• Title/Summary/Keyword: Different metal

Search Result 3,345, Processing Time 0.027 seconds

A Study On Heavy Metal Contamination in the Different Size Fractions of Deposited Road Particles(DRPs) (노면퇴적물의 입자 크기에 따른 중금속 오염에 관한 연구)

  • Kim, Boo-Gil;Lee, Byung-Cheol
    • Journal of Environmental Science International
    • /
    • v.15 no.12
    • /
    • pp.1171-1175
    • /
    • 2006
  • Deposited road particles (DRPs) were analysed for heavy metal concentrations at four different roads in a city, Korea. The samples were collected using a roadway surface vacuum cleaning vehicle which was commonly used in collecting roadway surface particles. Six particle size ranges were analyzed separately for twelve heavy metal elements (Cd, Cr, Pb, Ni, Al, As, Co, Cu, Fe, Mn, Zn and Hg). At all sampling sites, the high concentration of the heavy metals occurred in the <74um particle size range, which conventional roadway cleaning vehicles do not remove efficiently. The Pb concentration significantly increased with decreasing particle size of DRPs, and other toxic heavy metals (Cd, Cr and Ni) also showed similar results. The heavy metal concentrations in the smaller size fraction of DRPs is important because they are contaminants that are preferentially transported by road runoff during rainfall.

A Study on the Sterilization of Sea Water using Redox Reaction (Redox 반응을 이용한 해수 살균에 대한 연구)

  • Song, Ju-Yeong;Kim, Jong-Hwa
    • Journal of the Korean Applied Science and Technology
    • /
    • v.28 no.1
    • /
    • pp.29-34
    • /
    • 2011
  • The sterilization of strain and algae in sea water was studied to see the possibility to apply the redox reaction of metal alloy to meet the international marine organization(IMO) regulation, which was to regulate deballasting concentration of strain and algae above 99% of sterilization. Two different kinds of brass were heat treated at different temperature and cooled rapidly to conserve the specific character of ${\beta}$ brass. Untreated Muntz metal showed the best result of antimicrobial rate in sea water, and 7:3 brass showed similar result to Muntz metal. Heavy metal elution rate was inversely proportional to the sterilization capability.

A Performance Study of Portable Hydrogen Storage Tank (휴대용 수소 저장체 성능 특성 연구)

  • Park, Joon-Ho;Hwang, Yong-Sheen;Jee, Sang-Hoon;Kim, Sung-Han;Cha, Suk-Won
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2009.06a
    • /
    • pp.315-318
    • /
    • 2009
  • Hydrogen is the ideal candidate as an alternative energy carrier, so many hydrogen storage methods are investigated. The hydrogen storage method using metal hydride is good candidate as energy sources for portable devices because hydrogen-storage as metal hydride shows large volumetric storage density. In this study, we investigated the variations of hydrogen charging/discharging performance of metal hydride tanks at different temperature conditions. We charged metal hydride tanks with hydrogen in low temperature because of the exothermic reactions of hydrogen absorption while we discharged in high temperature to provide sufficient heat because of the endothermic reactions of desorption. In addition, we investigated the difference of hydrogen charging/discharging performance between two tanks having different sizes.

  • PDF

Synthesis of Poly(N-methylol Methacrylamide/Vinyl Sulfonic Acid) Hydrogels for Heavy Metal Ion Removal

  • Yakar, Arzu
    • Bulletin of the Korean Chemical Society
    • /
    • v.35 no.10
    • /
    • pp.3063-3070
    • /
    • 2014
  • In this study, poly(N-methylol methacrylamide) (NMMAAm) and poly(N-methylol methacrylamide/vinyl sulphonic acid) (NMMAAm-VSA) hydrogels were synthesized by $^{60}Co-{\gamma}$ ray irradiation at an ambient temperature. The graphs belonging to the gelation percent- percent-dose and swelling curves were drawn by using data which were obtained from water and different pH solutions. Characterization of hydrogels was performed by FTIR and DSC-TGA analysis. Heavy metal ion ($Ni^{2+}$, $Co^{2+}$) removal capacities of hydrogels were investigated in aqueous solutions, which had different concentrations (100-1500 mg/L). In metal ion removal studies, pH value of aqueous medium was kept constant at 5.0. Maximum metal ion removal values were obtained for NMMAAm-VSA (1:3 mole ratio) hydrogels. Metal ion removal capacities of NMMAAm-VSA (1:3 mole ratio) hydrogels were found as 82 mg/g and 98 mg/g for $Ni^{2+}$ and $Co^{2+}$ ions, respectively.

Electrical Properties by different method of metal complex of G4-48PyP Dendrimer (금속이온 착체방법에 의한 G4-48PyP 덴드리머의 전기적 특성)

  • Kim, S.U.;Jung, S.B.;Kim, C.;Park, J.C.;Chang, J.S.;Kwon, Y.S.
    • Proceedings of the KIEE Conference
    • /
    • 2003.07c
    • /
    • pp.1532-1534
    • /
    • 2003
  • We attempted to fabricate a dendrimer Langmuir-Blodgett(LB) films containing 48 pyridinepropanol functional end group. As the pyridinepropanol functional group could form a complex structure with metal ions. In this study the samples for electrical measurement were fabricated to two types metal complexes with $Pt^{4+}$ ions by LB method. And we have investigated the surface activity at the air-water interface as well as the electrical properties for the monolayers of G4-48PyP dendrimer complex with metal ions($Pt^{4+}$ ions) by different method. In the surface pressure-area(${\pi}$-A) isotherms of the dendrimers, the stable condensed films formed at the air-water interface and the different method of metal complex showed the difference on molecular behavior. We have studied the electrical properties of the ultra thin dendrimer LB films investigated by the current-voltage (I-V) characteristics of metal/dendrimer LB films/metal(MIM) structure. In conclusion, it is demonstrated that the metal ion around G4-48PyP dendrimer can contribute to make formation of network structure among dendrimers and it result from the change of electrical properties.

  • PDF

Cadmium and zinc removal from water by polyelectrolyte enhanced ultrafiltration

  • Ennigrou, Dorra Jellouli;Ali, Mourad Ben Sik;Dhahbi, Mahmoud;Mokhtar, Ferid
    • Membrane and Water Treatment
    • /
    • v.5 no.3
    • /
    • pp.183-195
    • /
    • 2014
  • The efficiency of two metal ions (cadmium, zinc) removal from aqueous solutions by ultrafiltration (UF) and Polymer Enhanced Ultrafiltration (PEUF) processes were investigated in this work. The UF and PEUF studies were carried out using an ultrafiltration tangential cell system equipped with 5.000 MWCO regenerated cellulose. A water-soluble polymer: the polyacrylic acid (PAA) was used as complexant for PEUF experiments. The effects of transmembrane pressure, pH, metal ions and loading ratio on permeate fluxes and metal ions removals were evaluated. In UF process, permeate fluxes increase linearly with increasing pH for different transmembrane pressure, which may be the consequence of the formation of soluble metal hydroxyl complexes in the aqueous phase. In PEUF process, above pH 5.0, the Cd(II) retention reaches a plateau at 90% and Zn(II) at 80% for L = 5. Also, cadmium retention at different L is greater than zinc retention at pH varying from 5.0 to 9.0. In a mixture solution, cadmium retention is higher than zinc for different loading ratio, this is due to interactions between carboxylic groups of PAA and metal ions and more important with cadmium ions.

The Low Cycle Fatigue Behavior of Laser Welded Sheet Metal for Different Materials (이종재료 레이저 용접 판재의 저주기 피로 특성)

  • Kim Seog-Hwan;Kwak Dai-Soon;Kim Woong-Chan;Oh Taek-Yul
    • Proceedings of the Korean Society of Precision Engineering Conference
    • /
    • 2005.10a
    • /
    • pp.627-631
    • /
    • 2005
  • In this study, low fatigue behavior of laser welded sheet metal were investigated. Before welding, the cross section of butt joint was prepared only by fine shearing without milling process. Specimens were same sheet metal and welding condition that using automobile manufacturing company at present. Butt joint of cold rolled sheet metal was welded by $CO_2$ laser. It is used that welding condition such as laser welding speed was 5.5m/sec and laser output power was 5kW for 0.8mm and 1.2mm sheet metal. The laser weldments were machined same or different thickness and same or different material. In order to mechanical properties of around welding zone, hardness test was performed. Hardness of welding bead is about 2 times greater than base material. We performed the low cycle fatigue tests for obtaining fatigue properties about thickness and the weld line direction of specimen. The results of strain controlled low cycle fatigue test indicate that all specimens occur cyclic softening, as indicated by the decrease in stress to reach a prescribed strain.

  • PDF

Environment-dependent Broadband Perfect Absorption of Metal-insulator-metal Metamaterial Systems

  • Feng Li;Yulong Tang;Qingsong Peng;Guosheng Hu
    • Current Optics and Photonics
    • /
    • v.7 no.2
    • /
    • pp.136-146
    • /
    • 2023
  • Based on calculations using the macroscopic Maxwell's equations with mesoscopic boundary conditions, light absorption by a layered metal-insulator-metal (MIM) metamaterial system embedded in three different environments is investigated. Increasing the top metal thickness shifts the broad absorption band to lower dielectric-constant regions and longer wavelengths, for either TM or TE waves. Boosting the dielectric-layer thickness redshifts the broadband absorption to regions of larger dielectric constant. In air, for the dielectric-constant range of 0.86-3.40, the absorption of the system exceeds 98% across 680-1,033 nm. In seawater with optimized dielectric constant, ≥94% light absorption over 400-1,200 nm can be achieved; particularly in the wavelength range of 480-960 nm and dielectric-constant range of 0.82-3.50, the absorption is greater than 98%. In an environment with even higher refractive index (1.74), ≥98% light absorption over 400-1,200 nm can be achieved, giving better performance. The influence of angle of incidence on light absorption of the MIM system is also analyzed, and the angle tolerance for ≥90% broadband absorption of a TM wave is up to 40° in an environment with large refractive index. While the incident-angle dependence of the absorption of a TE wave is nearly the same for different circumstances, the situation is different for a TM wave.

Antimicrobial Activities of Nano Metal Hybrid Materials against the Microorganisms Isolated from Cucurbit Seeds (나노 금속복합체의 박과 작물 종자 분리균에 대한 항균효과)

  • Kim, Sang Woo;Gwon, Byeong Heon;Ju, Han Jun;Adhikari, Mahesh;Park, Mi-ri;Song, Seok-Kyun;Lee, Youn Su
    • Research in Plant Disease
    • /
    • v.25 no.4
    • /
    • pp.179-187
    • /
    • 2019
  • This study was carried out to test the antimicrobial activities of nano metal hybrid materials produced by plasma technologies (radio frequency-thermal plasma system and direct current sputtering system) against microbes isolated from cucurbit (watermelon, pumpkin, and gourd) seeds. Eight different nano metal hybrid materials and four carriers were tested against five different fungal and ten different bacterial isolates in vitro. Among the tested nano metal hybrid material, Brass/CaCO3 (1,000 ppm) exhibited 100% antimicrobial effect against all the five tested fungi. However, nano metal hybrid material Brass/CaCO3 (1,000 ppm) inhibited only four bacterial isolates, Weissella sp., Rhodotorula mucilaginosa, Burkholderia sp., and Enterococcus sp. at 100% level, and did not inhibited other six bacterial isolates. Nano metal hybrid material graphite-nickel (G-Ni) showed 100% inhibition rate against Rhizopus stolonifer and 52.94-71.76% inhibition rate against four different fungal isolates. Nano metal hybrid material G-Ni did not show any inhibition effects against tested ten bacterial isolates. In summary, among the tested eight different nano metal hybrid materials and four carriers, Brass/CaCO3 showed inhibition effects against five fungal isolates and four bacterial isolates, and G-Ni showed variable inhibition effects (52.94-100%) against five fungal isolates and did not show any inhibition effects against all the bacterial isolates.

Short Channel Analytical Model for High Electron Mobility Transistor to Obtain Higher Cut-Off Frequency Maintaining the Reliability of the Device

  • Gupta, Ritesh;Aggarwal, Sandeep Kumar;Gupta, Mridula;Gupta, R.S.
    • JSTS:Journal of Semiconductor Technology and Science
    • /
    • v.7 no.2
    • /
    • pp.120-131
    • /
    • 2007
  • A comprehensive short channel analytical model has been proposed for High Electron Mobility Transistor (HEMT) to obtain higher cut-off frequency maintaining the reliability of the device. The model has been proposed to consider generalized doping variation in the directions perpendicular to and along the channel. The effect of field plates and different gate-insulator geometry (T-gate, etc) have been considered by dividing the area between gate and the high band gap semiconductor into different regions along the channel having different insulator and metal combinations of different thicknesses and work function with the possibility that metal is in direct contact with the high band gap semiconductor. The variation obtained by gate-insulator geometry and field plates in the field and channel potential can be produced by varying doping concentration, metal work-function and gate-stack structures along the channel. The results so obtained for normal device structure have been compared with previous proposed model and numerical method (finite difference method) to prove the validity of the model.