• Title/Summary/Keyword: Differential diffusion

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The Precipitation Phenomena of Al-2.1Li-2.9Cu alloy by Differential Scanning Calorimetry(I) - Precipitation sequence - (열분석법에 의한 Al-2.1Li-2.9Cu합금의 석출현상(I) - 석출순서 -)

  • Park, Tae-Won
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.4
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    • pp.252-260
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    • 1996
  • A study was conducted to examine the precipitation phenomena of Al-2.1Li-2.9Cu alloy by differential scanning calorimetry and transmission electron microscopy. DSC curves were measured over the temperature range of $25{\sim}550^{\circ}C$ at a heating rate of $2{\sim}20^{\circ}C$/min.. Three heat evolution peaks and three heat absorption peaks were observed in the DSC curve for the as-quenched specimen. From DSC results and TEM analysis, it was proved that the precipitation sequence in the as-quenched specimen is supersaturated solid solution ${\rightarrow}$ GP zone ${\rightarrow}{\delta}^{\prime}{\rightarrow}T_1{\rightarrow}T_2$ and ${\theta}^{\prime}$ was detected in the peak aged specimen at $160^{\circ}C$. The major phase formed at peak hardeness in the aging at $160^{\circ}C$ was ${\delta}^{\prime}$ phase. The activation energies for the formation of ${\delta}^{\prime}$ and $T_1$ phases were 22.3kcal/mole and 24.3kcal/mole, respectively. These lower activation energies than those for diffusion of Cu and Li in Al are ascribed to the quenched-in excess vacancies.

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An Efficient Chaotic Image Encryption Algorithm Based on Self-adaptive Model and Feedback Mechanism

  • Zhang, Xiao;Wang, Chengqi;Zheng, Zhiming
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.11 no.3
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    • pp.1785-1801
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    • 2017
  • In recent years, image encryption algorithms have been developed rapidly in order to ensure the security of image transmission. With the assistance of our previous work, this paper proposes a novel chaotic image encryption algorithm based on self-adaptive model and feedback mechanism to enhance the security and improve the efficiency. Different from other existing methods where the permutation is performed by the self-adaptive model, the initial values of iteration are generated in a novel way to make the distribution of initial values more uniform. Unlike the other schemes which is on the strength of the feedback mechanism in the stage of diffusion, the piecewise linear chaotic map is first introduced to produce the intermediate values for the sake of resisting the differential attack. The security and efficiency analysis has been performed. We measure our scheme through comprehensive simulations, considering key sensitivity, key space, encryption speed, and resistance to common attacks, especially differential attack.

A Study on the Prediction of Indoor Environment in Bio Safety Level 3 Laboratory According to Biohazard Scenario (생물안전 3등급(BSL3)시설의 생물재해 시나리오에 따른 실내 공기환경예측에 관한 연구)

  • Park, Hyun-Jin;Hong, Jin-Kwan
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.11
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    • pp.745-750
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    • 2010
  • Since the implementation of the LMO Law in Korea, the importance of the design qualification of BSL3 lab. is emphasizing. In this study, multizone simulation for three kind of biohazard scenarios using CONTAM is performed for design qualification of BSL3 lab. Also, in the case of unexpected spread of contaminants such as Influenza A virus(H1N1) in BL3 zone, the design qualification is carried out for diffusion and decontamination of contaminants according to differential pressure of BSL3 anteroom and door area of BSL3 lab. Also, in this study, appropriateness of laboratory room differential pressure and air flow rate to maintain pressure difference between laboratory rooms, and energy consumption due to air change rate variation according to door area in BL3 lab. Simulation results show that these approach methods are used as a tool for the design and verification of BL3 lab.

Cure Kinetics and Dynamic Mechanical Properties of an Epoxy/Polyoxypropylene Diamine System (에폭시/폴리옥시프로필렌 디아민계의 경화 반응속도 및 동역학 특성 분석)

  • Huang, Guang-Chun;Lee, Jong-Keun
    • Polymer(Korea)
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    • v.35 no.3
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    • pp.196-202
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    • 2011
  • The cure kinetics of a bisphenol A epoxy resin and polyoxypropylene diamine curing agent system are investigated in both dynamic and isothermal conditions by differential scanning calorimetry (DSC). In dynamic experiments, the shift of exothermic peaks obtained at different heating rates is used to obtain activation energy of overall cure reaction based on the methods of Ozawa and Kissinger. Isothermal DSC data at different temperatures are fitted to an autocatalytic Kamal kinetic model. The kinetic model is in a good agreement with the experimental data in the initial stage of cure. A diffusion effect is incorporated to describe the later stage of cure, predicting the cure kinetics over the whole range of curing process. Also, dynamic mechanical analysis is performed to evaluate the storage modulus and average molecular weight between crosslinkages.

Column Shortening of SRC Columns Considering the Differential Moisture Distribution (부등수분분포를 고려한 SRC 기둥의 축소량에 관한 연구)

  • Seol, Hyun-Cheol;Kim, Yun-Yong;Kwon, Seung-Hee;Kim, Han-Soo;Kim, Jin-Keun
    • Journal of the Korea Concrete Institute
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    • v.18 no.1 s.91
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    • pp.29-36
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    • 2006
  • Steel reinforced concrete(SRC) columns, which have been widely employed in high-rise buildings, exhibit a time-dependent behavior because of creep and shrinkage of concrete. This long-term behavior may cause a serious serviceability problem in structural systems, so it is very important to predict the deformation due to creep and shrinkage of concrete. However, it was found from the previous experimental studies that the long-term deformation of SRC columns was quite dissimilar from that of RC columns. A new method is required to quantitatively predict the long-term deformation of SRC columns. In this study, the causes of the discrepancy between the behaviors of RC and SRC columns are investigated and discussed. SRC columns exhibit a time-dependent relative humidity distribution in a cross section differently from that of reinforced concrete(RC) columns owing to the presence of a inner steel plate, which interferes with the moisture diffusion of concrete. This relative humidity distribution may reduce the drying shrinkage and the drying creep in comparison with RC columns. Therefore it is suggested that the differential moisture distribution should be taken into account in order to reasonably predict column shortening of SRC columns.

Dynamic Model of a Passive Air-Breathing Direct Methanol Fuel Cell (수동급기 직접 메탄올 연료전지의 동적 모델)

  • Ha, Seung-Bum;Chang, Ikw-Hang;Cha, Suk-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.33-36
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    • 2008
  • The transient behavior of a passive air breathing direct methanol fuel cell (DMFC) operated on vapor-feeding mode is studied in this paper. It generally takes 30 minutes after starting for the cell response to come to its steady-state and the response is sometimes unstable. A mathematical dynamic one-dimensional model for simulating transient response of the DMFC is presented. In this model a DMFC is decomposed into its subsystems using lumped model and divided into five layers, namely the anodic diffusion layer, the anodic catalyst layer, the proton exchange membrane (PEM), the cathodic catalyst layer and the cathodic diffusion layer. All layers are considered to have finite thickness, and within every one of them a set of differential-algebraic governing equations are given to represent multi-components mass balance, such as methanol, water, oxygen and carbon dioxide, charge balance, the electrochemical reaction and mass transport phenomena. A one-dimensional, isothermal and mass transport model is developed that captures the coupling between water generation and transport, oxygen consumption and natural convection. The single cell is supplied by pure methanol vapor from a methanol reservoir at the anode, and the oxygen is supplied via natural air-breathing at the cathode. The water is not supplied from external source because the cell uses the water created at the cathode using water back diffusion through nafion membrane. As a result of simulation strong effects of water transport were found out. The model analysis provides several conclusions. The performance drop after peak point is caused by insufficiency of water at the anode. The excess water at the cathode makes performance recovery impossible. The undesired crossover of the reactant methanol through the PEM causes overpotential at the cathode and limits the feeding methanol concentration.

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A Study on the Differences of Information Diffusion Based on the Type of Media and Information (매체와 정보유형에 따른 정보확산 차이에 대한 연구)

  • Lee, Sang-Gun;Kim, Jin-Hwa;Baek, Heon;Lee, Eui-Bang
    • Journal of Intelligence and Information Systems
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    • v.19 no.4
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    • pp.133-146
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    • 2013
  • While the use of internet is routine nowadays, users receive and share information through a variety of media. Through the use of internet, information delivery media is diversifying from traditional media of one-way communication, such as newspaper, TV, and radio, into media of two-way communication. In contrast of traditional media, blogs enable individuals to directly upload and share news, which can be considered to have a differential speed of information diffusion than news media that convey information unilaterally. Therefore this Study focused on the difference between online news and social media blogs. Moreover, there are variations in the speed of information diffusion because that information closely related to one person boosts communications between individuals. We believe that users' standard of evaluation would change based on the types of information. As well, the speed of information diffusion would change based on the level of proximity. Therefore, the purpose of this study is to examine the differences in information diffusion based on the types of media. And then information is segmentalized and an examination is done to see how information diffusion differentiates based on the types of information. This study used the Bass diffusion model, which has been frequently used because this model has higher explanatory power than other models by explaining diffusion of market through innovation effect and imitation effect. Also this model has been applied a lot in other information diffusion related studies. The Bass diffusion model includes an innovation effect and an imitation effect. Innovation effect measures the early-stage impact, while the imitation effect measures the impact of word of mouth at the later stage. According to Mahajan et al. (2000), Innovation effect is emphasized by usefulness and ease-of-use, as well Imitation effect is emphasized by subjective norm and word-of-mouth. Also, according to Lee et al. (2011), Innovation effect is emphasized by mass communication. According to Moore and Benbasat (1996), Innovation effect is emphasized by relative advantage. Because Imitation effect is adopted by within-group influences and Innovation effects is adopted by product's or service's innovation. Therefore, ours study compared online news and social media blogs to examine the differences between media. We also choose different types of information including entertainment related information "Psy Gentelman", Current affair news "Earthquake in Sichuan, China", and product related information "Galaxy S4" in order to examine the variations on information diffusion. We considered that users' information proximity alters based on the types of information. Hence, we chose the three types of information mentioned above, which have different level of proximity from users' standpoint, in order to examine the flow of information diffusion. The first conclusion of this study is that different media has similar effect on information diffusion, even the types of media of information provider are different. Information diffusion has only been distinguished by a disparity between proximity of information. Second, information diffusions differ based on types of information. From the standpoint of users, product and entertainment related information has high imitation effect because of word of mouth. On the other hand, imitation effect dominates innovation effect on Current affair news. From the results of this study, the flow changes of information diffusion is examined and be applied to practical use. This study has some limitations, and those limitations would be able to provide opportunities and suggestions for future research. Presenting the difference of Information diffusion according to media and proximity has difficulties for generalization of theory due to small sample size. Therefore, if further studies adopt to a request for an increase of sample size and media diversity, difference of the information diffusion according to media type and information proximity could be understood more detailed.

Diffusion-Weighted Imaging for the Left Hepatic Lobe has Higher Diagnostic Accuracy for Malignant Focal Liver Lesions

  • Han, Xue;Dong, Yin;Xiu, Jian-Jun;Zhang, Jie;Huang, Zhao-Qin;Cai, Shi-Feng;Yuan, Xian-Shun;Liu, Qing-Wei
    • Asian Pacific Journal of Cancer Prevention
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    • v.15 no.15
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    • pp.6155-6160
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    • 2014
  • Background: This study was conducted to investigate whether apparent diffusion coefficient (ADC) measurements by dividing the liver into left and right hepatic lobes may be utilized to improve the accuracy of differential diagnosis of benign and malignant focal liver lesions. Materials and Methods: A total of 269 consecutive patients with 429 focal liver lesions were examined by 3-T magnetic resonance imaging that included diffusion-weighted imaging. For 58 patients with focal liver lesions of the same etiology in left and right hepatic lobes, ADCs of normal liver parenchyma and focal liver lesions were calculated and compared using the paired t-test. For all 269 patients, ADC cutoffs for focal liver lesions and diagnostic accuracy in the left hepatic lobe, right hepatic lobe and whole liver were evaluated by receiver operating characteristic curve analysis. Results: For the group of 58 patients, mean ADCs of normal liver parenchyma and focal liver lesions in the left hepatic lobe were significantly higher than those in the right hepatic lobe. For differentiating malignant lesions from benign lesions in all patients, the sensitivity and specificity were 92.6% and 92.0% in the left hepatic lobe, 94.4% and 94.4% in the right hepatic lobe, and 90.4% and 94.7% in the whole liver, respectively. The area under the curve of the right hepatic lobe, but not the left hepatic lobe, was higher than that of the whole liver. Conclusions: ADCs of normal liver parenchyma and focal liver lesions in the left hepatic lobe were significantly higher than those in the right hepatic lobe. Optimal ADC cutoff for focal liver lesions in the right hepatic lobe, but not in the left hepatic lobe, had higher diagnostic accuracy compared with that in the whole liver.

Silicide Formation by Solid State Diffusion in Mo/Si Multilayer Thin Films (Mo/Si 다층박막에서의 고상확산에 의한 실리사이드 생성에 관한 연구)

  • 지응준;곽준섭;심재엽;백홍구
    • Journal of the Korean Vacuum Society
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    • v.2 no.4
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    • pp.507-514
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    • 1993
  • The solid state reaction of Mo/Si multilayer thin films produced by RF magnetron sputtering technique was examine dusing differential scanning calorimetry (DSC) and x-ray diffraction, and explained in view of two concepts, effective drivig force and effective heat of formation. In constant scanning rate DSC, there were two exothermic peks which corresponded to the formation of h-MoSi2 and t-MoSi2 , respectively. The activation energyfor theformation of h-MoSi2 was 1.5eV , and that of t-MoSi2 was 7.8eV. Nucleation wa stherate controlling mechanism for each of the silicide formation. Amorphous phase was not formed , which was consistent withtheprediction by the concept of effective driving force. h-MoSi2 the first crystalline phase, was considered to have lower interfacial free energy than t-MoSi2 and by increasing temperature it was transformed into more stable t-MoSi2.

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A study on Sintering Characteristics of Commercial 7xxx Series Al Alloy Powders (상용 7xxx Series Al 합금계 혼합분말의 소결 특성)

  • ;;;Panyu
    • Journal of Powder Materials
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    • v.11 no.1
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    • pp.69-73
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    • 2004
  • The sintering characteristics of commercial 7xxx series Al-Zn-Mg-Cu alloy have been investigated. Sintering system of this blended elemental powder has aspects of both transient and supersolidus liquid phase sintering. Transient liquids occur when the constitution point during sintering lies in a solid phase region but where the sintering temperature is greater than either the melting point of one of the constituent or a eutectic temperature. Supersolidus liquid phase sintering occurs when a preblended powder is heated to a temperature between the solidus and liquids. However, these reaction were restrained their inter diffusion due to the appearance of the oxide film. Thus, 7xxx series Al alloy is extremely sensitive to process variables, including particle size, holding time and sintering temperature. Therefore, above phenomenons were observed formation and behaviour of the liquid by using SEM and DSC.