• Korean Chemical Engineering Research
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• v.52 no.6
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• pp.720-726
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• 2014

PEM fuel cell vehicles have been getting much attraction due to a sort of highly clean and effective transportation. The onboard fuel processor, however, is inevitably required to supply the hydrogen by conversion from some fuels since there are not enough available hydrogen stations nearby. A lot of studies have been focused on analyses of ATR reactor under the assumption of thermo-neutral condition and those of the optimized process for the minimization of energy consumption using thermal efficiency as an objective function, which doesn't guarantee the maximum hydrogen production. In this study, the analysis of optimization for 100 kW PEMFC onboard fuel processor was conducted targeting various fuels such as gasoline, LPG, diesel using newly defined hydrogen efficiency and keeping simply synthesized heat exchanger network regardless of external utilities leading to compactness and integration. Optimal result of gasoline case shows 9.43% reduction compared to previous study, which shows the newly defined objective function leads to better performance than thermal efficiency in terms of hydrogen production. The sensitivity analysis was also done for hydrogen efficiency, heat recovery of each heat exchanger, and the cost of each fuel. Finally, LPG was estimated as the most economical fuel in Korean market.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.1
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• pp.1-9
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• 2015

To satisfy stricter $NO_X$ emission regulations for light- and heavy-duty diesel vehicles, a control algorithm needs to be developed based on a selective catalytic reaction (SCR) dynamics model for chemical reactions. This paper presents the development and validation of a SCR dynamics model through test rig experiments and MATLAB simulations. A nonlinear state space model is proposed based on the mass conservation law of chemical reactions in the SCR dynamics model. Experiments were performed on a test rig to evaluate the effects of the $NO_X$ and $NH_3$ concentrations, gas temperature, and space velocity on the $NO_X$ conversion efficiency for the urea-SCR system. The parameter values of the proposed SCR model were identified using the experimental datasets. Finally, a control-oriented model for an SCR system was developed and validated from the experimental data in a MATLAB simulation. The results of this study should contribute toward developing a closed-loop control strategy for $NO_X$ and $NH_3$ slip reduction in the urea-SCR system for an actual engine test bench.

• Environmental and Resource Economics Review
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• v.29 no.1
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• pp.23-45
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• 2020

The rapid economic growth has brought tremendous pressure on the environment and caused severe air pollution in China. This study empirically examines causes of air pollution in China. Panel-corrected standard errors procedure (PCSE) was used to analyze major determinants of increasing or reducing emissions of sulfur dioxide (SO₂) and nitrogen oxides (NO_X) in 30 Chinese provinces. The estimation results show that SO₂ emission is mitigated as per capita regional GDP increases, but the relation between emission of NO_X and per capita regional GDP is found to have an inverse N-shaped curve, which implies that emission of NO_X is ultimately expected to decline with economic growth. As for increasing factors of air pollutants, electricity consumption is a significant common source of SO₂ and NO_X emissions. Moreover, the results show that increment of coal consumption significantly affects emission of SO₂ while increase of natural gas consumption reduce emission of SO₂. On the other side, investment in energy industry, and investment on treatment of waste gases are determinants of mitigating emissions of SO₂, but have no impact on NO_X. Consumption of diesel, truck ratio and number of vehicles increase emission of NO_X. Meanwhile, higher precipitation rate is a common determinant of mitigating emissions of SO₂ and NO_X. Policy implications are suggested in the conclusion.

• Journal of the Korea Organic Resources Recycling Association
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• v.17 no.1
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• pp.39-48
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• 2009

Biodiesel is estimated to be the best recycling energy source as an alternative fuel for transportation vehicles which represents the biggest share of greenhouse effect gas exhausts. Thus, in order to widely expand use of biodiesel and to enhancement its reliability, studies on quality improvement of biodiesel is needed. In this study, we have produced biodiesel(BD100, BD20) through esterification reaction using raw material of waste frying oil and analyzed compatibility with 24 items of quality criteria. As waste frying oil has high contents of unsaturated fatty acid such as Oleic acid, Linoleic acid and Linolenic acid, it is confirmed that there is no problem in using the same as a raw material of biodiesel. The result of analyzing the quality criteria items of biodiesel showed that it satisfied all the quality criteria except the oxidation stability of BD100, which was 2 hours, fatty acid methyl ester of BD20, which was 18.6w% and the filter plugging point, which was $-5^{\circ}C$. We believe that it will contribute to improved utilization of waste resources as alternative energy if studies on technology to improve quality of some items are provided.

• The Journal of The Korea Institute of Intelligent Transport Systems
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• v.19 no.1
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• pp.71-82
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• 2020

The existing transportation system, which is based on internal combustion engines, is rapidly being converted to electrification. Thus, eco-friendly public transportation with high transportation efficiency will continue to spread throughout the market in the near future. The purpose of this study is to compare and analyze the cognitive characteristics of passengers redgarding the technical and social factors of various public transportation means to help a successful introduction of eco-friendly public transit. Through a survey questionnaire (N=485), seven factors of seven transportation modes were evaluated and analyzed using principal component analysis. As a result, it is confirmed that potential passengers have high expectations for the eco-friendliness and city image of the eco-friendly buses. Also, it is confirmed that eco-friendly buses are superior in cleanliness and ride comfort than diesel buses. Given the study's results, this study identifies the cognitive characteristics of passengers regarding eco-friendly public transportation. We hope that these results will be used as basic information for image positioning and improved service with the use of eco-friendly transportation.

• Journal of environmental and Sanitary engineering
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• v.12 no.3
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• pp.51-59
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• 1997

In this study, we researched the concentration of nitrogen dioxide($NO_{2}$) and sulfur dioxide($SO_{2}$) of indoor(waiting room) and outdoor(place of getting on the bus) at the bus terminals (Kang-Nam, Dong-Seoul and Nam-Bu) in Seoul to recognize the degree of pollution by exhaust gas of the diesel engine vehicles, and examine the factor that might affect air pollution of terminals. The concentration of $NO_{2}$ and $SO_{2}$ were measured in winter and summer, and the results of the analysis are as follows : The mean concentration of $NO_{2}$ was $57.49{\pm}21.86$ ppb and the concentration of outdoor with $64.10{\pm}27.69$ ppb was significantly higher than the indoor with $50.89{\pm}10.92$ ppb (p<0.05), and the highest with $73.54{\pm}25.54$ ppb at Kang-Nam terminal (p<0.01). The mean concentration of $NO_{2}$ was $62.80{\pm}24.74$ ppb in winter and $52.19{\pm}17.50$ ppb in summer, and had a not statistical difference. The mean concentration of $SO_{2}$ was $31.71{\pm}8.73$ ppb and the concentration of outdoor with $31.04{\pm}8.89$ ppb was similar to the indoor $32.29{\pm}8.70$ ppb, and the highest with $32.57{\pm}9.01$ ppb at Dong-Seoul terminal (p<0.05). The mean concentration of $SO_{2}$ in winter with $39.67{\pm}4.10$ ppb was significantly higher than in summer with $23.76{\pm}2.61$ ppb (p<0.01). The concentration of outdoor $NO_{2}$ at Kang-Nam terminal was 104, 84 ppb in winter and 81.20 ppb in summer, and had a statistical difference compared with the concentration of indoor $NO_{2}$ at Dong-Seoul and Nam-Bu terminals. The concentration of indoor $NO_{2}$ and $SO_{2}$ were higher than that of outdoor at Kang-Nam and Dong-Seoul terminals, but on the contrary, lower than that of outdoor at Nam-Bu terminal. The concentration of $NO_{2}$ and $SO_{2}$ at Nam-Bu terminal were lower than those at Kang-Nam and Dong-Seoul terminals. While the concentration of $SO_{2}$ show the large difference between winter and summer, that of $NO_{2}$ dose not.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.6
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• pp.633-648
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• 2010

The study was performed to elucidate the characteristics of VOCs at distinct monitoring sites in urban atmosphere; one is at a roadside in downtown inland city of Jeonju, and the other is at an industrial site in Gunsan near coastal area. The ambient samples were collected for 24 hours in two-bed adsorbent tubes by using MTS-32 sequential tube sampler equipped with Flex air pump every 16 days in a roadside and a industrial complex from February to November in 2009. VOCs were determined by thermal desorption coupled with GC/MSD. Major individual VOCs in roadside samples were shown as following order in magnitude: toluene>m,p-xylene>ethyl benzene>decanal; and those in the industrial complex samples were as follows: toluene>ethanol>ethyl acetate>decanal>m,pxylene. High benzene concentration in the roadside was more frequently occurred than in the industrial complex. However ambient level of toluene in the industrial complex was higher than that in the road side. Results from roadside sample analysis showed that nonane and 1,2,4-trimethylbenzene were very frequently observed with higher concentrations than those in the industrial complex. It seems that nonane and 1,2,4-trimethylbenzene could be the source characteristics for the roadside air. From the diurnal variation, it was found that concentrations of benzene, ethylbenzene, xylene, nonane and 1,2,4-trimethylbenznene in the roadside were higher during rush hours; but those in the industrial complex were higher from 10 to 16 LST when the industrial activities were animated. On weekly base, the concentration of benzene, toluene, ethylbenzene and m,p-xylene in the roadside were higher specifically on Wednesday, but those in the industrial complex were higher on Sunday. It was found that the general trends of VOCs levels at both sites significantly influence on seasonal changes. The results of factor analysis showed that the VOCs in the roadside were mainly affected by the emission of vehicles and the evaporation of diesel fuel, meanwhile those in the industrial complex were influenced by the evaporation of solvents and vehicular emission.

• Clean Technology
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• v.25 no.3
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• pp.263-272
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• 2019

Air pollutants have a high impact on everyday life as well as on human health; therefore, new technologies such as low-emission vehicles and add-on systems for air pollutant reduction are needed for our society. However, the environmental benefits and costs of those technologies are not taken into account in existing economic feasibility assessments, which is a barrier that needs to be overcome for green technology to achieve wide dissemination and fast penetration in the market. Thus, this study develops a methodology to assess the economic feasibility of an air pollutant reduction technology by taking into account the social costs from air pollutants and carries out a case study to validate the methodology. Because the social unit costs for air pollutants have not been evaluated yet in South Korea, the methodology uses the social unit costs evaluated for the European Union that are then converted to those for South Korea based on the measuring criteria for vehicle emission gases, parity purchasing price, foreign currency exchange rate, and customer price index. The social unit costs for South Korea are used to assess economic feasibility. A case study was performed to assess the economic feasibility of a dual fuel system using diesel and compressed natural gas by taking into account social costs from air pollutants as well as economic costs. This study could contribute to assessing the true economic feasibility of green technology, projects, and policy related with air pollutant reduction.