• 제목/요약/키워드: Dense materials

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Effects of Monosaccharides and Disaccharides on the Rheological Behavior of Dense Alumina Slurries I. Creep Testing Method

  • Kim, Jong-Cheol;Auh, Keun-Ho;Chr
    • The Korean Journal of Ceramics
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    • 제5권2호
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    • pp.104-109
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    • 1999
  • Rheological properties of dense slurries over 45 volume % with different monosaccharides and disaccharides were checked in order to increase the solid content of dense slurries without sacrificing plasticity using creep testing method. Strain in creep test showed good correlations with Burger model which is expressed as an exponential function of time. Among several monosaccharides and disaccharides studied here, fructose and sucrose were most effective in making dense alumina slurry plastic than other monosaccharides and disaccharides like glucose, galactose, xyloss and maltose. In the case of dense alumina slurry with sucrose, sucrose content or additional water content enhanced to the plasticity of the slurries.

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Effects of Monosaccharides and Disaccharides on the Rheological Behavior of Dense Alumina Slurries II. Oscillation Testing Method

  • Kim, Jong-Cheol;Auh, Keum-Ho;Christopher H. Schilling
    • The Korean Journal of Ceramics
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    • 제5권1호
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    • pp.25-29
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    • 1999
  • Complex viscosities of dense alumina slurries over 45% volume density measured with the oscillating method were correlated well with Casson model. Among several monosaccharides and disaccharides studied here, fructose and sucrose showed good rheological properties in making dense alumina slurry plastic compared to other monosaccharides and disaccharides like glucose, galactose, arabinose, xylose and maltose. Sucrose content or additional water content in dense alumina slurry with sucrose contributed to the plasticity of the slurries.

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Heteroepitaxial Growth of Diamond Films Synthesized by Microwave Plasma Enhanced Chemical Vapor Deposition

  • Kim, Yoon-Kee;Lee, Jai-Young
    • The Korean Journal of Ceramics
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    • 제2권4호
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    • pp.197-202
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    • 1996
  • The highly oriented diamond particles were deposited on the mirror-polished (100) silicon substrates in the bell-jar type microwave plasma deposition system using a three-step process consisting if carburization, bias-enhanced nucleation and growth. By adjusting the geometry of the substrate and substrate holder, very dense disc-shaped plasma was formed over the substrate when the bias voltage was below -200V. Almsot perfectly oriented diamond films were obtained only in this dense disc-shaped plasma. From the results of the optical emission spectra of the dense disc-shaped plasma, it was found that the concentrations of atomic hydrogen and hydrocarbon radical were increased with negative bias voltage. It was also found that the highly oriented diamonds were deposited in the region, where the intensity ratios of carbonaceous species to atomic hydrogen are saturated.

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Protective SiC Coating on Carbon Fibers by Low Pressure Chemical Vapor Deposition

  • Bae, Hyun Jeong;Kim, Baek Hyun;Kwon, Do-Kyun
    • 한국재료학회지
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    • 제23권12호
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    • pp.702-707
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    • 2013
  • High-quality ${\beta}$-silicon carbide (SiC) coatings are expected to prevent the oxidation degradation of carbon fibers in carbon fiber/silicon carbide (C/SiC) composites at high temperature. Uniform and dense ${\beta}$-SiC coatings were deposited on carbon fibers by low-pressure chemical vapor deposition (LP-CVD) using silane ($SiH_4$) and acetylene ($C_2H_2$) as source gases which were carried by hydrogen gas. SiC coating layers with nanometer scale microstructures were obtained by optimization of the processing parameters considering deposition mechanisms. The thickness and morphology of ${\beta}$-SiC coatings can be controlled by adjustment of the amount of source gas flow, the mean velocity of the gas flow, and deposition time. XRD and FE-SEM analyses showed that dense and crack-free ${\beta}$-SiC coating layers are crystallized in ${\beta}$-SiC structure with a thickness of around 2 micrometers depending on the processing parameters. The fine and dense microstructures with micrometer level thickness of the SiC coating layers are anticipated to effectively protect carbon fibers against the oxidation at high-temperatures.

기공 형성제 조절과 소결 온도의 변화가 다공질 지르코니아 세라믹스의 미세구조 및 강도에 미치는 영향 (Effect of Pore Formers and Sintering Temperatures on Microstructure and Bending Strength of the Porous Zirconia Ceramics)

  • 이은정;송인혁;하장훈;한유동;김양도
    • 한국분말재료학회지
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    • 제18권6호
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    • pp.502-509
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    • 2011
  • In this study, a novel-processing route for fabricating microcellular zirconia ceramics has been developed. The proposed strategy for making the microcellula zirconia ceramics involved hollow microspheres as pore former. Compared to conventional dense microspheres pore former, well-defined pore structured zirconia ceramics were successfully fabricated. Effects of hollow microsphere content and sintering temperature on microstructure, porosity, pore distribution, and strength were investigated in the processing of microcellular zirconia ceramics.

Synthesis of Intermetallics and Nanocomposites by High-Energy Milling

  • Bernd F. Kieback;H. Kubsch;Alexander Bohm;M. Zumdick;Thomas Weissgaerber
    • 한국분말재료학회지
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    • 제9권6호
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    • pp.416-421
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    • 2002
  • Elemental powders are used in high energy milling processes for the synthesis of new compounds. The low temperature solid state reactions during milling in inert gas atmosphere may result in intermetallic phases, carbides, nitrides or silicides with a nanocrystalline structure. To obtain dense materials from the powders a pressure assisted densification is necessary. On the other side the defect-rich microstructure can be used for activated sintering of elemental powder mixtures to obtain dense bodies by pressureless sintering. Results are discussed for nanocrystalline cermet systems and for the sintering of aluminides and silicides.

Synthesis and Characterization of Dense $Ti_{0.5}Zr_{0.5}B_2$ Solid Solutions by Electrically-Stimulated Combustion

  • Lee, H. B.;Kim, S. J.;Y. H. Han;J. E. Garay;Zuhair A. Munir
    • The Korean Journal of Ceramics
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    • 제6권2호
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    • pp.172-176
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    • 2000
  • Solid solutions of Ti$_{0.5}$Zr$_{0.5}$B$_2$were successfully synthesized and densified simultaneously from elemental reactants by the use of a field-activated, pressure-assisted synthesis method. The method involves the application of an electric current and mechanical pressure across reactant compacts to achieve combustion synthesis. Dense solid solutions with relative densities of up to 99% were produced and characterized by XRD, SEM, and EPMA methods. With a maximum measured temperature of 145$0^{\circ}C$ under a load of 86 MPa for 30 min, the desired dense solid solution wad synthesized.

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한국산 땃쥐류 3종에 대한 부정소 미부 정자의 미세구조 (Ultrastructure of epididymal spermatozoa in three Korean shrews)

  • 윤명희;정순정
    • 생명과학회지
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    • 제11권1호
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    • pp.54-61
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    • 2001
  • The comparative morphology of epididymal spermatozoa in the lesser white-toothed shrew, Crocidura suaveolens, the Japanese white-toothed shrew, C. dsinezumi and the big white-toothed shrew, C. lasiura, belonging to the subfamily Crocidurinae was studied with the light and electron microscopes. The spermatozoa of C. lasiura and C. dsinezumi were characterized by the large acrosome, serrated inner acrosomal membrane, common apical body and fistulous proximal centriole with slightly dense electron granular materials, which are the charateristics of the Crocidurinae. The C. suaveolens, however, is distinguished from the two species mentioned above in the sperm morphology. That is, the spermatozoa possess not only the charateristic of the Crocidurinae such aw the large acrosome, but also those of the Soricinae, i.e. the smooth inner acrosomal membrane, wavy, finger-like and electron-dense apical body, and the solid proximal centriole filled with electron-dense materials. The results suggest that C. suaveolens has conserved characteristics of the Soricinae.

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에어로졸 데포지션 법을 이용하여 제조한 SiO2 후막의 구조 및 광학 특성 (Structural and Optical Properties of SiO2 Thick Films by Aerosol Deposition Process)

  • 장찬익;고중혁
    • 한국전기전자재료학회논문지
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    • 제26권1호
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    • pp.6-12
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    • 2013
  • Aerosol deposition(AD) coating that enable fabricate films at low temperature have begun to be widely researched for the integration of ceramics as well to realize high-speed deposition rates. For application of ceramic thick film by AD to display and electronic ceramic industry, fabrication of dense structure with a no cracking is required. In this study, to fabricate dense ceramic thick film, the effect of crystal phase of starting powder was investigated. For this study, amorphous and crystalline $SiO_2$ powders were used as starting powders. Two types of $SiO_2$ powders were deposited on glass substrate by AD. In the case of amorphous $SiO_2$ powder, the deposited films had extremely incompact and opaque layer, irrespective of particle size. In contrast to amorphous powder, in the case of crystalline powder, porous structure layer and dense microstructure with no cracking layer were fabricated depending on the particle size. The optimized starting powder size for dense coating layer was $1{\sim}2{\mu}m$. The transmittance of film reached a maximum of 76% at 800 nm.

고주파유도 가열에 의한 나노구조의 텅스텐 카바이드 급속소결과 기계적 성질 (Rapid Sintering of Nanostuctured Tungsten Carbide by High-Frequency Induction Heating and its Mechanical Properties)

  • 강현수;도정만;홍경태;고인용;손인진
    • 대한금속재료학회지
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    • 제48권11호
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    • pp.1009-1013
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    • 2010
  • Extremely dense WC with a relative density of up to 99% was obtained within five minutes under a pressure of 80 MPa using the High-Frequency Induction Heated Sintering method. The average grain size of the WC was about 71 nm. The advantage of this process is not only rapid densification to obtain a neartheoretical density but also the prohibition of grain growth in nano-structured materials. The hardness and fracture toughness of the dense WC produced by HFIHS were $2660kg{\cdot}mm^{-2}$ and $7.2MPa{\cdot}m^{1/2}$, respectively.