• Title/Summary/Keyword: Detailed Chemistry

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A large eddy simulation on the effect of buildings on urban flows

  • Zhang, Ning;Jiang, Weimei;Miao, Shiguang
    • Wind and Structures
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    • v.9 no.1
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    • pp.23-35
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    • 2006
  • The effect of buildings on flow in urban canopy is one of the most important problems in local/micro-scale meteorology. A large eddy simulation model is used to simulate the flow structure in an urban neighborhood and the bulk effect of the buildings on surrounding flows is analyzed. The results demonstrate that: (a) The inflow conditions affect the detailed flow characteristics much in the building group, including: the distortion or disappearance of the wake vortexes, the change of funneling effect area and the change of location, size of the static-wind area. (b) The bulk effect of the buildings leads to a loss of wind speed in the low layer where height is less than four times of the average building height, and this loss effect changes little when the inflow direction changes. (c) In the bulk effect to environmental fields, the change of inflow direction affects the vertical distribution of turbulence greatly. The peak value of the turbulence energy appears at the height of the average building height. The attribution of fluctuations of different components to turbulence changes greatly at different height levels, in the low levels the horizontal speed fluctuation attribute mostly, while the vertical speed fluctuation does in high levels.

Taxonomic Study of the Genus Abundisporus in Korea

  • Jargalmaa, Suldbold;Park, Myung Soo;Park, Jae Young;Fong, Jonathan J.;Jang, Yeongseon;Lim, Young Woon
    • Mycobiology
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    • v.43 no.3
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    • pp.225-230
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    • 2015
  • The polypore genus Abundisporus Ryvarden is characterized by resupinate to pileate fruitbodies with a purplish brown hymenophore, slightly thick-walled, pale yellowish and non-dextrinoid basidiospores, and causing white rot. A purple color hymenophore, an easily observable and striking character, was considered the main distinctive feature at the generic level within polypores. However, due to highly similar basidiocarp features, species identification within these purple polypores is particularly difficult. Three species of purple colored polypores have been reported in Korea (Abundisporus fuscopurpureus, A. pubertatis, and Fomitopsis rosea). Based on morphological re-examination, ecological information, and sequence analysis of the internal transcribed spacer, we showed that previous classification was incorrect and there is only one species (A. pubertatis) in Korea. We provide a detailed description of A. pubertatis in Korea, as well as a taxonomic key to distinguish wood rot fungi with a purple hymenophore.

Numerical Study of Interaction between Hydrogen and Hydrocarbon Flames (수소화염과 탄화수소화염의 상호작용에 관한 수치계산 연구)

  • Oh, Chang-Bo;Lee, Eui-Ju
    • Journal of the Korean Society of Safety
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    • v.25 no.2
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    • pp.12-17
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    • 2010
  • Numerical simulations were performed for the prediction of the flame structure during the interaction between hydrogen and hydrocarbon flames. A counterflow flow geometry was introduced to establish the interacting two flames. Methane was used as a representative hydrocarbon fuel in this study. A well-known numerical code for the counterflow flame, OPPDIF, was used for the simulations. The detailed chemistry was adopted to predict the flame structure reasonably. The interaction of two one-dimensional premixed flames established in counterflow burner was investigated with the global strain rate and velocity ratio. It was found that the maximum temperature located near the methane flame surface while the heat release rate of methane was lower than hydrogen flame. The flame thickness become narrow with increasing the velocity ratio while the global strain rate was fixed. The local strain rate and heat release rate at the methane flame surface were correlated with the global strain rate, while those at the hydrogen flame were not correlated with the global strain rate. However, the maximum temperature of the interacting flames was correlated with the global strain rate.

Antimicrobial Fiber Products Treated with Silica Hybrid Ag Nanoparticles

  • Kim, Hwa-Jung;Park, Hae-Jin;Choi, Seong-Ho;Park, Hae-Jun
    • Journal of Radiation Industry
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    • v.6 no.3
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    • pp.273-279
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    • 2012
  • Silica hybrid silver nanoparticles showing the strong antimicrobial activity, in which nano-silver is bound to silica molecules, has been synthesized using ${\gamma}-irradiation$ at room temperature. The present study relates to an antimicrobial composition for coating fiber products comprising silica hybrid silver nanoparticles. In this study, we describe antimicrobial fiber products coated with the silica hybrid silver nanoparticles and a method of antimicrobially treating fiber products by coating the fiber products with the silica hybrid silver nanoparticles. The antimicrobial fiber products exhibited excellent antimicrobial effects. In detailed practice, when the present composition comprising nanosized silica-silver was applied to a cloth (fabric) in a concentration of $6.4mg\;yard^{-1}$, the viable cell number decreased to less than 10 cells before and after laundering, resulting in a reduction of 99.9% or greater in the viable cell number. The present composition displays long-lasting potent disinfecting effects on bacteria. Also, we investigated the toxicity of silica hybrid silver nanoparticles in rats. The skin of rats was treated with a 30 ppm nanoparticles solution ($2ml\;Kg^{-1}$) for 8 days. No toxicity was detected in the treatment. These results suggest that the fiber products coated with the silica hybrid silver nanoparticles can be used to inhibit the growth of various microorganisms.

C:N:P stoichiometry of particulate and dissolved organic matter in river waters and changes during decomposition

  • Islam, Mohammad Jahidul;Jang, Changwon;Eum, Jaesung;Jung, Sung-min;Shin, Myoung-Sun;Lee, Yunkyoung;Choi, Youngsoon;Kim, Bomchul
    • Journal of Ecology and Environment
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    • v.43 no.1
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    • pp.14-21
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    • 2019
  • Background: Stoichiometry plays an important role in understanding nutrient composition and cycling processes in aquatic ecosystems. Previous studies have considered C:N:P ratios constant for both DOM (dissolved organic matter) and POM (particulate organic matter). In this study, water samples were collected in the six major rivers in Korea and were incubated for 20 days. C:N:P ratios were determined during the time course of the incubations. This allowed us to examine the changes in N and P contents of organic matter during decomposition. Results: POM and DOM showed significant differences in N and P content and the elemental ratios changed during the course of decomposition; DOM showed higher C:N and C:P ratios than POM, and the C:N and C:P ratios increased during decomposition, indicating the preferential mineralization of P over N and N over C. Conclusions: The N and P contents of organic matter in aquatic ecosystem are far from constant and vary significantly during decomposition. More detailed information on the changes in C:N:P ratios will provide improved understanding of decomposition processes and improved modeling of aquatic ecosystems.

Crossover Temperature and Ignition Delay Time of Diluted Hydrogen-Air Mixtures (희석된 수소-공기 혼합기의 크로스오버 온도와 점화지연시간)

  • Dong Youl, Lee;Eui Ju, Lee
    • Journal of the Korean Society of Safety
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    • v.37 no.6
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    • pp.18-24
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    • 2022
  • Hydrogen is a clean fuel and is used in many applications in power systems such as fuel cells. It has unique properties such as wide flammability, high burning velocity, and difficulty to liquefy, which lead to critical safety issues. Fire and explosion are the most frequently occurring accidents and one of the major reasons is autoignition. In the ignition process, the chemistry of hydrogen combustion depends mainly on radical pools, and the temperature at which chain-branching and terminating rates are equal is called the crossover temperature. This study addresses the homogeneous autoignition of diluted hydrogen-air mixtures to investigate the effects of dilution on the crossover temperature to prevent explosions in the future. The new criterion for crossover temperature is introduced by only hydrogen radicals to adjust more simply. The detailed calculations indicate that the crossover temperatures are low at high dilutions of carbon dioxide and nitrogen because the concentrations of active radicals are reduced when an inert gas is added. This result is expected to contribute to hydrogen safety and realize a hydrogen society in the future.

The DISNY facility for sub-cooled flow boiling performance analysis of CRUD deposited zirconium alloy cladding under pressurized water reactor condition: Design, construction, and operation

  • Ji Yong Kim;Yunju Lee;Ji Hyun Kim;In Cheol Bang
    • Nuclear Engineering and Technology
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    • v.55 no.9
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    • pp.3164-3182
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    • 2023
  • The CRUD on the fuel cladding under the pressurized water reactor (PWR) operating condition causes several issues. The CRUD can act as thermal resistance and increases the local cladding temperature which accelerate the corrosion process. The hideout of boron inside the CRUD results in axial offset anomaly and reduces the plant's shutdown margin. Recently, there are efforts to revise the acceptance criteria of emergency core cooling systems (ECCS), and additionally require the modeling of the thermal resistance effect of the CRUD during the performance analysis. There is an urgent need for the evaluation of the effect of the CRUD deposition on the cladding heat transfer under PWR operating conditions, but the experimental database is very limited. The experimental facility called DISNY was designed and constructed to analyze the CRUD-related multi-physical phenomena, and the performance analysis of the constructed DISNY facility was conducted. The thermal-hydraulic and water chemistry conditions to simulate the CRUD growth under PWR operating conditions were established. The design characteristics and feasibility of the DISNY facility were validated by the MARS-KS code analysis and separate performance tests. In the current study, detailed design features, design validation results, and future utilization plans of the proposed DISNY facility are presented.

Could Natural Products Confer Inhibition of SARS-CoV-2 Main Protease? In-silico Drug Discovery

  • Mohamed-Elamir F Hegazy
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2020.12a
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    • pp.14-14
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    • 2020
  • In December 2019, the COVID-19 epidemic was discovered in Wuhan, China, and since has disseminated around the world impacting human health for millions. Herein, in-silico drug discovery approaches were utilized to identify potential candidates as Severe Acute Respiratory Syndrome coronavirus 2 (SARS-CoV-2) main protease (Mpro) inhibitors. We investigated several databases including natural and natural-like products (>100,000 molecules), DrugBank database (10,036 drugs), major metabolites isolated from daily used spices (32 molecules), and current clinical drug candidates for the treatment of COVID-19 (18 drugs). All tested compounds were prepared and screened using molecular docking techniques. Based on the calculated docking scores, the top ones from each project under investigation were selected and subjected to molecular dynamics (MD) simulations followed by molecular mechanics-generalized Born surface area (MM-GBSA) binding energy calculations. Combined long MD simulations and MM-GBSA calculations revealed the potent compounds with prospective binding affinities against Mpro. Structural and energetic analyses over the simulated time demonstrated the high stabilities of the selected compounds. Our results showed that 4-bis([1,3]dioxolo)pyran-5-carboxamide derivatives (natural and natural-like products database), DB02388 and Cobicistat (DB09065) (DrugBank database), salvianolic acid A (spices secondary metabolites) and TMC-310911 (clinical-trial drugs database) exhibited high binding affinities with SARS-CoV-2 Mpro. In conclusion, these compounds are up-and-coming anti-COVID-19 drug candidates that warrant further detailed in vitro and in vivo experimental estimations.

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A comprehensive computational approach to assess the influence of the material composition on vibration, bending and buckling response of FG beam lying on viscoelastic foundation

  • Brahim Laoud;Samir Benyoucef;Attia Bachiri;Rabbab Bachir Bouiadjra;Abdelouahed Tounsi;Mahmoud M Selim;Hosam A. Saad
    • Steel and Composite Structures
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    • v.52 no.1
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    • pp.45-56
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    • 2024
  • This paper proposes an analytical solution for the free vibration, bending and buckling a functionally graded (FG) beam resting on viscoelastic foundation. The materials characteristics of the FG beam are considered to be varying across the thickness according several power law functions. The governing equations are found analytically using a quasi-3D model that contains undetermined integral forms and involves few unknowns to derive. Navier's method for simply supported beam is employed to solve the problem. Numerical examples are presented and studied to demonstrate the accuracy and effectiveness of the proposed model. Then, a detailed parametric study is presented in the form of tables and graphs to study and analyze the effects of the different parameters on the response of FG beams with different material compositions resting on a viscoelastic foundation.

Analysis of Descriptive Course Evaluation of University Chemistry Laboratory Class using Text Mining (텍스트 마이닝을 활용한 대학 화학 실험 수업의 서술형 강의 평가 내용 분석)

  • Yun, Jeonghyun;Park, Geumju
    • Journal of the Korean Chemical Society
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    • v.66 no.3
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    • pp.218-227
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    • 2022
  • The purpose of this study is to analyze the opinions of students by using the text mining to the good points and improvements among the descriptive course evaluation written by the students who participated in the university chemistry laboratory class, and to derive the improvement for the class. We analyzed the frequency of occurrence, co-occurrence and network of key words. As a result of the study, in the network of good points in the class, the most frequent mentions were made between class and professor, along with explanation, understanding, student, passion, fun, TA, experiment, help, etc. In the network of improvements in the class, the most frequent mentions were made between class and student, along with professor, content, explanation, exam, wish, experiment, understanding, difficult, thought, problem, etc. In other words, the students suggested the opinion that the contents of the class were well understood and that they felt fun and satisfied with the experimental process due to 'easy and detailed explanation' and 'TA's assistance' as good points of the class. On the other hand, the students suggested the negative opinions that the understanding and concentration in the class was decreased due to 'difficulty of content and exam', 'excessive assignments', and 'class environment' as improvements of the class.