• Title/Summary/Keyword: Deterioration layer

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Poly-Si Thin Film Solar Cells by Hot-wire CVD

  • Lee, J.C.;Chung, Y.S.;Kim, S.K.;Yoon, K.H.;Song, J.S.;Park, I.J.;Kwon, S.W.;Lim, K.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.1034-1037
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    • 2003
  • Microcrystalline silicon(c-Si:H) thin-film solar cells are prepared with intrinsic Si-layer by hot wire CVD. The operating parameters of solar cells are strongly affected by the filament temperature ($T_f$) during intrinsic layer. Jsc and efficiency abruptly decreases with elevated $T_f$ to $1400^{\circ}C$. This deterioration of solar cell parameters are resulted from increase of crystalline volume fraction and corresponding defect density at high $T_f$. The heater temperature ($T_h$) are also critical parameter that controls device operations. Solar cells prepared at low $T_h$ ($<200^{\circ}C$) shows a similar operating properties with devices prepared at high $T_f$, i.e. low Jsc, Voc and efficiency. The origins for this result, however, are different with that of inferior device performances at high $T_f$. In addition the phase transition of the silicon films occurs at different silane concentration (SC) by varying filament temperature, by which highest efficiency with SC varies with $T_f$.

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Quality Attributes of Fat-free Sausage Made of Chicken Breast and Liquid Egg White

  • Lee, Hyun Jung;Jo, Cheorun;Nam, Ki Chang;Lee, Kyung Haeng
    • The Korean Journal of Food And Nutrition
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    • v.29 no.4
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    • pp.449-455
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    • 2016
  • We developed a type of sausage made of chicken breast and liquid egg whites for consumers interested in weight management. To determine the quality of the product, its chemical characteristics, fatty acid composition, free amino acid contents, and nucleotides contents were evaluated during 4 weeks of storage. Sensory evaluation was conducted by both general consumers and body-builders. The sausage was proposed as a fat-free product as fat content was 0.12% based on the Korean Indication Standard of Animal Origin Food. Protein content was 13.42% and calorie value was 61.50 kcal/100 g of the sausage. In sensory evaluation, the mixture of chicken breast and egg whites stuffed into the same casing had an adverse effect on taste, color, texture and overall acceptance while the product that contained egg white stuffed separately into the outer casing enclosing the chicken breast (double layer) improved these attributes. The developed double-layer sausage can last for at least 4 weeks of storage without quality deterioration of flavor-related compounds, such as fatty acids and nucleotides.

Evaluation on Physical and Mechanical Properties of Wood Plastic Composites Treated under Ultraviolet Irradiation (자외선을 처리한 목재 플라스틱 복합재의 물리 및 역학적 성질 평가)

  • Lee, Jong-Shin;Kim, Soung-Joon
    • Journal of the Korea Furniture Society
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    • v.26 no.4
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    • pp.428-434
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    • 2015
  • In this study, we received each wood plastic composites (WPC) from three manufacturers. These WPCs were evaluated regarding their physical and mechanical properties of both before and after accelerated weathering by ultraviolet (UV) irradiation. The total time of exposure of the WPCs to UV irradiation was 1800 h. The water absorption, volumetric swelling and shrinkage of WPCs did not affected by UV irradiation. Among the mechanical properties, there was no significant differences in bending strength and screw withdrawal resistance of UV treated WPCs compared with those of reference WPCs. However, surface hardness of WPCs showed decrease under UV irradiation. Stereoscopic microscopy observation revealed deterioration of the surface layer polymer in all weathered WPCs by UV. Exposure of the WPCs to UV irradiation caused decomposition and disappearance of the polymer layer. From this result, we can estimate that damage of polymer by UV led to a decrease in the surface hardness of the WPCs. The wood flours retained original shape after accelerated weathering by UV irradiation.

Improvement of Surface Hardness of 2205 Duplex Stainless Steel by Laser Shock Peening and Observations of Surface Changes (레이저 쇼크 피닝에 의한 2205 듀플렉스 스테인리스강의 표면 경도 향상과 표면 변화 관찰)

  • Lim, H.T.;Jeong, H.M.;Kim, P.K.;Jeong, Sung-Ho
    • Laser Solutions
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    • v.14 no.1
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    • pp.19-24
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    • 2011
  • This work reports the results for laser shock peening of duplex stainless steel (22% Chromium - 5% Nickel) using a pulsed Nd:YAG laser (wavelength = 532nm, pulse width = 8ns). for the application to high-capacity pumps for seawater desalination plants. By properly selecting the process parameters such as laser intensity of 10GW/$cm^2$, laser pulse density of 75pulse/$mm^2$, and $100{\mu}m$ thick aluminum foil as an absorbent coating layer, the surface hardness of duplex stainless steel could be enhanced by 26%, from 256HV to 323HV with little changes in surface morphology and roughness. The depth of laser shock peened layer was measured to be around 2mm. The large enhancement of surface hardness is considered to have high practical importance in minimizing abrasive and corrosive deterioration of pump parts.

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A Study on the Diffusion Barrier at the p/n Junctions of $Bi_{0.5}Sb_{1.5}Te_3/Bi_2Te_{2.4}Se_{0.6} p/n$ Thermoelectric Thin Films (열전 박막 $Bi_{0.5}Sb_{1.5}Te_3/Bi_2Te_{2.4}Se_{0.6} p/n$ 접합에서의 확산 장벽에 관한 연구)

  • Kim, Il-Ho;Lee, Dong-Hui
    • Korean Journal of Materials Research
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    • v.6 no.7
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    • pp.678-683
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    • 1996
  • In the fabrication processes of thin film thermoelectrics, a subsequent annealing treatment is inevitable to reduce the defects and residual stresses introduced during the film growth, and to make the uniform carrier concentration of the film. However, the diffusion-induced atomic redistribution and the broadening of p/n junction region are expected to affect the thermoelectric properties of thin film modules. The present study intends to investigate the diffusion at the p/n junctions of thermoelectric thin films and to relate it to the property changes. The film junctions of p-type(Bi0.5Sb1.5Te3)and n-type(Bi2Te2.4Se0.6)were prepared by the flash evaporation method. Aluminum thin layer was employed as a diffusion barrier between p-and n-type films of the junction. This was found to be an effective barrier by showing a negligible diffusion into both type films. After annealing treatment, the thermoelectric properties of p/n couples with aluminum barrier layer were accordingly retained their properties without any deterioration.

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Behavior and stress check of concrete box girders strengthened by external prestressing

  • Zhang, Yu;Xu, Dong;Liu, Chao
    • Computers and Concrete
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    • v.22 no.2
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    • pp.133-142
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    • 2018
  • The deterioration of existing bridges has become a major problem around the world. In the paper, a new model and an associated stress checking method are proposed for concrete box girders strengthened by external prestressing. The new model called the spatial grid model can analyze all the spatial behaviors clearly by transforming the box girder into discrete orthogonal grids which are equivalent to plate elements. Then the three-layer stresses are employed as the stress checking indices to evaluate the stress state of the plate elements. The initial stress check before strengthening reveals the cracked and potential cracking areas for existing bridges, making the strengthening design more targeted and scientific; the subsequent stress check after strengthening evaluates the strengthening effect and ensures safety. A deficient bridge is selected as the practical example, verifying the accuracy and applicability of the proposed model and stress checking method. The results show that principal stresses in the middle layer of plate elements reflect the main effects of external prestressing and thus are the key stress checking indices for strengthening. Moreover, principal stresses check should be conducted in all parts of the strengthened structure not only in the webs. As for the local effects of external prestressing especially in the areas near anchorage and deviator, normal stresses check in the outer and inner layers dominates and local strengthening measures should be taken if necessary.

FINITE ELEMENT MODELING AND PARAMETER STUDY OF HALF-BEAD OF MLS CYLINDER HEAD GASKET

  • CHO S. S.;HAN B. K.;LEE J. H.;CHANG H.;KIM B. K.
    • International Journal of Automotive Technology
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    • v.7 no.1
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    • pp.109-114
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    • 2006
  • Half-beads of multi-layer-steel cylinder head gaskets take charge of sealing of lubrication oil and coolant between the cylinder head and the block. Since the head lifts off periodically due to the combustion gas pressure, both the dynamic sealing performance and the fatigue durability are essential for the gasket. A finite element model of the halfbead has been developed and verified with experimental data. The half-bead forming process was included in the model to consider the residual stress effects. The model is employed to assess the dependence of the sealing performance and the fatigue durability on the design parameters of half-bead such as the width and height of bead and the flat region length. The assessment results show that the sealing performance can be enhanced without significant deterioration of the fatigue durability in a certain range of the half-bead width. In the other cases the improvement of sealing performance is accompanied by the loss of the fatigue durability. Among three parameters, the bead width has the strongest influence.

Characterization of ${\mu}c$-Si:H Thin-film Solar Cells by Hot-wire CVD

  • Lee, J.C.;Chung, Y.S.;Kim, S.K.;Youn, K.H.;Song, J.S.;Park, I.J.;Kwon, S.W.;Lim, K.S.
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1598-1600
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    • 2003
  • Microcrystalline silicon(c-Si:H) thin-film solar cells are prepared with intrinsic Si-layer by hot wire CVD. The operating parameters of solar cells are strongly affected by the filament temperature ($T_f$) during intrinsic layer. Jsc and efficiency abruptly decreases with elevated $T_f$ to $1400^{\circ}C$. This deterioration of solar cell parameters are resulted from increase of crystalline volume fraction and corresponding defect density at high $T_f$ The heater temperature ($T_h$) are also critical parameter that controls device operations. Solar cells prepared at low $T_h$ (<$200^{\circ}C$) shows a similar operating properties with devices prepared at high $T_f$, i.e. low Jsc, Voc and efficiency. The origins for this result, however, are different with that of inferior device performances at high $T_f$. In addition the phase transition of the silicon films occurs at different silane concentration (SC) by varying filament temperature, by which highest efficiency with SC vanes with $T_f$.

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Effects of CrN and TiN Coating by Hydrogen Embrittlement of Aluminum Alloys for Hydrogen Valves of Hydrogen Fuel Cell Vehicles on Mechanical Properties (수소연료전지 자동차의 수소밸브용 알루미늄 합금의 수소취화에 의한 기계적 특성에 미치는 CrN과 TiN 코팅의 영향)

  • Ho-Seong Heo;Dong-Ho Shin;Seong-Jong Kim
    • Corrosion Science and Technology
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    • v.22 no.4
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    • pp.232-241
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    • 2023
  • The mechanical properties of the hydrogen valve responsible for supplying and blocking hydrogen gas in a hydrogen fuel cell electric vehicle (FCEV) were researched. Mechanical properties by hydrogen embrittlement were investigated by coating chromium nitride (CrN) and titanium nitride (TiN) on aluminum alloy by arc ion plating method. The coating layer was deposited to a thickness of about 2 ㎛, and a slow strain rate test (SSRT) was conducted after hydrogen embrittlement to determine the hydrogen embrittlement resistance of the CrN and TiN coating layers. The CrN-coated specimen presented little decrease in mechanical properties until 12 hours of hydrogen charging due to its excellent resistance to hydrogen permeation. However, both the CrN and TiN-coated specimens exhibited deterioration in mechanical properties due to the peeling of the coating layer after 24 hours of hydrogen charging. The specimens coated at 350 ℃ presented a significant decrease in ultimate tensile strength due to abnormal grain growth.

Development of Prediction Model of Chloride Diffusion Coefficient using Machine Learning (기계학습을 이용한 염화물 확산계수 예측모델 개발)

  • Kim, Hyun-Su
    • Journal of Korean Association for Spatial Structures
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    • v.23 no.3
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    • pp.87-94
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    • 2023
  • Chloride is one of the most common threats to reinforced concrete (RC) durability. Alkaline environment of concrete makes a passive layer on the surface of reinforcement bars that prevents the bar from corrosion. However, when the chloride concentration amount at the reinforcement bar reaches a certain level, deterioration of the passive protection layer occurs, causing corrosion and ultimately reducing the structure's safety and durability. Therefore, understanding the chloride diffusion and its prediction are important to evaluate the safety and durability of RC structure. In this study, the chloride diffusion coefficient is predicted by machine learning techniques. Various machine learning techniques such as multiple linear regression, decision tree, random forest, support vector machine, artificial neural networks, extreme gradient boosting annd k-nearest neighbor were used and accuracy of there models were compared. In order to evaluate the accuracy, root mean square error (RMSE), mean square error (MSE), mean absolute error (MAE) and coefficient of determination (R2) were used as prediction performance indices. The k-fold cross-validation procedure was used to estimate the performance of machine learning models when making predictions on data not used during training. Grid search was applied to hyperparameter optimization. It has been shown from numerical simulation that ensemble learning methods such as random forest and extreme gradient boosting successfully predicted the chloride diffusion coefficient and artificial neural networks also provided accurate result.