• Title/Summary/Keyword: Degradation behavior

검색결과 909건 처리시간 0.044초

Kinetics of Thermal Degradation of Polypropylene/Nanoclay/Wood Flour Nanocomposites

  • Mohan, D. Jagan;Lee, Sun-Young;Kang, In-Aeh;Doh, Geum-Hyun;Park, Byung-Dae;Wu, Qinglin
    • 한국응용과학기술학회지
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    • 제24권3호
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    • pp.278-286
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    • 2007
  • As a part of enhancing the performance of wood-plastic composites (WPC), polypropylene (PP)/ nanoclay (NC)/ wood flour (WF) nanocomposites were prepared using melt blending and injection molding process to evaluate their thermal stability. Thermogravimetric analysis (TGA) was employed to investigate thermal degradation kinetics of the nanocomposites both dynamic and isothermal conditions. Dynamic scans of the TGA showed an increased thermal stability of the nanocomposites at moderate wood flour concentrations (up to 20 phr, percentage based on hundred percent resin) while it decreased with the addition of 30 phr wood flour. The activation energy $(E_a)$ of thermal degradation of nanocomposites increased when nanoclay was added and the concentration of wood flour increased. Different equations were used to evaluate isothermal degradation kinetics using the rate of thermal degradation of the composites, expressed as weight loss (%) from their isothermal TGA curves. Degradation occurred at faster rate in the initial stages of about 60 min., and then proceeded in a gradual manner. However, nanocomposites with wood flour of 30 phr heated at $300^{\circ}C$ showed a drastic difference in their degradation behavior, and reached almost a complete decomposition after 40 min. of the isothermal heating. The degree of decomposition was greater at higher temperatures, and the residual weight of isothermal degradation of nanocomposites greatly varied from about 10 to 90%, depending on isothermal temperatures. The isothermal degradation of nanocomposites also increased their thermal stability with the addition of 1 phr nanoclay and of wood flour up to 20 phr. But, the degradation of PP100/NC1/MAPP3/WF30 nanocomposites with 30 phr wood flour occurs at a faster rate compared to those of the others, indicating a decrease in their thermal stability.

A framework for modelling mechanical behavior of surrounding rocks of underground openings under seismic load

  • Zhang, Yuting;Ding, Xiuli;Huang, Shuling;Pei, Qitao;Wu, Yongjin
    • Earthquakes and Structures
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    • 제13권6호
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    • pp.519-529
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    • 2017
  • The surrounding rocks of underground openings are natural materials and their mechanical behavior under seismic load is different from traditional man-made materials. This paper proposes a framework to comprehensively model the mechanical behavior of surrounding rocks. Firstly, the effects of seismic load on the surrounding rocks are summarized. Three mechanical effects and the mechanism, including the strengthening effect, the degradation effect, and the relaxation effect, are detailed, respectively. Then, the framework for modelling the mechanical behavior of surrounding rocks are outlined. The strain-dependent characteristics of rocks under seismic load is considered to model the strengthening effect. The damage concept under cyclic load is introduced to model the degradation effect. The quantitative relationship between the damage coefficient and the relaxation zone is established to model the relaxation effect. The major effects caused by seismic load, in this way, are all considered in the proposed framework. Afterwards, an independently developed 3D dynamic FEM analysis code is adopted to include the algorithms and models of the framework. Finally, the proposed framework is illustrated with its application to an underground opening subjected to earthquake impact. The calculation results and post-earthquake survey conclusions are seen to agree well, indicating the effectiveness of the proposed framework. Based on the numerical calculation results, post-earthquake reinforcement measures are suggested.

Elasto-viscoplastic modeling of the consolidation of Sri Lankan peaty clay

  • Karunawardena, Asiri;Oka, Fusao;Kimoto, Sayuri
    • Geomechanics and Engineering
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    • 제3권3호
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    • pp.233-254
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    • 2011
  • The consolidation behavior of Sri Lankan peaty clay is analyzed using an elasto-viscoplastic model. The model can describe the secondary compression behavior as a continuous process and it can also account for the effect of structural degradation on the consolidation analysis. The analysis takes into account all the main features involved in the process of peat consolidation, namely, finite strain, variable permeability, and the secondary compression. The material parameters required for the analysis and the procedures to evaluate them, using both standard laboratory and field tests, are explained. Initially, the model performance is assessed by comparing the predicted and the observed peat consolidation behavior under laboratory conditions. The results indicate that the model is capable of predicting the observed creep settlements and the effect of layer thickness on the settlement analysis of peaty clay. Then, the model is applied to predict the consolidation behavior of peaty clay under different field conditions. In this context, firstly, the one-dimensional field consolidation of peaty clay, brought about by the construction of compacted earth fill, is predicted. Then, the two-dimensional peat foundation response upon embankment loading is simulated. A good agreement is seen in the comparison of the predicted results with the field observations.

Experimental study on seismic behavior of frame structures composed of concrete encased columns with L-shaped steel section and steel beams

  • Zeng, Lei;Ren, Wenting;Zou, Zhengtao;Chen, Yiguang;Xie, Wei;Li, Xianjie
    • Earthquakes and Structures
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    • 제16권1호
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    • pp.97-107
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    • 2019
  • The frame structures investigated in this paper is composed of Concrete encased columns with L-shaped steel section and steel beams. The seismic behavior of this structural system is studied through experimental and numerical studies. A 2-bay, 3-story and 1/3 scaled frame specimen is tested under constant axial loading and cyclic lateral loading applied on the column top. The load-displacement hysteretic loops, ductility, energy dissipation, stiffness and strength degradation are investigated. A typical failure mode is observed in the test, and the experimental results show that this type of framed structure exhibit a high strength with good ductility and energy dissipation capacity. Furthermore, finite element analysis software Perform-3D was conducted to simulate the behavior of the frame. The calculating results agreed with the test ones well. Further analysis is conducted to investigate the effects of parameters including concrete strength, column axial compressive force and steel ratio on the seismic performance indexes, such as the elastic stiffness, the maximum strength, the ductility coefficient, the strength and stiffness degradation, and the equivalent viscous damping ratio. It can be concluded that with the axial compression ratio increasing, the load carrying capacity and ductility decreased. The load carrying capacity and ductility increased when increasing the steel ratio. Increasing the concrete grade can improve the ultimate bearing capacity of the structure, but the ductility of structure decreases slightly.

Behavior of short columns constructed using engineered cementitious composites under seismic loads

  • Syed Humayun Basha;Xiaoqin Lian;Wei Hou;Pandeng Zheng;ZiXiong Guo
    • Steel and Composite Structures
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    • 제48권5호
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    • pp.565-582
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    • 2023
  • The present research reports the application of engineered cementitious composites (ECC) as an alternative to conventional concrete to improve the seismic behavior of short columns. Experimental and finite element investigation was conducted by testing five reinforced engineered cementitious composite (RECC) concrete columns (half-scale specimens) and one control reinforced concrete (RC) specimen for different shear-span and transverse reinforcement ratios under cyclic lateral loads. RECC specimens with higher shear-span and transverse reinforcement ratios demonstrated a significant effect on the column lateral load behavior by improving ductility (>5), energy dissipation capacity (1.2 to 4.1 times RC specimen), gradual strength degradation (ultimate drift >3.4%), and altering the failure mode. The self-confinement effect of ECC fibers maintained the integrity in the post-peak region and reserved the transmission of stress through fibers without noticeable degradation in strength. Finite element modeling of RECC specimens under monotonic incremental loads was carried out by adopting simplified constitutive material models. It was apprehended that the model simulated the global response (strength and stiffness) and damage crack patterns reasonably well.

지진시 지반의 반복경화/연화 현상에 의한 부지응답 특성 영향 연구 (Cyclic Hardening and Degradation Effects on Site Response during an Earthquake)

  • 이진선
    • 한국지진공학회논문집
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    • 제12권6호
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    • pp.65-71
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    • 2008
  • 본 논문에서는 반복하중에 의한 반복 경화 및 연화 현상을 나타낼 수 있는 수정 IWAN 모델을 이용하여, 1차원 비선형 부지응답 해석프로그램(이하 KODSAP; Kaist One Dimensional Site-response Analysis Program)을 개발하였다. 개발된 프로그램은 지진하중 재하에 따른 지반의 반복경화 및 연화현상에 의한 부지응답 특성 변화를 재현할 수 있다. KODSAP을 이용하여 기반암 상부 40m인 모형지반의 반복경화 및 연화 정도, 지진가속도의 크기에 따른 부지응답특성 변화를 살펴 보았으며, 현재 실무에서 널리 적용되고 있는 등가선형, 비선형해석과 KODSAP 해석결과(지반의 반복경화 및 연화현상을 고려한)과의 차이점을 살펴 보았다.

의사체액에서 수산화아파타이트의 결정성에 따른 분해거동 (Degradation Behavior of Hydroxyapatite with Different Crystallinity in Simulated Body Fluid Solution)

  • 진형호;김동현;김태완;박홍채;윤석영
    • 한국재료학회지
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    • 제21권6호
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    • pp.347-351
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    • 2011
  • Hydroxyapatite (HAp) powders with different crystallinities were synthesized at various calcination temperatures through the co-precipitation of $Ca(OH)_2$ and $H_3PO_4$. The degradation behavior of these HAp powders with different crystallinities was assessed in a simulated body fluid solution (SBF) for 8 weeks. Below $800^{\circ}C$, the powders were nonstochiometric HAp, and the single HAp phase was successfully synthesized at $800^{\circ}C$. The degree of crystallinity of the HAp powders increased with an increasing calcination temperature and varied in a range from 39.6% to 92.5%. In the low crystallinity HAp powders, the Ca and P ion concentrations of the SBF solution increased with an increasing soaking time, which indicated that the low crystallinity HAp degraded in the SBF solution. The mass of the HAp powders linearly decreased with respect to the soaking time, and the mass loss was higher at lower crystallinities. The mass loss ranged from 0.8% to 13.2% after 8 weeks. The crystallinity of the HAp powders increased with an increasing soaking time up to 4 weeks and then decreased because of HAp degradation. The pH of the SBF solution did not change much throughout the course of these experiments. These results suggested that the crystallinity of HAp can be used to control the degradation.

Performance analysis of automatic depressurization system in advanced PWR during a typical SBLOCA transient using MIDAC

  • Sun, Hongping;Zhang, Yapei;Tian, Wenxi;Qiu, Suizheng;Su, Guanghui
    • Nuclear Engineering and Technology
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    • 제52권5호
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    • pp.937-946
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    • 2020
  • The aim in the present work is to simulate accident scenarios of AP1000 during the small-break loss-of-coolant accident (SBLOCA) and investigate the performance and behavior of automatic depressurization system (ADS) during accidents by using MIDAC (The Module In-vessel Degradation severe accident Analysis Code). Four types of accidents with different hypothetical conditions were analyzed in this study. The impact on the thermal-hydraulic of the reactor coolant system (RCS), the passive core cooling system and core degradation was researched by comparing these types. The results show that the RCS depressurization becomes faster, the core makeup tanks (CMT) and accumulators (ACC) are activated earlier and the effect of gravity water injection is more obvious along with more ADS valves open. The open of the only ADS1-3 can't stop the core degradation on the basis of the first type of the accident. The open of ADS1-3 has a great impact on the injection time of ACC and CMT. The core can remain intact for a long time and the core degradation can be prevent by the open of ADS-4. The all results are significant and meaningful to understand the performance and behavior of the ADS during the typical SBLOCA.

$^{18}O$을 함유하는 X-TZP의 저온열화거동 (Low Temperature Degradation Behavior of $^{18}O$-Containing Y-TZP)

  • 김병국
    • 한국세라믹학회지
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    • 제34권2호
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    • pp.171-174
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    • 1997
  • 산소포논(phonon)이 Yttiria안정화 정방정 지르코니아 소결체(Yttria Stabilized Tetragonal Zirconia Po-lycrystals, Y-TZP)의 저온열화에 큰 영향을 미치는 사실을 실험적으로 밝혔다. Y-TZP의 저온열화 (정방정$\longrightarrow$단사정 상전이) 현상은 Y-TZP의 16O을 18O으로 치환함으로써 급격히 저하되었다. 이는 16O이 보다 무거운 18O으로 치환됨에 따라 임계변위 이상에서 산소원자가 존재할 확률이 감소하는 데 기인하는 것으로 설명하였다.

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