• Title/Summary/Keyword: Degree of substitution

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Retention and Drainage Characteristics of Compozil System and Impact of Cationic Corn Starch for its Improvement (콤포질 시스템의 보류 및 탈수특성과 양성 옥수수전분을 이용한 성능 개선)

  • 이학래;김태영;윤혜정
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.2
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    • pp.30-39
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    • 1998
  • Effect of cationic starches and anionic colloidal silica on retention and drainage characteristics of Compozil system was investigated. Depending upon the degree of substitution and molecular weight of cationic starches and morphological characteristics of anionic colloidal silica, retention and drainage properties of Compozil system were significantly influenced. When cationic starch addition level increased above a certain limit retention and stock freeness were decreased. To elucidate this an electrostatic coagulation mechanism occurring between unadsorbed starch molecules and anionic colloidal silica was proposed. Unstructured colloidal silica showed greater improvement in retention than structured colloidal silica. Cationic corn starches with different degree of substitution and molecular weights were prepared and their effect as a constituent of Compozil system was also evaluated. By controlling the molecular weight and degree of substitution of cationic corn starch it was possible to achieve significant improvement in fines retention. Cationic corn starch with higher degree of substitution maintained its retention efficiency even when the stock conductivity was increased. Turbidity measurement technique was found to be a simple and useful method to measure the retention characteristics.

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Mechanical Properties of Rice Noodles When Adding Cellulose Ethers (셀룰로오스 에테르를 첨가한 쌀면의 기계적 물성)

  • Um, In Chul;Yoo, Young Jin
    • Current Research on Agriculture and Life Sciences
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    • v.31 no.3
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    • pp.177-181
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    • 2013
  • This study examined the effect of the molecular weight, substitution degree, and substitution type of cellulose ether on the mechanical properties of dried rice noodles. When increasing the molecular weight of the hydroxypropyl methylcellulose (HPMC), the bending strength of the dried rice noodles also increased. However, the bending strength of the rice noodles with added HPMCs was still lower than that of the wheat noodles. Meanwhile, the bending elongation of the dried rice noodles was higher than that of the wheat noodles and was increased when decreasing the molecular weight of the HPMC. In conclusion, the bending strength and elongation of dried rice noodles is affected by the substitution degree and type of cellulose ether.

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Research of stone pagoda weathering degree from contaminated distribution analysis of 10-storied pagoda in the temple of Kyoungchunsa (경천사십층석탑의 오염물분포별 현황조사를 통한 석탑 풍화도에 관한 연구)

  • Kim, Jin-Hyoung;Lee, Joo-Wan;Kang, Dai-Ill
    • 보존과학연구
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    • s.25
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    • pp.75-92
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    • 2004
  • The conservation treatments of 10-storied pagoda in the temple of Kyoungchunsa is progressed favorably to come to the finish since 1995. Most of all, the important conservation treatments are stone crack, exfoliation and partial form modification. This pagoda has been made up a complicated structure constructed using 142 stones. Therefore, the stone crack and exfoliation have been occurred as very varied forms. Especially, the stylobate of the pagoda has 19 substitution stones of 48 stones, which is40% of modern stone substitution. It is supposed that there is serious weathering on the stones. The other stones, which are no substitution stones, have some kinds of weathering and so we carried out inside replenishment and partial outside reconstruction of crack stones using high molecular resin and substitution stone. The stone of each storey has also partial difference, but the condition of serious weathering on the whole. We can detect general degree through treatment of high molecule resin or distribution research of contaminated material on 10-storied pagoda in the temple of Kyoungchunsa. Especially, we are able to analyze general weathering degree and know details weathering of each storey or direction for the difference of replenishment quantity and different pattern of stone crack degree. Also, the distribution research will accomplish very important parts of examining environment effects and use as research data of cultural heritage conservation field.

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The Analysis of Manufactured Cellulose Acetate Using Old Newsprint by Acetosolv Pulping (초산펄프화법에 의해 신문고지로부터 제조된 셀룰로오스 아세데이트의 분석)

  • 임부국;이종윤;양재경;장준복
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.1
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    • pp.41-47
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    • 2003
  • Recently, interest in utilization plan of recycling paper have been enhanced. Therefore, this research aimed to develop the manufacture process of cellulose acetate using old newsprint by acetosolv pulping process. And the manufactured cellulose acetate was also analyzed, especially based on chemical properties. The summarized results in this research were as follows; Reaction time, kind and amount of catalyst, and ratio of liquor to material were varied during acetosolv pulping process of old newsprint. Ratio of liquor to material did not give the significant difference in reaction product. Delignification rate was increased with increasing reaction time during acetosolv pulping, but yield and degree of substitution decreased with increasing reaction time. Sulfuric acid are better catalyst than hydrochloric acid in acetosolv pulping process for old newsprint, and optimal addition amount of catalyst was 1% based on reaction material. Delignification, yield, and degree of substitution were influenced by the catalyst and reaction time. Under pulping condition of $120^{\circ}C$ in 1/12 liquor to material ratio and 60min, degree of substitution was about 0.7. The acetylation reaction was not completely caused by these reaction condition. The examination of the FT-IR spectra revealed that absorption band(1200$\textrm{cm}^{-2}$, 1,750$\textrm{cm}^{-1}$) caused by carbonyl group were confirmed.

Study on the Factor of Water Retention Capacity of Cement Mortar by Hydroxyalkyl Methylcellulose Ether (히드록시알킬 메틸셀룰로오스가 시멘트 모르타르의 보수성에 미치는 영향에 관한 연구)

  • 이무진
    • Journal of the Korea Concrete Institute
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    • v.11 no.3
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    • pp.153-160
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    • 1999
  • Water soluble hydroxyalkyl methycellulose ethers are used in a variety of applications incluing building industry as a supplementary agent used for incresing adhesives, water retention capacity, workability and viscosity modify. Water retention capacity(WRC) is the capability to contain water in the ploymer chain under condition of being mixed with cement. In general, the WRC is affected by the viscosity, the adding amount, the particle size, the rate of dissolving and the amount of substituted chemical in cellulose ethers. In the other words, WRC is increased as higher the viscosity, more adding amount, finer the particle size and longer the dissolving time of cellulose ethers. This thesis investigated each factor that effect the WRC, particularly the relation between degree of substitution(DS), molar of substitution(MS) and WRC. It is observed that WRC is not nearly affected by DS of cellulose ethers, but is changes proportionally as MS increases in the narrow range(0.10~2.25)

Dollarization in North Korea: Evidence from a Survey of North Korean Refugees

  • Mun, Sung Min;Jung, Seung Ho
    • East Asian Economic Review
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    • v.21 no.1
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    • pp.81-100
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    • 2017
  • This study measures the degree of dollarization in North Korea using results from a survey of 231 North Korean refugees. Specifically, we compare foreign currency use of households as both store-of-value substitutes (i.e., asset substitution) and transaction substitutes (i.e., currency substitution) before and after the confiscatory currency reform of 2009. The degree of dollarization has advanced since the currency reform in terms of both asset and currency substitutions. Survey results also indicate that the Chinese yuan is frequently used in the Sino-North Korean border area, whereas the US dollar is predominantly used in non-border areas. Furthermore, foreign currency increasingly serves as a medium of exchange not only for large transactions but also for smaller transactions, such as food purchases.

Generation Z and Its OTT Usage Patterns: The Case of Netflix in Korea

  • Ahn, Jungah
    • International Journal of Contents
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    • v.18 no.1
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    • pp.65-75
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    • 2022
  • This study aims to reveal the various differences within the factors that influence use satisfaction, continuous use intention, and media substitution intention, specifically in regard to the use motives and use behaviors of Netflix viewers. This study's results demonstrate that the following various factors affected use satisfaction, continuous use intention, and media substitution intention in differential ways. Firstly, the diversity of content influenced use satisfaction to a greater degree than social relations; and the diversity of content, social relations, and active participation all positively influenced continuous use intention. In other words, the more positively users appreciated the diversity of content, and the more strongly they had social relations, and the more actively they participated within communities, the greater degree to which they increased their continuous use intention for Netflix. However, the diversity of content and the convenience of use also had a negative effect on the media substitution intention for Netflix, which means that the more diverse the content and the more convenient the use of Netflix, the fewer the number of users who intended to cancel Netflix and subscribe to another OTT service or resubscribe to traditional media sources.

Effects of Ammonia Swelling Treatment in Carboxymethylation of Domestic Kraft Pulp on Characteristics of Corboxymethylcellulose(CMC) and CMC Solution (국산(國産) 크라프트 펄프의 카르복시메틸화시(化時) 암모니아 팽윤처리(膨潤處理)가 카르복시메틸셀룰로오스와 카르복시메틸셀룰로오스 용액(溶液)의 특성(特性)에 미치는 효과(效果))

  • Ahn, Byoung-Kuk;Ahn, Won-Yung
    • Journal of the Korean Wood Science and Technology
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    • v.18 no.2
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    • pp.25-35
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    • 1990
  • To investigate the effects of swelling treatment by ammonia on characteristics of carboxymethy1cellulose(CMC) and CMC solution, the domestic kraft pulp pretreated with 5%, 10%, 15% and 20% $NH_4OH$ solution, was carboxymethylated by the standard method, and then the CMC prepared was tested. The physical properties of CMC and CMC solution, such as degree of substitution, transparency. viscosity, weight increase and solubility, were measured, and the comparison with commercial domestic CMC used as a food additive was done. The results obtained were as follows; 1. In CMC manufactured by standard solvent method, hardwood bleached kraft pulp(LBKP) was more substituted than safwood bleached kraft pulp(NBKP), and viscosity of NBKP was higher than that of LBKP. 2. When ammonia swelling treatment was done, degree of substitution gradually decreased with increasing concentration of $NH_4OH$, and degree of substitution of LBKP decreased with a larger range than that of NBKP. 3. When ammonia swelling treatment was done. transparency of CMC solution from LBKP was hardly effected, but in case of NBKP gradually increased with increasing concentration of $NH_4OH$. 4. When ammonia swelling treatment was done, viscosity of CMC solution was higher than that of CMC solution without ammonia swelling treatment. Especially, CMC of high viscosity could be manufactured in 5%, 10% concentration levels of $NH_4OH$. 5. In CMC manufactured from domestic NBKP, CMC at the range of 0.40 to 0.50 in DS was dispersed easily and quickly dissolved, and CMC at more than 0.50 in DS was dispersed slowly in water solution. 6. In comparison with commercial domestic CMC used as a food additive, CMC manufactured from domestic NBKP was higher in DS, and was lower in viscosity and transparency.

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Total Utilization of Woody Biomass by Steam Explosion(II) -The Preparation of Carboxymethylcellulose from Exploded Wood- (폭쇄법(爆碎法)을 이용(利用)한 목질계(木質系) biomass의 종합적(綜合的) 이용(利用)(II) -폭쇄재(爆碎材)로부터 Carboxymethyl cellulose의 제조(製造)-)

  • Han, Sang-Yeol;Chang, Jun-Pok;Lee, Jong-Yoon
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.2
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    • pp.30-36
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    • 1994
  • Steam explosion process is one of the most efficient, pretreatment method for the utilization of lignocellulosic biomass. The carbxymethyl-cellulose(CMC) was prepared with steam exploded wood(EXW), pine(Pinus densiflora) and oak(Quercus mongolica), by standard method using isopropyl alcohol and monochloroacetic acid. The range of water solubility of carboxymethylated pine exploded wood was 45.2~66.8 % and those of oak was 60.7~84.7 %. The degree of substitution(D.S) of carboxymethylated pine exploded wood was 0.11~0.33 and oak exploded wood was 0.48~0.76. The color of carboxymethylated pine and oak exploded wood was brown-black. When carboxymethylated EXW was purified by sulfuric acid, the yield of carboxymethylated wood was lower than non-treated one. However, the color was still brown-black although after delignification. In carboxymethylated EXM prepared after delignification, the water solubility and degree of substitution(D.S) of pine were 81.4~95.9 % and 0.71~0.79, and those of oak were 76.2~89.5 % and 0.79~1.05. The values were higher than non-treated. The degree of substitution of purified carboxymethylated wood prepared with delignified EXM, pine and oak were 0.50~0.71 and 0.70~0.88. The color of carboxymethylated wood was white. In carboxymethylated wood preparde after delignification of EXM, swelling ratio and water retention value of pine were 95.9~96.5 and 580.0~751.2, those of oak were 76.2~89.5 and 124.3~307.6.

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Synthesis of Various Siloxylcellulose Derivatives (Siloxylcellulose 유도체의 합성)

  • Hong, Jae-Jin;Yang, Jae-Kun
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.275-280
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    • 1999
  • Cellulose has three hydroxyl groups with different reactivity. By substitution reaction, trimethylsiloxyl-, vinyldimethylsiloxyl-, allyldimethylsiloxyl-, phenyldimethylsiloxyl-, 3,3,3-trifluoropropyldimethylsiloxyl- and tris(trimethylsiloxy)siloxylcellulose were synthesized IR, NMR, and elemental analysis were used for confirming their structures, degree of substitution (D.S.) and the reactivity of siloxylation agent, respectively. The D.S. values were 2.5, 2.2, 2.1, 2.2, 2.6, 0.7 for the corresponding siloxylcellulose.

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