroyed by proteinaseK or pronase treatments.

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Electrochemical Behavior of Mordant Red 19 and its Complexes with Light Lanthanides

  • Sang Kwon Lee;Taek Dong Chung;Song-Ju Lee;Ki-Hyung Chjo;Young Gu Ha;Ki-Won Cha;Hasuck Kim
    • Bulletin of the Korean Chemical Society
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    • 제14권5호
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    • pp.567-574
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    • 1993
  • Mordant Red 19(MR19) is reduced at mercury electrode at -0.67 V vs. Ag/AgCl with two electrons per molecule in pH 9.2 buffer by differential pulse polarography and linear sweep voltammetry. The peak potential is dependent on the pH of solution. The exhaustive electrolysis, however, gives 4 electrons per molecule because of the disproportionation of the unstable hydrazo intermediate. The electrochemical reduction of lanthanide-MR19 complexes is observed at more cathodic potential than that of free ligand. The difference in peak potentials between complex and free ligand varies from 75 mV for $La^{3+}$ to 165 mV for $Tb^{3+}$ and increases with increasing the atomic number of lanthanide. The electrochemical reduction of lanthanide complexes with MR19 is due to the reduction of ligand itself, and it can be potentially useful as an indirect method for the determination of lanthanides. The shape of i-E curves and the scan rate dependence indicates the presence of adsorption and the adsorption was confirmed by potential double-step chronocoulometry and the effect of standing time. Also the surface excess of the adsorbed species and diffusion coefficients are determined. The composition of the complex is determined to be 1 : 2 by spectrophotometric and electrochemical methods.

FO-WLP (Fan Out-Wafer Level Package) 차세대 반도체 Packaging용 Isocyanurate Type Epoxy Resin System의 경화특성연구 (Cure Properties of Isocyanurate Type Epoxy Resin Systems for FO-WLP (Fan Out-Wafer Level Package) Next Generation Semiconductor Packaging Materials)

  • 김환건
    • 반도체디스플레이기술학회지
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    • 제18권1호
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    • pp.65-69
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    • 2019
  • The cure properties of ethoxysilyl diglycidyl isocyanurate(Ethoxysilyl-DGIC) and ethylsilyl diglycidyl isocyanurate (Ethylsilyl-DGIC) epoxy resin systems with a phenol novolac hardener were investigated for anticipating fan out-wafer level package(FO-WLP) applications, comparing with ethoxysilyl diglycidyl ether of bisphenol-A(Ethoxysilyl-DGEBA) epoxy resin systems. The cure kinetics of these systems were analyzed by differential scanning calorimetry with an isothermal approach, and the kinetic parameters of all systems were reported in generalized kinetic equations with diffusion effects. The isocyanurate type epoxy resin systems represented the higher cure conversion rates comparing with bisphenol-A type epoxy resin systems. The Ethoxysilyl-DGIC epoxy resin system showed the highest cure conversion rates than Ethylsilyl-DGIC and Ethoxysilyl-DGEBA epoxy resin systems. It can be figured out by kinetic parameter analysis that the highest conversion rates of Ethoxysilyl-DGIC epoxy resin system are caused by higher collision frequency factor. However, the cure conversion rate increases of the Ethylsilyl-DGEBA comparing with Ethoxysilyl-DGEBA are due to the lower activation energy of Ethylsilyl-DGIC. These higher cure conversion rates in the isocyanurate type epoxy resin systems could be explained by the improvements of reaction molecule movements according to the compact structure of isocyanurate epoxy resin.

Numerical simulation of single-phase two-components flow in naturally fractured oil reservoirs

  • Debossam, Joao Gabriel Souza;dos Santos Heringer, Juan Diego;de Souza, Grazione;Souto, Helio Pedro Amaral
    • Coupled systems mechanics
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    • 제8권2호
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    • pp.129-146
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    • 2019
  • The main goal of this work is to develop a numerical simulator to study an isothermal single-phase two-component flow in a naturally fractured oil reservoir, taking into account advection and diffusion effects. We use the Peng-Robinson equation of state with a volume translation to evaluate the properties of the components, and the discretization of the governing partial differential equations is carried out using the Finite Difference Method, along with implicit and first-order upwind schemes. This process leads to a coupled non-linear algebraic system for the unknowns pressure and molar fractions. After a linearization and the use of an operator splitting, the Conjugate Gradient and Bi-conjugated Gradient Stabilized methods are then used to solve two algebraic subsystems, one for the pressure and another for the molar fraction. We studied the effects of fractures in both the flow field and mass transport, as well as in computing time, and the results show that the fractures affect, as expected, the flow creating a thin preferential path for the mass transport.

Numerical simulation of the flow in pipes with numerical models

  • Gao, Hongjie;Li, Xinyu;Nezhad, Abdolreza Hooshmandi;Behshad, Amir
    • Structural Engineering and Mechanics
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    • 제81권4호
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    • pp.523-527
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    • 2022
  • The objective of this study is to simulate the flow in pipes with various boundary conditions. Free-pressure fluid model, is used in the pipe based on Navier-Stokes equation. The models are solved by using the numerical method. A problem called "stability of pipes" is used in order to compare frequency and critical fluid velocity. When the initial conditions of problem satisfied the instability conditions, the free-pressure model could accurately predict discontinuities in the solution field. Employing nonlinear strains-displacements, stress-strain energy method the governing equations were derived using Hamilton's principal. Differential quadrature method (DQM) is used for obtaining the frequency and critical fluid velocity. The results of this paper are analyzed by hyperbolic numerical method. Results show that the level of numerical diffusion in the solution field and the range of well-posedness are two important criteria for selecting the two-fluid models. The solutions for predicting the flow variables is approximately equal to the two-pressure model 2. Therefore, the predicted pressure changes profile in the two-pressure model is more consistent with actual physics. Therefore, in numerical modeling of gas-liquid two-phase flows in the vertical pipe, the present model can be applied.

Numerical calculations for bioconvection MHD Casson nanofluid flow: Study of Brownian motion

  • Hussain, Muzamal;Sharif, Humaira;Khadimallah, Mohamed Amine;Ayed, Hamdi;Banoqitah, Essam Mohammed;Loukil, Hassen;Ali, Imam;Mahmoud, S.R.;Tounsi, Abdelouahed
    • Computers and Concrete
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    • 제30권2호
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    • pp.143-150
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    • 2022
  • In this paper, the non-linear mathematical problem is solved via numerical scheme by utilizing shooting method. Brownian diffusion and thermophoresis along mass and heat transfer are accounted for. Non-linear expression is reduced via non-dimensional variables. The simplified ordinary differential equations are tackled by shooting technique. Behavior of distinct influential parameters is investigated graphically and analyzed for temperature and concentration profile. Our finding indicates that temperature profile is enhanced for the thermophoresis, Brownian motion coefficient, Prandtl number, Eckert number and temperature slip parameter. Comparison of numerical technique with the extant literature is made and an acceptable agreement is attained. Graphs are plotted to examine the influence of these parameters.

Wind-induced random vibration of saddle membrane structures: Theoretical and experimental study

  • Rongjie Pan;Changjiang Liu;Dong Li;Yuanjun Sun;Weibin Huang;Ziye Chen
    • Wind and Structures
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    • 제36권2호
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    • pp.133-147
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    • 2023
  • The random vibration of saddle membrane structures under wind load is studied theoretically and experimentally. First, the nonlinear random vibration differential equations of saddle membrane structures under wind loads are established based on von Karman's large deflection theory, thin shell theory and potential flow theory. The probabilistic density function (PDF) and its corresponding statistical parameters of the displacement response of membrane structure are obtained by using the diffusion process theory and the Fokker Planck Kolmogorov equation method (FPK) to solve the equation. Furthermore, a wind tunnel test is carried out to obtain the displacement time history data of the test model under wind load, and the statistical characteristics of the displacement time history of the prototype model are obtained by similarity theory and probability statistics method. Finally, the rationality of the theoretical model is verified by comparing the experimental model with the theoretical model. The results show that the theoretical model agrees with the experimental model, and the random vibration response can be effectively reduced by increasing the initial pretension force and the rise-span ratio within a certain range. The research methods can provide a theoretical reference for the random vibration of the membrane structure, and also be the foundation of structural reliability of membrane structure based on wind-induced response.

EFFECTS OF RADIATION AND HEAT GENERATION ON MHD AND PARABOLIC MOTION ON CASSON FLUIDS FLOW THROUGH A ROTATING POROUS MEDIUM IN A VERTICAL PLATE

  • J. PRAKASH;A. SELVARAJ
    • Journal of applied mathematics & informatics
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    • 제42권3호
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    • pp.607-623
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    • 2024
  • This article studies the effects of heat generation/absorption and thermal radiation on the unsteady magnetohydrodynamic (MHD) Casson fluid flow past a vertical plate through rotating porous medium with constant temperature and mass diffusion. It is assumed that the plate temperature and concentration level are raised uniformly. For finding the exact solution, a set of non-dimensional partial differential equations is solved analytically using the Laplace transform technique. The influence of various non-dimensional parameters on the velocity are discussed, including the effects of the magnetic parameter M, heat generation/absorption Q, thermal radiation parameter R, Prandtl number Pr, Schmidt number Sc, permeability of porous medium parameter, Casson fluid parameter γ, on velocity, temperature, and concentration profiles, which are discussed through several figures. It is found that velocity, temperature, and concentration profiles in the case of heat generation parameter Q, Casson fluid parameter γ, thermal Grashof number Gr, mass Grashof number Gc, Permeability Porous medium parameter K, and time t have retarding effects. It is also seen that the magnetic field M, Thermal Radiation parameter R, Prandtl field Pr, Schmidt number Sc have reverse effects on it.