• Title/Summary/Keyword: Delta Expansion

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Synthesis of (Ba0.5Sr0.5)0.99Co0.2Fe0.8O3-δ (BSCF) and the Electrochemical Performance of the BSCF/GDC(Buffer)/ScSZ ((Ba0.5Sr0.5)0.99Co0.2Fe0.8O3-δ(BSCF)의 합성 및 BSCF/GDC(Buffer)/ScSZ의 전기화학적 특성)

  • Lim, Yong-Ho;Hwang, Hae-Jin;Moon, Ji-Woong;Park, Sun-Min;Choi, Byung-Hyun;Lee, Mi-Jai
    • Journal of the Korean Ceramic Society
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    • v.43 no.6 s.289
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    • pp.369-375
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    • 2006
  • [ $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{x}Fe_{1-x}O_{3-{\delta}}$ ] [x=0.8, 0.2](BSCF) powders were synthesized by a Glycine-Nitrate Process (GNP) and the electrochemical performance of the BSCF cathode on a scandia stabilized zirconia, $[(Sc_{2}O_3)_{0.11}(ZrO_2)_{0.89}]-1Al_{2}O_3$ was investigated. In order to prevent unfavorable solid-state reactions between the cathode and zirconia electrolyte, a GDC ($Gd_{0.1}Ce_{0.9}O_{2-{delta}}$) buffer layer was applied on ScSZ. The BSCF (x = 0.8) cathode formed on GDC(Buffer)/ScSZ(Disk) showed poor electrochemical property, because the BSCF cathode layer peeled off after the heat-treatment. On the other hand, there were no delamination or peel off between the BSCF and GDC buffer layer, and the BSCF (x = 0.2) cathode exhibited fairly good electrochemical performances. It was considered that the observed phenomenon was associated with the thermal expansion mismatch between the cathode and buffer layer. The ohmic resistance of the double layer cathode was slightly lower than that of the single layer BSCF cathode due to the incorporation of platinum particle into the BSCF second layer.

The Thermal Properties Analysis of the Mixtures Composed with Epoxy Resin and Amine Curing Agent (에폭시 수지/방향족 아민 경화물의 배합비 변화에 따른 열적 특성 분석)

  • Kim, Daeyeon;Kim, Soonchoen;Park, Young-Il;Kim, Young Chul;Lim, Choong-Sun
    • Journal of Adhesion and Interface
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    • v.15 no.3
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    • pp.100-108
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    • 2014
  • In this work, a series of molar ratios composed with YD-128 and DDM were chosen based on the viscosity analysis. The mixtures of YD-128 and DDM with the different molar ratios were cured at $170^{\circ}C$ for 15 min followed by post cure at $190^{\circ}C$ for two hours. The thermal properties of the cured samples were investigated with DSC, TGA, DMA, and TMA. The conversion ratio of the mixtures of YD-128 and DDM (1 : 1.1) was calculated by dividing ${\Delta}H$ obtained from DSC experiments for each cured sample by ${\Delta}H$. The TGA data of the cured samples showed that the thermal stability and thermal degradation activation energy were proportional to the amount of DDM in the mixtures. However, the highest tan ${\delta}$, and the lowest thermal expansion data with DMA and TMA respectively were obtained from the stoichiometric mixture of YD-128 and DDM. Furthermore, the different ratio of mixtures were applied to test specimens to be cured at $170^{\circ}C$ to measure single lap shear strength with universal testing machine.

Monte Carlo analysis of earthquake resistant R-C 3D shear wall-frame structures

  • Taskin, Beyza;Hasgur, Zeki
    • Structural Engineering and Mechanics
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    • v.22 no.3
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    • pp.371-399
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    • 2006
  • The theoretical background and capabilities of the developed program, SAR-CWF, for stochastic analysis of 3D reinforced-concrete shear wall-frame structures subject to seismic excitations is presented. Incremental stiffness and strength properties of system members are modeled by extended Roufaiel-Meyer hysteretic relation for bending while shear deformations for walls by Origin-Oriented hysteretic model. For the critical height of shear-walls, division to sub-elements is performed. Different yield capacities with respect to positive and negative bending, finite extensions of plastic hinges and P-${\delta}$ effects are considered while strength deterioration is controlled by accumulated hysteretic energy. Simulated strong motions are obtained from a Gaussian white-noise filtered through Kanai-Tajimi filter. Dynamic equations of motion for the system are formed according to constitutive and compatibility relations and then inserted into equivalent It$\hat{o}$-Stratonovich stochastic differential equations. A system reduction scheme based on the series expansion of eigen-modes of the undamaged structure is implemented. Time histories of seismic response statistics are obtained by utilizing the computer programs developed for different types of structures.

LYα LINE FORMATION IN HUBBLE-TYPE SPHERICAL OUTFLOWS IN STARBURST GALAXIES

  • AHN SANG-HYEON;LEE HEE-WON
    • Journal of The Korean Astronomical Society
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    • v.35 no.4
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    • pp.175-185
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    • 2002
  • Almost half of primeval galaxies show P-Cygni type profiles in the Ly$\alpha$ emission line. The main underlying mechanism for the profile formation in these systems is thought to be the frequency re-distribution of the line photons in expanding scattering media surrounding the emission source. A Monte Carlo code is developed to investigate the Ly$\alpha$ line transfer in an optically thick and moving medium with a careful consideration of the scattering in the damping wings. Typical column densities and expansion velocities of neutral hydrogen investigated in this study are $N_{H1}{\~}10^{17-20}\;cm^{-2}$ and ${\Delta}V{\~} 100 km\;s^{-1}$. We investigate the dependence of the emergent profiles on the kinematics and on the column density. Our numerical results are applied to show that the damped Ly$\alpha$ absorbers may possess an expanding H I supershell with bulk flow of ${\~}200 km\;s^{-l}$ and H I column density $N_{H1}{\~}10^{19}\;cm^{-2}$. We briefly discuss the observational implications.

Effect of Electron Beam Irradiation on the Interfacial and Thermal Properties of Henequen/Phenolic Biocomposites

  • Pang, Yansong;Yoon, Sung Bong;Seo, Jeong Min;Han, Seong Ok;Cho, Donghwan
    • Journal of Adhesion and Interface
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    • v.6 no.4
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    • pp.12-17
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    • 2005
  • Natural fiber/phenolic biocomposites with chopped henequen fibers treated at various levels of electron beam irradiation (EBI) were made by means of a matched-die compression molding method. The interfacial property was explored in terms of interfacial shear strength measured by a single fiber microbonding test. The thermal properties were studied in terms of storage modulus, tan ${\delta}$, thermal expansion and thermal stability measured by dynamic mechanical analysis, thermomechanical analysis and thermogravimetric analysis, respectively. The result showed that the interfacial and thermal properties depend on the treatment level of EBI done to the henequen fiber surfaces. The present result also demonstrates that 10 kGy EBI is most preferable to physically modify the henequen fiber surfaces and then to improve the interfacial property of the biocomposite, supporting earlier results studied with henequen/poly (butylene succinate) and henequen/unsaturated polyester biocomposites.

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Mechanical Analysis of Field Coil Deformation in Gas Turbine Generator (가스터빈 발전기의 계자권선 손상에 관한 역학적 분석)

  • Han, Seok-Woo;Kwon, Young-Dong;Choe, Gyu-Ha
    • Proceedings of the KIEE Conference
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    • 1998.07a
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    • pp.107-109
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    • 1998
  • This paper presents mechanical analysis of gas turbine generator (113MVA, $3{\phi}$, 2P, 0.9PF, F class, 3600rpm, 60Hz, 13.8kV, 4.72kA, Air-Cooling) field coil deformation. Rotor end coil deformation is only appeared on turbine end but collector end coil is normal. Expansion direction of end coil is tangential not axial. Deformation appears more severe at top turn. Retaining ling is expanded by centrifugal force of coil and itself. In case friction coefficient between coil top surface and retaining ring insulation inner surface is small, coil end length ${\ell}$ does not change. However, in case friction coefficient big condition, coil end is expanded ${\Delta}{\ell}$ due to start and stop. Deformation is assumed about 30mm by watching photograph inner surface of retaining ring is coated by Teflon at manufacturing condition. Usually Teflon coating insulation surface is small friction coefficient. It's value 0.08${\sim}$0.15. However it's value exceeds more than 0.297. Since top turn deformation appears. The distortion and subsequent failure have occurred because of the lack of a sufficient slip-plane between the top field coil conductors and the inside surface of the retaining ring insulation on the turbine end of the field-winding.

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Quality Characteristics of White Pan Breads Made from Domestic Wheat Flour Added with Deabong Persimmon Puree (대봉감 퓨레를 첨가한 우리밀 식빵의 품질 특성)

  • Ren, Chuanshun;Kim, Ji Myoung;Shin, Malshick
    • Korean journal of food and cookery science
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    • v.30 no.6
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    • pp.695-703
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    • 2014
  • Daebong persimmon puree (DPP) prepared from removing the astringency of persimmon was used as a substitute for water when making the dough of white pan bread using domestic wheat flour, and the resulting, quality characteristics were investigated. The moisture content of DPP was 96.69%, and the dough was made by various levels of substitution of DPP for water (0, 10, 30, 50 and 100%). During fermentation, the expansion power of the dough decreased with increasing DPP levels (p<0.05). The volume, specific volume, baking loss, and the L and ${\Delta}E$ values of the crust and crumb of the breads also decreased with increasing DPP levels. The hardness and chewiness of the bread containing 100% DPP (without water) showed the highest values, but the springiness, cohesiveness and resilience showed the opposite trends. In the difference tests, all attributes except air cell uniformity were significantly different (p<0.05). Bread made with 100% substitution of DPP for water achieved the highest scores for flavor, taste and overall acceptability.

Physicochemical Properties of Rice Extrudate Added with Onion Kimchi Powder (양파김치 분말을 첨가한 쌀 압출팽화물의 이화학적 특성)

  • Keawpeng, Ittiporn;Kang, Seong-Koo;Park, Yang-Kyun
    • Food Science and Preservation
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    • v.14 no.5
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    • pp.504-510
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    • 2007
  • An extrusion process was to make an onion kimchi snack from rice grit and onion kimchi powder, in an effort to enhance the nutritional value, flavor, and physicochemical properties of the extrudate. This study investigated optimum conditions (moisture content, barrel temperature, and the content of onion kimchi powder) for the production of high-quality rice extrudate products, and measured quality properties (water absorption index, texture, expansion ratio, and color) of rice extrudate to which onion kimchi powder had been added. Onion kimchi powder at 3%, 5%, 7%, and 10% (all w/w) was mixed with rice grit and the mixture then extruded in a twin-screw extruder. The texture of onion kimchi mack became softer as onion kimchi powder level rose, and water absorption ability increased. The expansion ratio and the lightness of extrudates decreased with increases in onion kimchi powder levels. The maximum water absorption index am the minimum hardness were obtained with 10% onion kimchi powder. Rice extrudate with 10% onion kimchi powder was suitable for extrusion cooking md obtained the highest score for overall acceptability by sensory evaluation.

Thermoelectric Properties of Skutterudite CoSb3 Prepared by Arc Melting (아크용해법으로 제조된 Skutterudite CoSb3의 열전특성)

  • Yu S.W.;Park J.B.;Cho K.W.;Jang K.W.;Ur S.C.;Lee J.I.;Kim I.H.
    • Korean Journal of Materials Research
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    • v.15 no.2
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    • pp.93-96
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    • 2005
  • The arc melting was employed to prepare undoped $CoSb_3$ compounds and their thermoelectric properties were investigated. Specimen annealed at $400^{\circ}C$ for 24 hrs showed sound microstructure. However, considerable voids and cracks were found after annealing at above $500^{\circ}C$. It seems to be attributed to the phase dissociation and thermal expansion due to phase transitions during annealing and cooling. Single phase $\delta-CoSb_3$ was successfully obtained by annealing at $400^{\circ}C$ for 24 hrs. In the case of increasing annealing temperature, phase decompositions occurred. Undoped $CoSb_3$ showed p-type conduction and intrinsic semiconducting behavior at all temperatures examined. Thermoelectric properties were remarkably improved by annealing and they were closely related to phase transitions.

An Experimental Study on the Effects of Tabs and Small Proturbances Inside Nozzle on Supersonic Jet Flowfield (노즐 탭과 노즐 내부 낮은 돌출부가 초음속 제트유동장에 미치는 영향에 관한 연구)

  • Jin, Won-Jin;Cho, Chang-Kwon;Lee, Yeol;Yoon, Woong-Sup
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.5
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    • pp.24-31
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    • 2002
  • The effects of vortex generators, in the form of small delta-shaped tabs or thin tapes at an axi-symmetric supersonic nozzle exit, on the characteristics of supersonic jet flowfields are investigated by Schlieren images and Pitot-tube measurements. Small tabs as small as 1 % of the nozzle exit area can introduce streamwise vortices and produce a significant effect on the jet flowfield downstream of the nozzle. The effect is stronger for the cases of under-expanded jet than over- and perfect-expanded cases, introducing a larger flow entrainment. The effects of the angle of tabs with respect to the flow direction are also investigated, and for over-expanded jet cases, it is found that the tabs bended toward upstream can weaken the interaction strength and remove the Mach disc in the jet flowfield. Introduction of small proturbances inside the nozzle surface by attachment of thin tapes is also found to change the pressure distribution in the circumferential direction of the flowfield. Its effect is also found to be dependent on the jet expansion ratio.