• Journal of the Korean Society of Propulsion Engineers
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• v.17 no.6
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• pp.38-47
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• 2013

Traditional propellants release toxic gases during combustion that are harmful to the environment. This study describes a novel synthetic process of two high nitrogen containing tetrazines, TATTz and BTATz, which can be adapted as solid fuels for a solution to environmental concerns. The compounds were characterized by NMR, IR spectroscopy, and differential scanning calorimetry(DSC). Detonation properties were calculated with the EXPLO5 program based on calculated heats of formation and measured densities.

• Journal of the Korean Society of Propulsion Engineers
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• v.20 no.6
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• pp.11-17
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• 2016

BTTN and TMETN are representative energetic plasticizers used for various propellants. However these compounds are sensitive relatively. So, in order to develop insensitive energetic plasticizer, this study attempted to synthesize derivative of triazole, 4,5-bis(azidomethyl)-(2-methoxyethyl)-1,2,3- triazole (DAMETR). Also, the prepared compound was characterized by NMR, IR spectroscopy, and physicochemical properties such as glass transition temperature, melting point, decomposition temperature, density, viscosity and impact sensitivity. In addition, the heats of formation (${\Delta}H_f$) and detonation properties (pressure and velocity) of DAMETR were calculated using Gaussian 09 and EXPLO5 programs. Especially, 1-DAMETR(>50 J) was more insensitive than BTTN(1 J) and TMETN(9.2 J).

• Journal of the Korean Society of Propulsion Engineers
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• v.20 no.2
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• pp.31-38
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• 2016

Most of propellants that is used widely in the world release toxic gases such as methane gas and carbon dioxide during combustion which are noxious to the environment. This study established a synthetic process of a high nitrogen containing derivative of triazole, 4,5-bis(azidomethyl)-methyl-1,2,3-triazole (DAMTR), which can be applied as energetic plasticizer to environmental concerns. Also, the compound was characterized by NMR, IR spectroscopy, and physical properties such as glass transition temperature, melting point, decomposition temperature, density, impact sensitivity, viscosity and volatility were measured. In addition, the heats of formation (${\Delta}H_f$) and detonation properties (pressure and velocity) of DAMTR were calculated using Gaussian 09 and EXPLO5 programs.

• Explosives and Blasting
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• v.30 no.2
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• pp.29-42
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• 2012

Variables influencing the free face movement due to rock blasting include the physical and mechanical properties, in particular the discontinuity characteristics, explosive type, charge weight, burden, blast-hole spacing, delay time between blast-holes or rows, stemming conditions. These variables also affects the blast vibration, air blast and size of fragmentation. For the design of surface blasting, the priority is given to the safety of nearby buildings. Therefore, blast vibration has to be controlled by analyzing the free face movement at the surface blasting sites and also blasting operation needs to be optimized to improve the fragmentation size. High-speed digital image analysis enables the analyses of the initial movement of free face of rock, stemming optimality, fragment trajectory, face movement direction and velocity as well as the optimal detonator initiation system. Even though The high-speed image analysis technique has been widely used in foreign countries, its applications can hardly be found in Korea. This thesis aims at carrying out a fundamental study for optimizing the blast design and evaluation using the high-speed digital image analysis. A series of experimentation were performed at two large surface blasting sites with the rock type of shale and granite, respectively. Emulsion and ANFO were the explosives used for the study. Based on the digital images analysis, displacement and velocity of the free face were scrutinized along with the analysis fragment size distribution. In addition, AUTODYN, 2-D FEM model, was applied to simulate detonation pressure, detonation velocity, response time for the initiation of the free face movement and face movement shape. The result show that regardless of the rock type, due to the displacement and the movement velocity have the maximum near the center of charged section the free face becomes curved like a bow. Compared with ANFO, the cases with Emulsion result in larger detonation pressure and velocity and faster reaction for the displacement initiation.

• Proceedings of the Korean Geotechical Society Conference
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• 2010.03a
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• pp.1409-1416
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• 2010

It is essential to predict a blasting-induced excavation damage zone (EDZ) beyond the proposed excavation line of a tunnel because the unwanted damage area requires extra support system for tunnel safety. Complicated blasting process which may hinder a proper characterization of the damage zone can be effectively represented by two loading mechanisms. The one is a dynamic impulsive load generating stress waves outwards immediately after detonation. The other is a gas pressure that remains for a relatively long time. Since the gas pressure reopens up the arrested cracks and continues to extend some cracks, it contributes to the final formation of EDZ induced by blasting. This paper presents the simple method to evaluate EDZ induced by gas pressure during blasting in rock. The EDZ is characterized by analyzing crack propagation from the blasthole. To do this, a model of the blasthole with a number of radial cracks of equal length in an infinite elastic plane is considered. In this model, the crack propagation is simulated by using three conditions, the crack propagation criterion, the mass conservation of the gas, and the adiabatic condition. As a result, the stress intensity factor of the crack generally decreases as crack propagates from the blasthole so that the length of the crack is determined. In addition, the effect of rock properties, initial number of cracks, and the adiabatic exponent are investigated.

• Tunnel and Underground Space
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• v.16 no.5 s.64
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• pp.413-421
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• 2006

In order to explain entirely dynamic fracture process induced by blasting in rock mass, it needs to consider detonation pressure and gas pressure acting on blasthole wall simultaneously. In this study, prior to simulating the coupling between gas flow and rock mass, we analyzed effects of gas pressure-time history, length of cracks and equation of state adopted to calculate the gas pressure on the gas flow within a radial fracture created by single-hole blasting. The effects were investigated on two assumptions: (a) the radial fracture was composed of 5 cracks which were 0.01 m in length and 0.001 m in asperity each and (b) the PETN explosive which diameter was 36 mm was charged in a blasthole of 45 mm diameter. It was concluded that the maximum gas pressure and its travel time were dependent on characteristics of charged explosives and geometrical properties of radial fracture.