• 대한기계학회논문집A
• /
• 제22권1호
• /
• pp.44-51
• /
• 1998

In order to develop the evaluation methods of degradation for the Ni-Cr-Mo-V steel, which is in use for turbine rotor in nuclear power plant, the degraded materials were prepared by simulated degradation methods. The result of impact test and fatigue crack growth test shows that the FATT(Fracture Appearance Transition Temperature) and fatigue crack growth rate increased with the increase of degradation. And the result of new electrochemical polarization test method was suggested for the evaluating FATT, fatigue crack growth exponent and coefficient C values based on the results of relationship between corrosion current density(Icorr) & FATT, and the m & C and Icorr.

• International Journal of Precision Engineering and Manufacturing
• /
• 제6권3호
• /
• pp.51-55
• /
• 2005

This study addresses the contamination sensitivity test of a typical fuel pump for an automotive vehicle. The objective of the study is to find the contamination sensitivity coefficient of a fuel pump on specific contaminant particle sizes so that an optimal fuel filter could be selected. To achieve the objective, the degradation of discharge flow rate of the fuel pump is measured under the experiments of various contaminants size ranges of ISO test dust up to $80\;{\mu}m$. The fundamental theory of contamination sensitivity is introduced and the contamination sensitivity coefficients are estimated using the experimental data. Maximum contamination sensitivity coefficient of $5\chi\;10^{-6}\;L/min{\cdot}Ea$ is found in the contaminant size range of $40\;{\mu}m\~50\;{\mu}m$. The magnified picture of the surface of vane disc reveals that the abrasive wear is the principal cause of discharge flow rate degradation. Hence, this study reveals that a high efficiency filter for contaminant particles especially in the size range of $30\;{\mu}m\~70\;{\mu}m$ especially should be used to maintain the service life of the fuel filter.

• 한국정밀공학회지
• /
• 제21권6호
• /
• pp.102-108
• /
• 2004

This study addresses the contamination sensitivity test of a typical fuel pump for automotive vehicle. The objective of the study is to find the contamination sensitivity coefficient of fuel pump on specific contaminant particle sizes so that optimal fuel filter could be selected. To achieve the objective, the degradation of discharge flow rate of fuel pump was measured under the experiments of various contaminants size ranges of ISO test dust up to 80${\mu}{\textrm}{m}$. The fundamental theory of contamination sensitivity was introduced and the contamination sensitivity coefficients were estimated using the experimental data. Maximum contamination sensitivity coefficient of $5{\times}10^{-6}$ L/minㆍEa was found on the contaminant size range of 40${\mu}{\textrm}{m}$∼50${\mu}{\textrm}{m}$. The magnified picture of the surface of vane disc revealed that the abrasive wear was the principal cause of discharge flow rate degradation. Hence, this study revealed that high efficiency filter on the contaminant particle size range of 30${\mu}{\textrm}{m}$∼70${\mu}{\textrm}{m}$ especially should be used to maintain the service lift of the fuel filter.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
• /
• pp.349-352
• /
• 2009

In this study, the relation between the performance degradation of SOFC single cell and the increase of polarization resistance for the cathode is investigated. $Pr_{0.3}Sr_{0.7}Co_{0.3}Fe_{0.7}O_3$(PSCF3737, $19.4{\times}10^{-6}K^{-1}$) and $Gd_{0.1}Ce_{0.9}O_2$ (CGO91, $12{\times}10^{-6}K^{-1}$) are used as a cathode and an electrolyte, respectively. The polarization resistance of cathode is increased due to the delamination caused by thermal expansion coefficient difference. The voltage drop with 10%/1000h decline rate occurs during long-term, when the interface between the cathode and the electrolyte is delaminated due to TEC difference.

• 한국환경과학회지
• /
• 제21권7호
• /
• pp.845-853
• /
• 2012

Diethyl phthalate (DEP) is widely spread in the natural environment as an endocrine disruption chemicals (EDs). Therefore, in this study, ultrasound (US) and ultraviolet (UVC), including various applied power density (10-40 W/L), UV wavelengths (365 nm, 254 nm and 185 nm) and frequencies (283 kHz, 935 kHz) were applied to a DEP contaminated solution. The pseudo-first order degradation rate constants were in the order of $10^{-1}$ to $10^{-4}\;min^{-1}$ depending on the processes. Photolytic and sonophotolytic DEP degradation rate also were high at shortest UV wavelength (VUV) due to the higher energy of photons, higher molar absorption coefficient of DEP and increased hydroxyl radical generation from homolysis of water. Sonolytic DEP degradation rate increased with increase of applied input power and the dominant reaction mechanism of DEP in sonolysis was estimated as hydroxyl radical reaction by the addition of t-BuOH, which is a common hydroxyl radical scavenger. Moreover, synergistic effect of were also observed for sonophotolytic degradation with various UV irradiation.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2001년도 하계학술대회 논문집
• /
• pp.157-160
• /
• 2001

Three sets of ZnO ceramic devices (reference samples with Matsuoka\`s composition; added 7o MgO, A1$_2$O$_3$, SiO$_2$) have been prepared by the conventional mixed oxide route. These additives were determined by the factors of valences and ionic radiuses. DC accelerated degradation test was performed for analysis of degradation characteristics versus the various additives. The conditions of DC degradation test were 115${\pm}$2$^{\circ}C$ for 12h. Using XRD and SEM, the Phase and microstructure of samples were analyzed respectively. E-J analysis was used to determine ${\alpha}$. Frequency analysis was accomplished to understand the relationship between R$\sub$g/ and $R_{b}$ with the electric stress at the equivalent circuit.

• Biomolecules & Therapeutics
• /
• 제1권1호
• /
• pp.31-36
• /
• 1993

To evaluate the feasibility of transmucosal delivery of methionine enkephalin analog, [$D-Ala^2$]-me-thionine enkephalinamide (YAGFM), the influence of pH, temperature, ionic strength and initial peptide concentration on the physicochemical stability of YAGFM in aqueous buffered solutions were investigated using a stability-indicating HPLC method. The degradation of YAGFM followed the pseudo-first-order kinetics. From the pH-rate profile, the maximum stability of YAGFM was shown to be at the pH of about 5.0. The halflife for the degradation of YAGFM was found to be 181.3 days at pH 5.0 and $37^{\circ}C.$ Arrhenius plots of the data obtained at 25~$45^{\circ}C$ were reasonably linear with a correlation coefficient greater than 0.99, and the activation energy was calculated to be 8.9 kcal/mole. A higher ionic strength and/or a higher peptide concentration in buffered solutions retarded the degradation of YAGFM.

• 에너지공학
• /
• 제14권2호
• /
• pp.105-111
• /
• 2005

본 연구는 마이크로 채널 반응기를 이용하여 다양한 실험조건에서 D-glucose용액을 이용하여 광촉매 분해특성을 연구하였다. Titanium oxysulfate의 수산화반응을 통하여 합성한 $TiO_2$수용액을 이용하여 마이크로 채널 반응기에 $TiO_2$를 코팅하였다. D-glucose광촉매 분해특성은 반응기의 주입유속이 증가함에 따라 증가하는 것으로 나타났으며 반응속도 상수와 Langmuir 흡수 제수를 다양한 실험조건에서 계산하였다. 또한 반응 시스템에서의 광효율을 계산하였다 따라서 이 연구는 배치 시스템에 적용된 $TiO_2$코팅이 되어 있는 마이크로 채널 반응기의 광분해 특성을 이해하기 위한 것이다.

• 한국농공학회논문집
• /
• 제50권2호
• /
• pp.3-10
• /
• 2008

The main objectives of this study are to calibrate the RICEWQ model with Korean field data and then analyse the sensitivity of the parameters to identify sensitive parameters. The RICEWQ is widely used to predict pesticide fate in a paddy plot. An experimental paddy plot of 0.2 ha($100{\times}20\;m$) at Seobyeon-dong, Daegu, Korea was selected, and field observations for water and pesticide balance were performed from 4 June to 2 September 2006. The molinate, which is a herbicide widely used for weed control in rice culture, was selected. The RICEWQ model was successfully calibrated both for the water and pesticide mass balance. The calibrated model showed a RMSE of 0.537 cm for ponded water depths and a RMSE of 0.036 mg/L for the molinate concentrations in the ponded water. The most sensitive parameters for molinate concentrations in ponded water were the metabolism degradation rate in water, volatilization coefficient, and release rate for slow release formulation. In contrast, the RICEWQ model was not sensitive to parameters such as hydrolysis degradation rate in water and degradation rate in unsaturated soil.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2003년도 봄 학술발표회 논문집
• /
• pp.681-686
• /
• 2003

One of the major degradation processes of reinforced concrete (RC) structure is corrosion of reinforced steel due to chloride attack. Severe environments, such as marine environment and exposure to de-icing salts, could accelerate the steel corrosion of RC structures through the chloride ion intrusion into concrete. In order to delay this degradation process, several kinds of admixtures have been used in concrete mix. In this study, effective diffusion coefficient of chloride ion ($D_{eff}$) and total passed charge of concrete with and without fly ash were measured using electrical method. It is found that fly ash concrete has much less chloride ion coefficient than ordinary concrete at later age. By analyzing the test results, $D_{eff}$ at 28 and 90 days was obtained as a function of water-binder ratio (W/B) and an equation for predicting $D_{eff}$ with age was proposed considering the decreasing rate of $D_{eff}$.