• 제목/요약/키워드: Degradation behavior

검색결과 905건 처리시간 0.025초

탈질촉매 내 열화특성과 유동상태에 관한 연구 (A Study on Degradation Characteristic and Flow Behavior in De-NOx Catalyst)

  • 황승민
    • 한국환경과학회지
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    • 제19권9호
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    • pp.1093-1101
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    • 2010
  • In this study, the indirect correlation of degradation characteristic and flow behavior in the de-NOx catalyst is investigated experimentally. The inner flow behavior in the de-NOx catalyst is varied from turbulent flow to laminar flow and the degradation of the de-NOx catalyst is remarkably affected by the inner flow. The degradation of the catalyst is increased in the upstream region near the inlet because injected turbulent flow enhances the adhesion of ash particle on the catalyst surface. The degradation of the catalyst near the inlet also governs the overall efficiency of the catalyst. The amount of adhered ash particles on the catalyst surface decreases as they progress downstream. This is due to the inner flow transition from turbulent flow to laminar flow.

Ti-Ni 형상기억합금의 열피로열화 거동 (Thermal Fatigue Degradation Behavior of Ni-Ti Shape Memory Alloy)

  • 박영철;조용배;오세욱
    • 대한기계학회논문집
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    • 제18권11호
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    • pp.2913-2921
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    • 1994
  • In SMA(shape memory alloy), the degradation by fatigue is one of the most important problems to be overcome, when SMA is used for robot-actuator material. The actuator is operated repeatitively for long time and its repeating operation develops the fatigue degradation of SMA. The fatigue degradation changes the transformation temperature and deformation behavior and results in inaccurate operation control of robot. Accordingly, the changing behavior of transformation temperature and deformation which results from repeating operation is to be investigated in advance and the scheme to resolve those problems have to be made for the design of actuator. In this study, the fatigue tests were carried out on SMA specimens prepared to have different condition of aging time and pre-strain with the direct-current heating-cooling method, which was a general method of operation in robot actuators. The behavior of transformation temperature and deformation were examined and analyzed in each specimen and the study was performed to establish the optimistic manufacturing condition of SMA against the fatigue degradation.

Strength degradation of reinforced concrete piers wrapped with steel plates under local corrosion

  • Gao, Shengbin;Ni, Jie;Zhang, Daxu;Ge, Hanbin
    • Steel and Composite Structures
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    • 제24권6호
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    • pp.753-765
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    • 2017
  • This paper aims to investigate the strength degradation of reinforced concrete piers wrapped with steel plates which corrode at the pier base by employing a three dimensional elasto-plastic finite element formulation. The prediction accuracy of the employed finite element analysis method is firstly verified by comparing the analytical results with test results. Then, a series of parametric studies is carried out to investigate the effects of steel plate's corrosion position along width direction, corrosion depth along plate thickness, corrosion range along width direction, and steel plate-concrete bonding degradation on the strength of the piers. It is observed that the strength degradation of the piers is closely related to steel plate's corrosion position, corrosion depth and corrosion range in the case of local corrosion on the webs. In contrast, when the base of flanges corrodes, the strength degradation of the piers is only related to steel plate's corrosion depth and corrosion range, and the influence of corrosion position on the strength degradation is very gentle. Furthermore, the strength of the piers decreases with the degradation of steel plate-concrete bonding behavior. Finally, the maximum strength of the piers obtained from numerical analysis corresponding to different bonding behavior is compared with theoretical results within an accepted error.

수치해석을 이용한 터널 부재의 열화로 인한 장기 거동 예측 (Numerical Approach to Predict the Long Term Behavior of Tunnel Considering the Degradation of Tunnel Members)

  • 반호기;김동규
    • 한국지반환경공학회 논문집
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    • 제23권12호
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    • pp.33-39
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    • 2022
  • 본 논문은 터널을 구성하고 있는 구성요소(지보재, 주변지반)들의 열화로 인한 터널의 장기거동을 수치해석을 이용하여 예측/분석하였다. 터널의 구성요소들은 시간이 지남에 따라 열화를 겪게 된다. 이러한 열화로 인해 터널의 장기적인 안정성을 예측하는 것은 매우 중요한 이슈이다. 따라서 본 연구에서는 열화를 예측하는 모델을 제시하였으며, 이 모델은 두 개의 파라미터로 구성되어 있다. 그 중 하나는 부재 및 주변지반의 열화로 인해 남아있는 잔류강도를 나타내며, 나머지 하나는 열화되는 모양을 표시한다. 제안한 열화 모델을 이용하여 수치해석을 수행하여 터널의 장기거동을 예측하였다. 그 결과 열화로 인해 터널 주변 지반의 이완응력이 증가하여 터널의 장기적인 안정성에 영향을 미치고 있음을 알 수 있었다.

발전설비 보일러 튜브용 X20강의 가속열처리에 의한 재질 열화 (Material Degradation of X20 Steel (12Cr-1MoVNi) for Boiler Tube of Power Plant)

  • 최병학;윤기봉;이남혁;김신;이길재;김광호;권동일
    • 대한금속재료학회지
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    • 제46권5호
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    • pp.276-282
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    • 2008
  • Material degradation of Cr steels in boiler tubes was accompanied by the microstructural changes including carbide behavior and crack formation. The microstructural change and the mechanical behavior of hardness and creep properties in accelerated heat-treatments were studied in order to identify the material degradation of the X20 Cr steel. The degradation behavior was occurred in the hardness increasing followed by decreasing due to carbide dissolution and precipitation.

과산화수소/자외선/산소 처리를 이용한 베르베린 염료 및 염직물의 퇴화거동 연구 (Study on the Degradation Behavior of Berberine Dye and Berberine Dyed Silk using Hydrogen Peroxide/UV/Oxygen Treatment)

  • 안춘순
    • 복식문화연구
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    • 제20권2호
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    • pp.238-250
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    • 2012
  • This study examined the degradation behavior of SB(standard berberine) dye and SB dyed silk using HPLC-MS instrument after degradation in the hydrogen peroxide/ultraviolet ray radiation/oxygen system up to 9 days and 40 hours respectively. In the degraded samples, berberine was detected at 5.2 min in the SB dye and 5.3 min in the SB dyed silk with its molecular ion=336 and the UV spectra of quaternary alkaloid. Degradation product 3(m/z=102) newly appeared after 5 day degradation treatment with continued increase till the end of degradation treatment. The amount of berberine in the degraded dye decreased with degradation progression. In the silk dyeings, berberine was detected only up to 21 hour degradation sample. The amount of berberine decreased dramatically during the first 6 hours of degradation treatment. The CIELAB color measurement of the silk dyeings showed dramatic change in the b* value, near zero in the 40 hour degraded silk. CIELAB and Munsell color measurements were in agreement with the HPLC-MS results of the dyed silk in the change of berberine content that the degraded silk became white and lost yellow color.

Degradation Behavior of 850 nm AlGaAs/GaAs Oxide VCSELs Suffered from Electrostatic Discharge

  • Kim, Tae-Yong;Kim, Tae-Ki;Kim, Sang-In;Kim, Sang-Bae
    • ETRI Journal
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    • 제30권6호
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    • pp.833-843
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    • 2008
  • The effect of forward and reverse electrostatic discharge (ESD) on the electro-optical characteristics of oxide vertical-cavity surface-emitting lasers is investigated using a human body model for the purpose of understanding degradation behavior. Forward ESD-induced degradation is complicated, showing three degradation phases depending on ESD voltage, while reverse ESD-induced degradation is relatively simple, exhibiting two phases of degradation divided by a sudden distinctive change in electro-optical characteristics. We demonstrate that the increase in the threshold current is mainly due to the increase in leakage current, nonradiative recombination current, and optical loss. The decrease in the slope efficiency is mainly due to the increase in optical loss.

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칼슘 용출 열화에 의해 표면이 손상된 콘크리트 부재의 구조적 거동에 관한 해석적 연구 (Analytical Study on Structural Behavior of Surface Damaged Concrete Member by Calcium Leaching Degradation)

  • 최윤석;장용환;최소영;김일순;양은익
    • 한국구조물진단유지관리공학회 논문집
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    • 제18권4호
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    • pp.22-32
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    • 2014
  • 다양한 열화 인자에 의해 저감된 콘크리트의 내구성은 구조물의 구조적 성능과 사용 수명에 부정적인 영향을 미치게 되며 콘크리트 연구 분야 중에서도 매우 중요하고 매력적인 주제라고 할 수 있다. 이러한 이유로 콘크리트의 내구성과 관련된 많은 연구들이 발표되었으나 물리-화학적 열화에 기인하는 콘크리트의 본질적인 물성 변화에 주된 초점이 맞춰져 왔으며, 콘크리트 내구성과 구조물의 구조적 성능 사이의 관계 정립은 아직 미흡한 실정이다. 본 연구에서는 콘크리트의 강도 감소에 원인이 되는 칼슘 용출 열화를 적용하였으며, 열화 정도에 따른 구조적 거동을 평가하기 위하여 열화 손상을 입은 콘크리트 부재의 압축 및 휨 거동 실험을 수행하고 그 결과를 비선형 유한요소해석 결과와 비교 분석하였다. 연구 결과에 따르면 칼슘 용출 열화는 콘크리트의 압축 강도를 저하시키며, 열화가 진행됨에 따라 취성 거동에서 연성 거동으로 변화되는 경향을 나타냈다. 또한 열화에 의한 압축 영역의 손상 정도가 심화될수록 RC 부재의 내하력과 강성은 저하되었으며, 이러한 구조적 거동은 ABAQUS의 CDP 모델을 사용한 비선형 유한요소해석의 결과와도 비교적 잘 일치하였다.

가전제품용 플라스틱 재료의 열분해 거동 및 신뢰성 평가 (Thermal Degradation Behavior and Reliability Analysis of Plastic Materials for Household Electric Appliances)

  • 임창규;김준영;김성훈
    • 폴리머
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    • 제29권5호
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    • pp.508-517
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    • 2005
  • 가전제품용 플라스틱 재료의 열화 거동과 신뢰성을 고찰하기 위해 열분해에 따른 동역학적 매개변수를 결정하기 위하여 동역학적 열중량 분석기법을 사용하였고, 촉진 열화시험을 수행하였다. 또한, 플라스틱 재료의 내후성을 고찰하고자 제논 아크 광원을 사용하여 촉진 열화시험을 하였고, 가속 열화시험후 시료의 색차를 컬러 아이 3010 색차분석기를 이용하여 측정하였다. 재료는 중량감소율이 증가함에 따라 열분해 활성화 에너지도 증가하는 경향을 보였다. 플라스틱 재료의 열분해에 관한 기술은 Kim-Park법이 가장 효과적인 분석법으로 나타났다. 플라스틱 재료는 빠른 열화를 진행시키는 자외선에 아주 민감하게 반응하였다.

Preparation of Electrospun Oxidized Cellulose Mats and Their in vitro Degradation Behavior

  • Khil Myung Seob;Kim Hak Yong;Kang Young Sic;Bang Ho Ju;Lee Douk Rae;Doo Jae Kyun
    • Macromolecular Research
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    • 제13권1호
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    • pp.62-67
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    • 2005
  • This paper investigated the effect of biodegradation behavior on the oxidation of cellulose nanofiber mats. The cellulose mats were produced through electro spinning. The diameter of an electrospun fiber varied from 90 to 240 nm depending on the electrospinning parameters, such as the solution concentration, needle diameter, and rotation speed of a grounded collector. Oxidized cellulose (OC).mats containing different carboxyl contents were prepared using $NO_2$ as an oxidant. The total carboxyl content of the cellulose nanofiber mats obtained after oxidation for 20 h was $20.6\%$. The corresponding carboxyl content was important from a commercial point of view because OC containing $16-24\%$ carboxyl content are used widely in the medical field as a form of powder or knitted fabric. Degradation tests of the OC mats were performed at $37^{\circ}C$ in phosphate-buffered saline (pH 7.4). Microscopy techniques were introduced to study the morphological properties and the degradation behavior of the OC mats. Morphological changes of the mats were visualized using optical microscopy. Within 4 days of exposure to PBS, the weight loss of the OC mats was $>90\%$.