• Title/Summary/Keyword: Desorption Time

Search Result 450, Processing Time 0.025 seconds

Confirmation of The Fouling Phenomena in CDI Process and The Establishment of Its Removal Process Conditions (CDI 전극 내 파울링 현상 확인 및 제거공정 조건의 확립)

  • Kim, Tae Yeong;Rhim, Ji Won
    • Membrane Journal
    • /
    • v.29 no.5
    • /
    • pp.276-283
    • /
    • 2019
  • In this study, The experiments of the confirmation of the fouling phenomena in CDI process and the establishment of its removal process conditions were carried out. The foulant concentrations of humic acid sodium salt (HA) added to the feed solution were 5, 10, 15 mg/L, respectively. The occurrence of fouling under the certain adsorption/desorption conditions could be confirmed with an increase in adsorption and desorption concentration curve over time. Both the voltage and time in adsorption and desorption processes were changed to eliminate the fouled pollutants. Typically, the fouling removal condition was found at the adsorption condition 1.2 V/5 min and the desorption condition -3 V/2 min, respectively.

Biosorption and Desorption Characteristics of Heavy metal ion in Aqueous Solution by Chlorophyll (엽록체를 이용한 수중에서의 중금속 흡착 및 탈착 특성)

  • 연익준;신택수;이명선;주소영;김광렬
    • Journal of environmental and Sanitary engineering
    • /
    • v.14 no.1
    • /
    • pp.80-87
    • /
    • 1999
  • According to the fact that algae, which is usually used as a biosorbent, contains chlorophyll, we used the chlorophyll as an adsorbent. In this study, chlorophyll is immobilized by agar, which was made of platan, oak, ginkgo and pine. We investigated the removing capacity of biosorbents to toxic heavy metals (Pb, CU, Cd, Zn) in the single ion solution. Then the experimental parameters were pH, reaction time and concentration of heavy metal ions.The optimum conditions for the adsorption of heavy metals were as follows : pH range was 4~5, reaction time was 40mon, and the highest ratio of the removing rate was 50~70 ppm. The order of the amount of Pb, Cu and Cd removed was specified as oak > ginkgo > pine > platan in these conditions and as pine > ginkgo > oak > platan at Zn. Fro the results of the desorption experiments, we found that the heavy metal with the highest ratio of desorption in the single ion adsorbent was Cu.

  • PDF

The aging characteristics of composite insulating materials due to high-temperature and high-moisture (고온 다습하에서 복합절연재료의 열화특성)

  • 이종호;이규철;김순태;박홍태
    • Electrical & Electronic Materials
    • /
    • v.7 no.1
    • /
    • pp.15-24
    • /
    • 1994
  • For increasing the insulating proper-ties and the reliability of composite materials due to environmental aging, the electrical and mechanical characteristics of moisture absortion specimens and moisture desorption specimens were investigated. After moisture absorption wt% and moisture desorption wt% increased with time, a state of saturation arrived subsequent to a constant time. Moisture absorption constants with the layers of glass fiber showed 0.0117 in 1 layer, 0.0123 in 2 layers and 0.0152 in 3 layers. Electrical and mechanical characteristics dropped significantly with moisture absorbing in composite materials. Although moisture dried completly at 70.deg. C, it is impossible to obtain the electrical and mechanical characteristics before moisture absorption. Many defaults by moisture in composite materials exist at interface between epoxy matrix and filler.

  • PDF

Adsorption and Desorption Characteristics of Toluene in Modified Activated Carbon Using Microwave Irradiation (마이크로파를 이용한 탈착시스템에서 개질화 된 활성탄의 흡.탈착 특성)

  • Kim, Beom-Jun;Choi, Sung-Woo
    • Journal of Environmental Science International
    • /
    • v.17 no.5
    • /
    • pp.493-500
    • /
    • 2008
  • This paper describes the adsorption/desorpton efficiency of a modified activated carbon by irradiated microwave to treat toluene. By employing microwave energy, the regeneration time was considerably shortened compared with conventional thermal heating regeneration. New adsorbent called ACB (Activated Carbon-Bentonite) was prepared from powder activated carbon with mixing bentonite as a binder. Specific surface area, average pore size and total pore volume of ACB were calculated from the nitrogen adsorption/desorption isotherm. The surface of ACB was characterized with scanning electron microscope(SEM). The results showed that the specific surface area, total pore volume, average pore size of ABC was not influenced by regenerating cycle with microwave irradiation. Toluene was adsorbed onto ACB which desorbed by MW irradiation. Absorption capacity of ACB was 0.117 $g_{toluene}/g_{ACB}$. Desorption efficiency of toluene increased as higher microwave output was applied.

Bioavailability of sorbed phenanthrene in soil slurries (토양 슬러리내에 수착된 phenanthrene의 생물학적 이용성)

  • 신원식;김영규;김영훈;송동익
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2002.09a
    • /
    • pp.92-95
    • /
    • 2002
  • Bioavailability study was conducted to elucidate the relationship between sorption/desorption and biodegradation of sorbed phenanthrene in seven different soils. Mineralization kinetics was determined for phenanthrene-sorbed soil slurries inoculated with Pseudomonas putida (ATCC strain 17484). Two biodegradation models were used to fit mineralization kinetics; (i) a first-order degradation model and (ii) a coupled degradation-desorption model. The biodegradation rates were in order of vermicompost >Bion peat > 50% organoclay > Pahokee > blank (no soil, medium only) > montmorillonite > Ohio shale. The mineralization rate constants increased as desorption-resistance of phenanthrene increased. Among the tested sorbents, active biodegradation of phenanthrene was observed in vermicompost and Bion peat. Biodegradation in these two sorbents exhibited little lag time and a high maximum mineralized capacity. The role of sorption/desorption in bioavailability of phenanthrene sorbed in soils was discussed.

  • PDF

Effect of Desorption Pressure on Adsorption and Desorprtion Breakthrough Behaviors of Carbon Dioxide with Zeolite 3A, 4A, 5A, and 13X Pellets (제올라이트 3A, 4A, 5A, 13X 펠렛의 탈착 압력에 따른 이산화탄소 흡·탈착 파과특성)

  • Sim, Jungbo;Noh, Young-Kyoung;Park, Young Cheol;Kim, Hyunuk;Ryu, Ho-Jung;Cho, Churl-Hee;Moon, Jong-Ho
    • Clean Technology
    • /
    • v.20 no.2
    • /
    • pp.179-188
    • /
    • 2014
  • The effect of desorption pressure on $CO_2/N_2$ breakthrough behaviors for 4 different adsorbents was studied at a fixed bed. Zeolite 3A, 4A, 5A, and 13X pellets were used as adsorbents. Cyclic operations were executed with varying desorption pressure from vacuum (0 bar) to 3 bar while other conditions such as adsorption step pressure (3 bar), temperature (293 K), composition ($CO_2:N_2=10:90$vol%) and flow rate (400 ccm) were fixed at constant values. Each adsorption and desorption step was set as 80 min, which totaled up to 160 min per a cycle. 5 cycles with adsorption and desorption steps were run overall. After the experiment, breakthrough time, saturation time, and adsorption amount were measured and compared in order to find an optimum adsorbent and a proper operating condition for a post combustion $CO_2$ capture process.

The Influence of Dehydrogenation Speed on the Microstructure and Magnetic Properties of Nd-Fe-B Magnets Prepared by HDDR Process

  • Cha, Hee-Ryoung;Yu, Ji-Hun;Baek, Youn-Kyoung;Kwon, Hae-Woong;Kim, Yang-Do;Lee, Jung-Goo
    • Journal of Magnetics
    • /
    • v.19 no.1
    • /
    • pp.49-54
    • /
    • 2014
  • The influence regarding the dehydrogenation speed, at the desorption-recombination state during the hydrogenation-disproportionation-desorption-recombination (HDDR) process, on the microstructure and magnetic properties of Nd-Fe-B magnetic powders has been studied. Strip cast Nd-Fe-B-based alloys were subjected to the HDDR process after the homogenization heat treatment. During the desorption-recombination stage, both the pumping speed and time of hydrogen were systematically changed in order to control the speed of the desorption-recombination reaction. The magnetic properties of HDDR powders were improved as the pumping speed of hydrogen at the desorption-recombination stage was decreased. The lower pumping speed resulted in a smaller grain size and higher DoA. The coercivity and the remanence of the 200-300 ${\mu}m$ sized HDDR powder increased from 12.7 to 14.6 kOe and from 8.9 to 10.0 kG, respectively. In addition, the remanence was further increased to 11.8 kG by milling the powders down to about 25-90 ${\mu}m$, resulting in $(BH)_{max}$ of 28.8 MGOe.

Analysis of Organic Compounds in Ambient PM2.5 over Seoul using Thermal Desorption-comprehensive Two Dimensional Gas Chromatography-time of Flight Mass Spectrometry (TD-GCxGC-TOFMS) (Thermal Desorption-comprehensive Two Dimensional Gas Chromatography-time of Flight Mass Spectrometry (TD-GCxGC-TOFMS)을 이용한 서울 대기 중 PM2.5 유기성분 분석)

  • Lee, Ji-Yi;Lane, Douglas A.;Huh, Jong-Bae;Yi, Sung-Muk;Kim, Yong-Pyo
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.25 no.5
    • /
    • pp.420-431
    • /
    • 2009
  • Characteristics and advantages of the thermal desorption-comprehensive two dimensional gas chromatography-time of flight mass spectrometry (TD-GCxGC-TOFMS) were discussed and the organic compound's analysis result was shown for the ambient $PM_{2.5}$ sample collected in Seoul, Korea. Over 10,000 individual organic compounds were separated from about $70{\mu}g$ of aerosols in a single procedure with no sample pre-treatment. Among them, around 300 compounds were identified and classified based on the mass fragmentation patterns and GCxGC retention times. Several aliphatic compounds groups such as alkanes, alkenes, cycloalkanes, alkanoic acids, and alkan-2-ones were identified as well as 72 PAH compounds including alkyl substituted compounds and 8 hopanes. In Seoul aerosol, numerous oxidized aromatic compounds including major components of secondary organic aerosols were observed. The inventory of organic compounds in $PM_{2.5}$ of Seoul, Korea suggested that organic aerosol were constituted by the compounds of primary source emission as well as the formation of secondary organic aerosols.

Desorption Kinetics and Removal Characteristics of Pb-Contaminated Soil by the Soil Washing Method: Mixing Ratios and Particle Sizes

  • Lee, Yun-Hee;Oa, Seong-Wook
    • Environmental Engineering Research
    • /
    • v.17 no.3
    • /
    • pp.145-150
    • /
    • 2012
  • Pb-contaminated soil at a clay shooting range was analyzed by the sequential extraction method to identify metal binding properties in terms of detrital and non-detrital forms of the soil. Most of the metals in the soils existed as non-detrital forms, exchangeable and carbonate-bound forms, which could be easily released from the soil by a washing method. Therefore, the characteristics of Pb desorption for remediation of the Pb-contaminated soil were evaluated using hydrochloric acid (HCl) by a washing method. Batch experiments were performed to identify the factors influencing extraction efficiency. The effects of the solid to liquid (S/L) ratio (1:2, 1:3, and 1:4), soil particle size, and extraction time on the removal capacity of Pb by HCl were evaluated. Soil samples were collected from two different areas: a slope area (SA) and a land area (LA) at the field. As results, the optimal conditions at 2.8 to 0.075 mm of particle size were 1:3 of the S/L ratio and 10 min of extraction time for SA, and 1:4 of the S/L ratio and 5 min of extraction time for LA. The characteristics of Pb desorption were adequately described by two-reaction kinetic models.

Application of Matrix-assisted Laser Desorption/Ionization Time-of-flight Mass Spectrometry (Matrix-assisted Laser Desorption/Ionization Time-of-flight Mass Spectrometry의 활용)

  • Pil Seung KWON
    • Korean Journal of Clinical Laboratory Science
    • /
    • v.55 no.4
    • /
    • pp.244-252
    • /
    • 2023
  • The timeliness and accuracy of test results are crucial factors for clinicians to decide and promptly administer effective and targeted antimicrobial therapy, especially in life-threatening infections or when vital organs and functions, such as sight, are at risk. Further research is needed to refine and optimize matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS)-based assays to obtain accurate and reliable results in the shortest time possible. MALDI-TOF MS-based bacterial identification focuses primarily on techniques for isolating and purifying pathogens from clinical samples, the expansion of spectral libraries, and the upgrading of software. As technology advances, many MALDI-based microbial identification databases and systems have been licensed and put into clinical use. Nevertheless, it is still necessary to develop MALDI-TOF MS-based antimicrobial-resistance analysis for comprehensive clinical microbiology characterization. The important applications of MALDI-TOF MS in clinical research include specific application categories, common analytes, main methods, limitations, and solutions. In order to utilize clinical microbiology laboratories, it is essential to secure expertise through education and training of clinical laboratory scientists, and database construction and experience must be maximized. In the future, MALDI-TOF mass spectrometry is expected to be applied in various fields through the use of more powerful databases.