• Journal of the Korean Wood Science and Technology
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• v.20 no.3
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• pp.55-60
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• 1992

Japanese red pine (Pinus densiflora S. et. Z.) decayed by brown-rot fungi Tyromyces palustris and Gloeophyllum trabeum were subjected to X-ray diffraction analysis and infrared spectral examinations. Pine woods decayed by T. palustris showed the increase of relative crystallinity in the initial stage of degradation. When the weight loss was above 30%, then the crystallinity went down slowly. In contrast, the wood samples degraded by G. trabeum showed the decrease of crystallinity from the beginning stage of decay. The changes of crystallinity in brown-rotted woods suggested that the degradation rate of crystalline cellulose was varied with the brown rot fungal species. X-ray diffraction analyses also indicated that crystalline cellulose was much more slowly broken down than the amorphous one. The most notable difference in the IR spectra of the brown-rotted wood samples was that the adsorption band centered at 1,730$cm^{-1}$ was significantly diminished in the decayed wood. indicating the degradation of hemicellulose by brown-rot fungi. However, no marked changes of intensities at 1,000, 1,060 and 1,040$cm^{-1}$ were observed in the brown rotted wood samples, suggesting that crystal line cellulose was resistant against the attack by brown rot fungi.

• Journal of the Korean Chemical Society
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• v.18 no.3
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• pp.215-220
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• 1974

Conformations and cofigurations were studied for some ${\alpha},{\beta}$-unsaturated phenylhydrazones which have similar structures to the stucture of butenedial bistosylhydrazone, a precursor of tetrahedrane, by the analysis of their nmr spectra. The chemical shift difference between two solvents, benzene and aliphatic solvents, was applied for the assigning syn and anti structures of phenylhydrazone isomers as a convenient method. In this work, it was found that the phenylhydrazones have syn configurations and also found that the dihedral angles of $CH_a-CH_b$ are around $150^{\circ}$ at room temperature from the the interpretation of the vicinal spin-spin coupling constants. These results were discussed in concerning with their conformations.

• Journal of Radiation Protection and Research
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• v.45 no.1
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• pp.35-44
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• 2020

Background: Cadmium zinc telluride (CZT) is a promising material because of a high detection efficiency, good energy resolution, and operability at room temperature. However, the cost of CZT dramatically increases as its size increases. In this study, to achieve a large effective volume with relatively low cost, an array structure comprised of individual virtual Frisch-grid CZT detectors was proposed. Materials and Methods: The prototype consisted of 2 × 2 CZTs, a holder, anode and cathode printed circuit boards (PCBs), and an application-specific integrated circuit (ASIC). CZTs were used and the non-contacting shielding electrode method was applied for virtual Frisch-grid effect. An ASIC was used, and the holder and the PCBs were fabricated. In the current system, because the CZTs formed a common cathode, a total of 5 channels were assigned for data processing. Results and Discussion: An experiment using ¹³⁷Cs at room temperature was conducted for 10 minutes. Energy and timing information was acquired and the depth of interaction was calculated by the timing difference between the signals of both electrodes. Based on obtained three-dimensional position information, the energy correction was carried out, and as a result the energy spectra showed the improvements. In addition, a Compton image was reconstructed using the iterative method. Conclusion: The virtual Frisch-grid CZT detector based on the array structure was developed and the energy spectra and the Compton image were successfully acquired.

• International Journal of Ocean Engineering and Technology Speciallssue:Selected Papers
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• v.4 no.1
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• pp.51-55
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• 2001

The characteristics of elastic waves emanating from crack initiation in 2024 and 5052 aluminum alloys subject to static and fatigue loading are investigated through laboratory experiments. The objective of the study is to determine difference in the properties of the signals generated from static and fatigue tests and also to examine if the sources of the waves could be identified from the temporal and spectral characteristics of the acoustic emission (AE) waveforms. The signals are recoded using non-resonant, flat, broadband transducers attached to the surface of the alloy specimens. The time dependence and power spectra of the signals recorded during the tests were examined and classified according to their special features. Three distinct types of signals were observed. The waveforms and their power spectra were found to be dependent on the material and the type of fracture associated with the signals. Analysis of the waveforms indicated that some signals could be attributed to plastic deformation associated with static tests. The potential application of the approach in health monitoring of aging aircraft structures using a network of surface mounted broadband sensors is discussed.

• Journal of the Mineralogical Society of Korea
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• v.22 no.2
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• pp.81-86
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• 2009

The luminescence and fluorescence were investigated by photoluminescence spectroscopy for six gemstones which exhibit color change effect. The shape of luminescence peaks appears different when observed by a photoluminescence spectroscopewith a 514 nm Ar laser source. However, it was not possible to observe the difference in the spectra between the natural and synthetic origins for the same type of gemstones. It was found that the photoluminescence spectrum was related to the crystal structure of the stones. Photoluminescence spectra using a 325 nm He-Cd source reveal that fluorescence is relatively strong for synthetic alexandrite, synthetic color change sapphire and natural alexandrite comparing to the rest of gemstones examined.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.24 no.7
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• pp.569-574
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• 2014

In order to investigate low frequency swishing noise of wind turbines, acoustic source model using a singularity in circular motion is introduced to derive analytic solution of Lowson acoustic analogy in time domain. Results in time and frequency domains computed by the solution show apparent modulation of amplitude and frequency. The solution indicates that time histories of acoustic pressure at receiver points varied significantly according to receiver's directional location, even when the retarded time distributions are similar. However, the corresponding time-averaged spectra of sound pressure at the receiver locations where the retarded time distributions are almost same are not significantly different. It can be inferred from these results that the time-averaged sound pressure spectra which cannot take into account the detailed difference in the time-variation of wind turbine noise may not represent the sound quality of wind turbines due to its swishing. Finally, as an introduction of procedure to quantify low frequency swishing noise level, relative variation of overall sound pressure level is obtained using tonal low frequency noise model.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.29 no.12
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• pp.1-7
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• 2015

In this paper, we propose a second-order fiber flexible comb filter based on a polarization-diversity loop(PDL). The proposed filter consists of a polarization beam splitter, four half-wave plates(HWPs), and three high birefringence fiber(HBF) segments. In the previous Solc-type second-order filter based on the PDL, HBF segments were fusion-spliced with a fixed angle offset between their principal axes with each other. But, the proposed filter implemented by inserting two HWPs between three HBF segments has a great flexibility in adjusting relative angular difference between the principal axes of two adjacent HBF segments. Owing to this flexibility, second-order transmission spectra, which had a channel spacing of ~0.8nm, could be interleaved by controlling the orientation angles of four HWPs. The output transmission spectra of the proposed filter were theoretically analyzed and experimentally verified.

• Bulletin of the Korean Chemical Society
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• v.31 no.4
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• pp.999-1003
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• 2010

Raman spectra of a single layer graphene sheet placed in different gold substrates were obtained and are discussed in the context of surface enhanced Raman scattering (SERS). The gold substrates were composed of a combination of a thermally deposited gold film and a close-packed gold nanosphere layer. The SERS effects were negligible when the excitation wavelength was 514 nm, while the Raman signals were enhanced 3-to 50-fold when the excitation wavelength was 633 nm. The large SERS enhancement accompanied a spectral distortion with appearance of several unidentifiable peaks, as well as enhancement of a broadened D peak. These phenomena are interpreted as the local field enhancement in the nanostructure of the gold substrates. The difference in the enhancement factors among the various gold substrates is explained with a model in which the spatial distribution and polarization of the local field and the orientation of the inserted graphene sheet are considered important.

• Macromolecular Research
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• v.16 no.2
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• pp.108-112
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• 2008

Matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) analysis of nonpolar polymeric materials is affected by the sample preparation as well as the matrix and cationizing agent. This study examined the influence of silver salt types on the MALDI analysis of polybutadiene (PB). Silver trifluoroacetate (AgTFA), silver benzoate (AgBz), silver nitrate ($AgNO_3$), and silver p-toluenesulfonate (AgTS) were used as the silver salts to compare the MALDI mass spectra of PB. The mixture solution of PB and 2,5-dihydroxybenzoic acid (DHB), as a matrix dissolved in THF, was spotted on the sample plate and dried. A droplet of the aqueous silver salt solution was placed onto the mixture. The mass spectrum with AgBz showed the clear $[M+Ag]^+$ ion distribution of PB while the mass spectrum with AgTFA did not show $[M+Ag]^+$ ions but only silver cluster ions. The mass spectra with $AgNO_3$ and AgTS did not show a clear $[M+Ag]^+$ ion distribution. The difference in the formation of $[M+Ag]^+$ ions of PB depending on the silver salts was attributed to the silver cation transfer reaction between the silver salt and the matrix (DHB). The mass spectrum showed a clear $[M+Ag]^+$ ion distribution of PB when the conjugate acid of the silver salt was less acidic than the matrix.

• Structural Engineering and Mechanics
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• v.60 no.6
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• pp.953-977
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• 2016

Modern performance-based design methods require ways to determine the factual behavior of structures subjected to earthquakes. Drift ratio demands are important measures of structural and/or nonstructural damage of the structures in performance-based design. In this study, global drift ratio and interstory drift ratio demands, obtained by nonlinear time history analysis of three generic RC frames using code-compatible ground motion record sets, are statistically evaluated. Several ground motion record sets compatible with elastic design spectra defined for the local soil classes in Turkish Earthquake Code are used for the analyses. Variation of the drift ratio demands obtained from ground motion records in the sets and difference between the mean of drift ratio demands calculated for ground motion sets are evaluated. The results of the study indicate that i) variation of maximum drift ratio demands in the sets were high; ii) different drift ratio demands are calculated using different ground motion record sets although they are compatible with the same design spectra; iii) the effect of variability due to random causes on the total variability of drift ratio demands is much larger than the effect of variability due to differences between the mean of ground motion record sets; iv) global and interstory drift ratio demands obtained for different ground motion record sets can be accepted as simply random samples of the same population at %95 confidence level. The results are valid for all the generic frames and local soil classes considered in this study.