• Bulletin of the Korean Chemical Society
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• v.21 no.11
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• pp.1077-1084
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• 2000

The dipolar effect of neighboring protons that are not directly bonded to the carbon of interest on coupled carbon-13 relaxation in a simple organic molecule has been studied by comparing the relaxation behaviors of labeled carbon-13 in $Br13CH_2COOH$ with those in $BrCH_213COOH.$ Various pulse sequences, such as coupled inversion recovery pulse sequence, J-negative and J-positive pulse sequence, and nonselective and selective proton ${\pi}pulse$ sequence, were employed to perform the required coupled spin relaxation experiments. To gain information on various spectral densities, including that of dipolar-CSA cross correlation, the experiments were performed on two different spectrometers, operating, respectively, at 50.31 and 125.51MHz for 13C. The magnitude of CH dipolar spectral densities for $BrCH_213COOH$ was found to be about 8% of those for $Br13CH_2COOH$, which means the effect due to the protons not directly bonded to the carbon of interest is small but not completely negligible.

• Bulletin of the Korean Chemical Society
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• v.21 no.6
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• pp.628-634
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• 2000

Crosslink is the most important chemistry in a rubber vulcanizate. Degree and type of crosslinks of the vulcanizate determine its physical properties. Change of crosslink density and deformation of a rubber vulcanizate by thermal aging were studied using natural rubber (NR) vulcanizates with various cure systems (conventional, semi-EV, and EV) and different cure times (under-, optimum-, and overture). All the NR vulcanizates were deformed by the thermal aging at 60-100 $^{\circ}C.$ The higher the aging temperature is, the more degree of the deformation is. The undercured NR vulcanizates after the thermal aging were deformed more than the optimumand overcured ones. The NR vulcanizates with the EV cure system were less deformed than those with the conventional and semi-EV cure systems. The deformation of the NR vulcanizates was found to be due to change of the crosslink density of the vulcanizates. The crosslink densities of all the vulcanizates after the extraction of organic materials were also changed by the thermal ging. The sources to change the crosslink densities of the vulcanizates by the thermal aging were found to be dissociation of the existing sulfur crosslink and the formation of new crosslinks by free sulfur, reaction products of curing agents, and pendent sulfide groups.

• 제어로봇시스템학회:학술대회논문집
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• 2001.10a
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• pp.98.1-98
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• 2001

An actuator using a permanent magnet and solenoid is proposed and designed in this paper. Its design concept is composed of a driving force generation, a guide mechanism, and a symmetric structure. At first, Driving Force generation uses a concept that is a change efflux by using a permanent magnet and solenoid. A permanent flux is generated by a permanent magnet. Changeable flux is created by a variable current flowing through coil such the solenoid. The direction of this flux is changed due to current flowing through coils. The combination of permanent and changeable fluxes make various flux densities between yokes of moving part and fixed yokes. And then, the flux densities create forces(F), which are used to drive this actuator, in lower and upper gap. In this actuator ...

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.20 no.4
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• pp.383-398
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• 2022

The electrochemical behavior was investigated during the electrolysis of nickel oxide in LiCl-Li₂O salt mixture at 650℃ by changing several components. The focus of this work is to improve anode design and shroud design to increase current densities. The tested components were ceramic anode shroud porosity, porosity size, anode geometry, anode material, and metallic porous anode shroud. The goal of these experiments was to optimize and improve the reduction process. The highest contributors to higher current densities were anode shroud porosity and anode geometry.

• The Bulletin of The Korean Astronomical Society
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• v.44 no.2
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• pp.47.3-47.3
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• 2019

In this talk, we present numerical simulations of driven hydrodynamic and magnetohydrodynamic (MHD) turbulence with weak/strong imposed magnetic fields. We mainly focus on turbulence driven compressively (∇ × f = 0). Our main goal is to examine how magnetic fields play a role in generating solenoidal modes in compressive turbulence. From our simulation analysis, we find that solenoidal energy densities in hydrodynamic and weak magnetic field cases are generated up to ~ 30% of total ones. On the other hand, in the case of strong magnetic fields, solenoidal energy densities are excited up to ~ 70%. To interpret the results, we further analyze vorticity (w = ∇ × u) equation and find that magnetic fields directly create solenoidal motions, and magnetic tension is most effective in this sense. In hydrodynamic simulations, however, we find that viscous dissipation provides vorticity seeds at the very early stage and they are amplified via stretching process. Lastly, in weak magnetic fields cases, we find that solenoidal motions are created by the effects of magnetic fields, viscosity, and stretching in conjunction.

• Geomechanics and Engineering
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• v.35 no.2
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• pp.165-179
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• 2023

This study investigates the uplift capacity of a single vertical belled pile buried at shallow depth in dry sand. The laboratory model experiments are conducted with different pile-tip angles and relative densities. In addition, image and FEM analyses are performed to observe the failure surface of the belled pile for different pile-tip angles and relative densities. Accordingly, the uplift capacity and failure angle in the failure surface of the belled pile were found to depend on the belled pile-tip angle and relative density. A predictive model for the uplift capacity of the belled pile was proposed considering the relative density and belled pile-tip angle based on a previous limit equilibrium equation. To validate the applicability of the proposed model, the values calculated using the proposed and previous models were compared to those obtained through a laboratory model experiment. The proposed model had the best agreement with the laboratory model experiment.

• Proceedings of the Korean Society of Applied Entomolohy Conference
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• 2001.05a
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• pp.134-134
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• 2001

• Journal of the Chungcheong Mathematical Society
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• v.21 no.1
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• pp.71-78
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• 2008

We introduce the homogenized differential systems for fissured medium equations representing the small temperature variation or densities of a fluid in a system consisting of two components.

• The Bulletin of The Korean Astronomical Society
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• v.32 no.1
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• pp.33.2-33.2
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• 2007

• Proceedings of the Plant Resources Society of Korea Conference
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• 1995.01a
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• pp.31-31
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• 1995