• Journal of the Korean Ceramic Society
• /
• v.47 no.4
• /
• pp.283-289
• /
• 2010

Physical properties of Plasma electrolytic oxidized 8 different kinds of Al alloys, A-1100, A-2024, A-5052, A-6061, A-6063, A-7075, ACD-7B and ACD-12 were investigated. The electrolyte for PEO was $Na_2SiO_3$ and NaOH and some alkali earthen metal salts system solution. $\eta$-alumina, as well as $\gamma$-alumina, was main crystal phase, which were ever reported. Also, $Al_{4.95}Si_{1.05}O_{9.52}$ was found only in this research. So we can conclude that the process conditions of PEO apparatus and composition and concentration of its electrolyte affects crystal structure and physical properties of PEO layers much more than the compositions of Al alloy.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2015.05a
• /
• pp.54-58
• /
• 2015

인간이 생활하는데 필요한 전기를 생산하는 시설 중 하나인 화력발전소의 발전수차를 냉각시키기 위하여 많은 양의 냉각수를 바다에서 취수하게 되는데, 이 과정 중에서도 특히 흡입수조(Intake Basin)에서 흡입펌프(Suction Pump)를 통과하는 단계가 매우 중요하다. 흡입수조의 형상과 펌프운용조건 등에 의하여 흡입구(Bell Mouth)에 접근하는 유동이 비대칭일 경우 흡입구 주변에서 선회류가 발생하거나 유속분포가 비균일?비대칭이 되기 쉽다. 그러면 선회류가 더욱 악화되어 볼텍스(Vortex)로 발달되면 취수 펌프에 악영향을 준다. 또한 볼텍스의 발생은 흡입수조의 형상뿐만이 아니라 낮은 수위일 경우 수면과 흡입구의 거리가 짧아지면서 자유수면볼텍스 또는 수중볼텍스가 발생할 확률이 높아지게 된다. 본 연구에서 수리모형시험을 통하여 펌프 조합 및 수위 변화에 따른 볼텍스의 발생여부를 파악하고 볼텍스 저감장치를 고안하였다.

• Journal of the Korean Chemical Society
• /
• v.37 no.2
• /
• pp.199-205
• /
• 1993

The decomposition of hydrogen peroxide by copper-amines complexes was studied in the pH range of 7.3∼11.3 by measuring the rate of the decreasing concentration of $H_2O_2$. Decomposition rate of hydrogen peroxide increased with increasing pH, and then decreased with increasing pH successively. The mechanism for this type of reaction involves the formation of peroxo complexes in the rate-determining step preceding deprotonation of hydrogen peroxide and copper-amines complexes.

• Analytical Science and Technology
• /
• v.12 no.6
• /
• pp.465-471
• /
• 1999

Chloromethylated polystyrene resins supported diethylenetriamine of linear and claw types have been prepared by the reaction of diethylenetriamine with chloromethylated polystyrene. The kinetics of adsorption of transition metal ions on polystyrene resins were measured by the limited-bath technique. This paper reports the results of the diffusion coefficients, entropies of activation, and free energies of activation. The ratedetermining step of the adsorption of transition metals on the resins is a process of diffusion through the particles.

• Proceedings of the Korea Environmental Mutagen Society Conference
• /
• 2004.11a
• /
• pp.147-147
• /
• 2004

• Proceedings of the KIEE Conference
• /
• 2002.07c
• /
• pp.1757-1759
• /
• 2002

Global simulator for $CF_4$ discharge in transformer coupled plasma (TCP) source is developed and simulations arc performed under various conditions. The developed simulator is based on a set of space averaged fluid equations for electrons, positive ions, neutrals and radicals of $CF_4$ plasma. And the used absorbed power by electrons is calculated by a 2-dimensional heating model[1].

• Design & Manufacturing
• /
• v.2 no.2
• /
• pp.6-9
• /
• 2008

Injection molding is representative process of plastic production. Most of numerical analyses for injection molding have been based on the Hele Shaw's approximation: two-dimensional flow analysis. The present work covers numerical analyses of injection molding using three-dimensional solid elements. The accuracy of the analysis results has been verified through some numerical examples in comparison with the various conditions. In this study, moldflow software was used to analyze the cooling analysis. The results of cooling analysis and testing catapult were compared for plastic products.

• Journal of the Korean Chemical Society
• /
• v.39 no.1
• /
• pp.29-34
• /
• 1995

The rates for the oxidation reaction of l-ascorbic acid by Cu(Ⅱ)-polyamine complexes were measured by Onish's method at the pH 4.6. The oxidation process of l-ascorbic acid is proposed to occur by the inner-sphere mechanism that involves the formation of a Cu(Ⅱ)-ascorbic acid complex and electron transfer at the rate-determining step.

• Journal of the Korean Chemical Society
• /
• v.35 no.1
• /
• pp.16-23
• /
• 1991

Resins of polystyrene supported triethylenetetramine of linear and claw types have been prepared by the reaction of triethylenetetramine with chloromethylated polystyrene. The resin supported triethylenetetramines were principally characterized by infrared spectra. Kinetics of adsorption of transition metals on the resin have been investigated. This paper reports the results of the diffusion coefficients and entropies of activation. The rate determining step is a process of diffussion through the particle.

• Proceedings of the Korean Society of Life Science Conference
• /
• 2007.10a
• /
• pp.43.1-43.1
• /
• 2007

See Full Text