• Title/Summary/Keyword: Degradation parameters

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광촉매 반응에 의한 환경호르몬 분해특성

  • 박재홍;안상우;장순웅
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.358-361
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    • 2004
  • The photocatalytic degradation of Endocrine Discruptors, dibuthyl phthalate(DBP) has been investigated over TiO$_2$ photocatalysts irradiated with a ultraviolet (UV) light. The effect of operational parameters, i.e., reaction time, light intensity, pH and additive on the degradation rate of aqueous solution of Endocrine Discruptors has been examined. Results show that the employment of efficient photocatalysts and the selection of optimal operational parameters may lead to degradation of Endocrine Discruptors solutions.

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Effect of dielectric barrier discharge parameters on degradation efficiency of ethyl acetate

  • Deng, Xu;Lu, SiHeng;Zheng, Kun;Yu, ZhiMin
    • Journal of Urban Science
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    • v.8 no.2
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    • pp.13-18
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    • 2019
  • Using self-made coil dielectric barrier discharge reactor, the removal efficiency of ethyl acetate under simulated experimental parameters such as initial concentration of waste gas, total flow rate, relative humidity and voltage was investigated. The results show that the degradation rate of ethyl acetate increases with the increase of output voltage. When other conditions remain unchanged, the degradation rate decreases with the increase of initial concentration of ethyl acetate; with the increase of total flow rate, the degradation rate of ethyl acetate decreases; with the increase of relative humidity, the degradation rate first increases and then decreases, and when the relative humidity is 64%, the degradation efficiency is the highest.

Determination of New Parameter for Materials Degradation Using Continuous Indentation Testing Technique (연속압입 시험기법을 이용한 석유화학설비 경년손상의 새로운 평가변수 고찰)

  • Jang, Jae-Il;Choi, Yeol;Son, Dongil;Lee, Yun-Hee;Kwon, Dongil;Kim, Jeoung-Tae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.5
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    • pp.881-889
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    • 2002
  • Newly developed continuous indentation technique has made nondestructive assessment of tensile properties possible. The present study was undertaken to determine new parameters for indicating time-dependent material degradation of petro-chemical plant. Continuous indentation tests were performed for Cr-Ni steel and Cr-Mo steel which are widely used as facilities of petro-chemical plant. From the results, it was found that yield strength and tensile strength cannot be used as general degradation parameters because the changes in the strengths with aging time didn't show any tendency. On the other hand, work hardening exponent and yield ratio showed consistent tendency with increasing aging time. Therefore, nam attention of this work was paid on them as new degradation parameters, and the in-field applicability of the parameters was evaluated and discussed.

Determination of Kinetic Parameters for Texture Changes of Sweet Potatoes during Heating (고구마 조직의 가열변화에 대한 반응속도론적 상수 결정)

  • Lee, Jung-Ju;Rhim, Jong-Whan
    • Korean Journal of Food Science and Technology
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    • v.33 no.1
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    • pp.66-71
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    • 2001
  • Kinetic parameters for the texture degradation of three varieties of sweet potato during heating were determined using two alternative methods, the biphasic model and the fractional conversion method. The texture degradation of sweet potatoes during heating could be expressed by two simultaneous first order reactions using the biphasic method, whose activation energies were ranged $71.0{\sim}75.1\;kJ/mol\;and\;48.4{\sim}59.6\;kJ/mol$ for the initial fast texture degradation reaction and the slow texture degradation reaction at a prolonged heating period, respectively. However, the whole texture degradation phenomena of sweet potatoes during heating could also be explained by a single first order reaction using the fractional conversion method. The activation energies were $67.5{\sim}75.3\;kJ/mol$, which were comparable with those of the first phase reaction for the texture degradation determined by the biphasic model. A kinetic compensation effect shown between the kinetic parameters determined by both methods indicates that both methods can be conveniently used to determine kinetic parameters for the texture degradation of sweet potatoes by heating.

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Analysis of Luminance Degradation characteristics of OLED using the Hotplate (핫플레이트를 이용한 OLED의 휘도열화특성 분석)

  • Kim, Yun-Cheol;Lee, Duek-Jung;Jang, Joong-Soon
    • Journal of Applied Reliability
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    • v.16 no.4
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    • pp.356-363
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    • 2016
  • Purpose: The purpose of this study is to propose efficiency of equipment testing the luminance degradation of OLED. Methods: The degradation model of Exponential model and Stretched exponential model is analyzed by goodness of fit test using calculated R-square. The degradation model having the higher R-square is finally selected. Scale parameter and Shape parameter using the selected degradation model is estimated. The activation energy and current density n using peck model among the accelerated model is estimated. the estimated parameters are analyzed by t-test. Results: The results of t-test show that the estimated parameters on chamber and hotplate are equal statistically. we can know the similarity of the luminance degradation rate and degradation pattern on chamber and hotplate. Conclusion: The result of the degradation test on chamber and hotplate is similar. when the accelerated degradation test on the panel of the OLED TV is performed, hotplate is requiring less samples, time and cost than chamber. so the accelerated degradation test on the panel of the OLED TV using the hoplate is efficient of time and cost.

Evaluation of Bioremediation Effectiveness by Resolving Rate-Limiting Parameters in Diesel-Contaminated Soil

  • Joo, Choon-Sung;Oh, Young-Sook;Chung, Wook-Jin
    • Journal of Microbiology and Biotechnology
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    • v.11 no.4
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    • pp.607-613
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    • 2001
  • The biodegradation rates of diesel oil by a selected diesel-degrading bacterium, Pseudomonas stutzeri strain Y2G1, and microbial consortia composed of combinations of 5 selected diesel-degrading bacterial were determined in liquid and soil systems. The diesel degradation rate by strain Y2G1 linearly increased $(R^2=0.98)$ as the diesel concentration increased up to 12%, and a degradation rate as high as 5.64 g/l/day was obtained. The diesel degradation by strain Y2G1 was significantly affected by several environmental factors, and the optimal conditions for pH, temperature, and moisture content were at pH8, $25^{\circ}C$, and 10%, respectively. In the batch soil microcosm tests, inoculation, especially in the form of a consortium, and the addition of nutrients both significantly enhanced the diesel degradation by a factor of 1.5 and 4, respectively. Aeration of the soil columns effectively accelerated the diesel degradation, and the initial degradation rate was obviously stimulated with the addition of inorganic nutrients. Based on these results, it was concluded that the major rate-limiting factors in the tested diesel-contaminated soil were the presence of inorganic nutrients, oxygen, and diesel-degrading microorganisms. To resolve these limiting parameters, bioremediation strategies were specifically designed for the tested soil, and the successful mitigation of the limiting parameters resulted in an enhancement of the bioremediation efficiency by a factor of 11.

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Quality of Service Parameters Estimation Model for Adaptive Bandwidth Service in Mobile Cellular Networks (적응형 서비스를 제공하는 이동통신망에서의 서비스 품질 척도 추정 모델)

  • Jung, Sung Hwan;Hong, Jung Wan;Lie, Chang Hoon
    • Journal of Korean Institute of Industrial Engineers
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    • v.33 no.1
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    • pp.153-163
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    • 2007
  • An adaptive framework paradigm where the bandwidth values of the ongoing calls vary according to the trafficsituations is one of the promising concepts for overcoming poor resource conditions due to handoffs in mobilecellular networks. However, quantifying the level of bandwidth degradation of the ongoing calls in an adaptiveframework is important in view of Quality of Service (QoS) Provisioning. Therefore we introduce new QoSparameters, the Degradation Degree Ratio (DDR), which represents the average portion of the degradationdegree during degradation pehod of a call, and the Degradation Area Ratio (DAR), which represents the averageratio of a call's degradation level considering both the period and the degree of degradation jointly in multi-levelbandwidth service. We also develop a new analytical model for estimating the QoS measures such as theDegradation Pehod Ratio (DPR), DDR and DAR. We show how to calculate the QoS measures and illustrate themethod by numerical examples. The proposed model can be used to determine the optimal parameter of theCAC scheme and analyze the sensitivity ofthe QoS parameters in adaptive networks.

Effects of Operating Parameters on Dissolved Ozone and Phenol Degradation in Ozone Contact Reactor (오존 접촉 반응기의 용존 오존 농도 및 페놀 분해에 미치는 운전변수의 영향)

  • Chung, Jae-Woo;Park, Jeong-Wook;Lee, Chun-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.3
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    • pp.241-247
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    • 2010
  • The Effects of operating parameters such as initial pH, gaseous ozone concentration, supplied gas flow rate on dissolved ozone concentration and phenol degradation in ozone contact reactor were investigated. Dissolved ozone concentrations were saturated to constant values after a certain ozone contact time. The saturation values were influenced by experimental parameters. Dissolved ozone concentration decreased with the increase of initial pH because the ozone is unstable in high pH regions. The gaseous ozone concentration in a constant gas supply affected the saturation concentration of dissolved ozone and the injection rate of gas with a constant ozone concentration determined the rate to reach dissolved ozone saturation. Effects of operating parameters on phenol degradation were closely related with those of parameters on dissolved ozone concentration. Phenol degradation was enhanced by the increase of initial pH, because the degradation of dissolved ozone gave birth to free radicals which have much higher reactivity with phenol. Increase of gaseous ozone concentration and gas flow rate promoted the phenol degradation through the generation of dissolved ozone which plays the role in phenol degradation. The injection of methanol deteriorated the phenol degradation through the scavenging effect on OH radicals.

Degradation of methyl orange by pulsed corona discharges in aqueous solution (수중 펄스코로나 방전에 의한 메틸오렌지 제거 특성)

  • Lee, Hyeon-Don;Kim, Jong-Oh;Kim, Hyoung-Kab;Chung, Jae-Woo
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.1
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    • pp.69-76
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    • 2012
  • A laboratory experiment on methyl orange degradation in pulsed corona discharges was carried out. Effects of operating parameters such as applied voltage, pH, conductivity and initial concentration on methyl orange degradation were investigated. The pulsed corona discharges decreased the pH of solution and increased conductivity, probably due to products generated from methyl orange degradation by corona discharges. The decrease of initial pH enhanced the methyl orange degradation. The methyl orange degradation was fastest in $100{\mu}S/cm$ conductivity solution, followed by 50 and $200{\mu}S/cm$, indicating that $100{\mu}S/cm$ is the most favorable in the aspect of radical generation among the experimented conditions. The methyl orange of initial concentration from 20 to 60mg/L was effectively degraded in pulsed corona discharges. The lower initial concentration of methyl orange, the faster degradation was observed.

Thermal Degradation Kinetics of Antimicrobial Agent, Poly(hexamethylene guanidine) Phosphate

  • Lee, Sang-Mook;Jin, Byung-Suk;Lee, Jae-Wook
    • Macromolecular Research
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    • v.14 no.5
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    • pp.491-498
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    • 2006
  • The thermal degradation of poly(hexamethylene guanidine) phosphate (PHMG) was studied by dynamic thermogravimetric analysis (TGA) and pyrolysis-GC/MS (p-GC). Thermal degradation of PHMG occurs in three different processes, such as dephosphorylation, sublimation/vaporization of amine compounds and decomposition/ recombination of hydrocarbon residues. The kinetic parameters of each stage were calculated from the Kissinger, Friedman and Flynn-Wall-Ozawa methods. The Chang method was also used for comparison study. To investigate the degradation mechanisms of the three different stages, the Coats-Redfern and the Phadnis-Deshpande methods were employed. The probable degradation mechanism for the first stage was a nucleation and growth mechanism, $A_n$ type. However, a power law and a diffusion mechanism, $D_n$ type, were operated for the second degradation stage, whereas a nucleation and growth mechanism, $A_n$ type, were operated again for the third degradation stage of PHMG. The theoretical weight loss against temperature curves, calculated by the estimated kinetic parameters, well fit the experimental data, thereby confirming the validity of the analysis method used in this work. The life-time predicted from the kinetic equation is a valuable guide for the thermal processing of PHMG.