• Composites Research
• /
• 제27권3호
• /
• pp.90-95
• /
• 2014

복합재료의 경화 시 발생하는 수축 변형률은 복합재료 구조물 내에 잔류응력을 발생시키며 이러한 잔류응력은 spring-in, spring-out, warpage와 같은 구조물 변형의 원인이 된다. 본 연구에서는 Hexcel사의 "Hexply M21EV/34%/UD268NFS/IMA-12K" prepreg를 사용하였다. 시험편의 경화에 따른 cure shrinkage 변화를 DSC(differential scanning calorimetry)와 TMA(thermomechanical analyzer)를 이용하여 측정하였다. 수지의 수축률은 $140{\sim}240^{\circ}C$ 구간에서 $20^{\circ}C$ 간격으로 질소 분위기에서 측정하였다. 경화도는 dynamic과 isothermal DSC scanning을 통하여 측정된 반응열을 이용하여 산출하였으며, DSC 시험은 Argon 분위기에서 수행하였다. 시험결과, 열경화성 수지는 27~80% 경화도에서 급격한 수축이 일어났으며, 경화온도가 높을수록 더 낮은 경화도에서 수축이 시작되는 것을 알 수 있었다.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2001년도 추계학술대회논문집A
• /
• pp.797-803
• /
• 2001

The on-line cure monitoring of fiber reinforced thermosetting resin matrix composite material was performed for the better quality and productivity during manufacturing. Since the dissipation factor measured by dielectrometry method is dependent on the degree of cure and temperature of resin, in this study, a new method to obtain the degree of cure during on-line cure monitoring for glass/polyester composites was developed by employing a combination function of the temperature and the dissipation factor. Two sensor signals from a K-type thermocouple and an interdigitated dielectric sensor were processed during curing process under various cure cycles. The DSC (Differential Scanning Calorimetry) data was also used for the reference of degree of cure.

• 대한기계학회논문집
• /
• 제19권9호
• /
• pp.2154-2164
• /
• 1995

In this study, a dielectric cure monitoring system which consists of an electric circuit, a sensor and a personal computer was developed to on-line monitor the dielectric properties of carbon fiber epoxy composite materials. Also, the kinetic model of carbon fiber epoxy composite materials was developed by curve fitting of differential scanning calorimetry data. The start and end points of cure and the relationship between the dissipation factor and the degree of cure were obtained by comparing the dissipation factor from the dielectric properties with the degree of cure from the DSC data. The relationship between the dissipation factor and the degree of cure was tested under various temperature profiles.

• 비파괴검사학회지
• /
• 제23권5호
• /
• pp.409-417
• /
• 2003

열경화성 수지 복합재료의 제조과정에서 제품의 품질과 생산성 향상에 필수적인 경화 모니터링 기술을 개발하였다 경화도를 분석하기 위해, 동일한 경화조건에서 유전기법에 의한 소산계수 측정결과와 시차 주사 열분석 방법에 의한 발열량 계측 결과를 비교하였으며, 계측 감도의 향상을 위해 센서부분과 계측선의 영향을 적절히 분리하는 방법을 사용하였다. 유리섬유/폴리에스터 복합재료와 유리섬유/에폭시 복합재료에 대하여 경화과정에서의 경화도 분석을 위한 새로운 경화 모니터링 방법으로 소산계수와 온도를 동시에 고려하였다. 이 때, 소산계수의 변화 경향은 수지 점도의 변화 양상과 비교하여 분석하였다 개발된 경화 모니터링 방법은 다양한 종류의 열경화성 복합재료 경화 모니터링에 사용될 수 있다.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2001년도 춘계학술발표대회 논문집
• /
• pp.219-223
• /
• 2001

The on-line cure monitoring during the cure process of composite materials is important for better quality and productivity. The dielectric sensor for cure monitoring consists of base film and electrodes. Because the characteristic of dielectric sensor for the on-line cure monitoring is dependent on the base material, width and number of electrode, etc, the dielectric sensor should be standardized. And the selection of base film material of sensor is very important. In order to prevent the measuring errors generated from the increase of environmental temperature, the base film material should have stable dielectric constant with respect to environmental temperature. In this study, the newly developed dielectric sensor for cure monitoring was designed and the dissipation factor which is function of degree of cure was measured using the sensor. The relationship between the dissipation factor and degree of cure with respect to environmental temperature was investigated.

• Restorative Dentistry and Endodontics
• /
• 제20권1호
• /
• pp.33-54
• /
• 1995

The degree of conversion of composite resin was known to have influence on the mechanical properties of composite materials such as hardness, strength, wear resisitance, dimensional and color stability. Also unreacted monomer was reported to be harmful to the pulp. So the degree of conversion was a very important factor in the success of composite resin restorations. In recent, the dual cure resin cement was developed with the advocations that it could increase the curing rates in the sites where the curing ligt could not reach. Moreover many manufactors added some adhesive components in the resin cement. This study was undertaken to observe the effects of curing depth and light curing times on the degree of conversion of dual cure resin cements. CR INLAY CEMENT, DUAL CEMENT and OPTEC BOND, by the Fourier transform Infrared analysis, changing the curing depth 1mm, 2mm and 3mm, and varying the light curing time 20 seconds, 40 seconds and 80 seconds at each depth. The cytotoxicity of dual cure resin cements was tested by the in vitro MTT method using L929 cell. The results was evaluated and compared statistically. The results were obtained as follows : 1. The dual cure resin cements reavealed various degree of conversion, CR INLAY CEMENT and DUAL CEMENT had a tendency to be more reactive to the light cure and OPTEC BOND was a more chemical one. 2. CR INLAY CEMENT and DUAL CEMENT showed the lowest degree of conversion in 2 mm depth, and in 3mm depth the degree of conversion increased, which were due to the chemical cure of dual cures, but OPTEC BOND showed decreasing degree of conversion with increasing curing dept h and all experimental groups showed lower degree of conversion than CHEMICAL group which cured in dark room with no light, so the weak light-curing of dual cure resin cement prevented the chemical cure. (P<0.05) 3. CR INLAY CEMENT and DUAL CEMENT showed increasing degree of conversion in 1 mm and 3 mm, according to the increasing cure times, but in 2 mm depth the degree of conversion decreased with increasing light-curing times and OPTEC BOND showed contrary tendency, but there was no ststistical importance in the differences among the experimental group.(P>0.05) 4. The optical density by MTT assay of extractions of CR INLAY CEMENT, DUAL CEMENT and OPTEC BOND revealed no statitically important differences comparing with optical density of negative control.(P>0.05) 5. CR INLAY CEMENT showed a tendency of increaing cytotoxicity with days and DUAL CEMENT and OPTEC BOND showed higher cytotoxicity in 2 days than in 4 days, but there was no statistical importance in the differences.(P>0.05).

• Elastomers and Composites
• /
• 제33권4호
• /
• pp.281-289
• /
• 1998

4종류의 고무 즉, 천연고무(NR), styrene-butadiene copolymer(SBR), ethylene-propylene diene monomer(EPDM), brominated isobutylene-p-methyl-styrene copolymer(BIMS)의 영(Young) 탄성율을 비롯한 인장특성과 인열강도를 여러가지 가교도와 시험온도에서 측정하였다. 과가황(over-cure)의 영향을 조사하기 위해 과가교 고무컴파운드의 인장강도와 팽윤(swelling) 거동도 조사하였다. 모든 고무컴파운드에 대해 영 탄성율(E)은 가교도와 선형적인 비례관계를 보였다. EPDM이 가장 높은 기울기를 그리고 BIMS가 가장 낮은 기울기를 보였고, NR과 SBR은 이들 사이의 값을 나타내었다. 인열강도 Gc는 NR>BIMS>SBR>EPDM의 순으로 나타났다. 과가교에 따라 NR과 SBR의 가교도는 감소한 반면, BIMS는 오히려 증가하였고, EPDM은 거의 변하지 않았다.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2000년도 추계학술발표대회 논문집
• /
• pp.42-45
• /
• 2000

The properties of thermosetting resins are dependent on the degree of cure and consolidation quality. Since the consolidation process of thermosetting resin matrix fiber composites is much dependent on the viscosity of resin in the composites, in this study, the dissipation factor which is a function of viscosity was measured by the newly developed Lacomtech dielectrometry apparatus and sensors. Using the measured dissipation factors, the relationship between the dissipation factor and degree of cure with respect to environmental temperature was investigated.

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2001년도 춘계학술대회 논문집
• /
• pp.32-36
• /
• 2001

Recently, reaction injection molding has been used broadly for rapid prototyping, because of its convenience and versatility. Since the properties of molded products are dependent on the process variables and the production is very short(less than 2minutes), the control of process variables is important. Generally, the two significant process variables are degree of cure and temperature of the reactants. In this paper, the relation between the degree of cure and the temperature of reactants was investigated to find the optimal curing condition of reaction injection molding for rapid prototyping. The degree of cure during reaction injection molding was measured by the Lacomtech sensor and dielectrometry equipment employing Wheatstone bridge type circuit.

• Composites Research
• /
• 제30권3호
• /
• pp.202-208
• /
• 2017

RTM은 작은 크기에서 큰 크기의 복합재료를 생산할 수 있는 대량 생산 공정이다. 최근 경화 시간이 약 10분 이내인 속경화 수지가 자동차 및 항공우주 산업에 사용되고 있다. 수지의 점도는 경화 정도와 관련이 있으며, 금형 내부로 충진되는 과정에서 급격히 점도가 변할 수 있다. 따라서 속경화 수지의 유동 특성과 경화도를 해석적으로 예측하는 데 많은 노력이 필요하므로 실험적으로 측정하고 평가하는 것이 유리하다. 복합재료의 경화도를 측정하는 방법은 대표적으로 DMA, 유전기법 등이 있다. 본 논문에서는 다채널 경화 모니터링 시스템을 이용하여 속경화 수지의 유동과 경화도를 측정하였다. 총 8채널의 유전센서가 사용되었으며, 다양한 압력 조건에 따른 금형 내부의 유동과 경화도를 측정하고 상호 비교하였다.