• Title/Summary/Keyword: Degradation Curve

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Effect of MEA fabrication on the performance degradation of DMFC (MEA 제조 방법에 따른 직접 메탄올 연료전지의 성능저하 현상 평가)

  • Cho, Yoon-Hwan;Cho, Yong-Hun;Park, Hyun-Seo;Won, Ho-Youn;Sung, Yung-Eun
    • New & Renewable Energy
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    • v.3 no.1 s.9
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    • pp.60-67
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    • 2007
  • Catalyst coated membrane [CCM] type and catalyst coated substrate [CCS] type of membrane electrode assembly [MEA] were manufactured and evaluated their performance. Degradation test were conducted to find the difference of long term stability in two types of MEA and the factor for performance degradation problem occurred. Performance degradation test of single cell in two different types of MEA were carried out when current density was $200mA/cm^{2}$. The degradation test had proceeded for 230 hours and performance degradation was checked by I-V curve and impedance measurement at regular intervals. Also, MEA before/after operation and changes of catalyst layer were characterized by SEM, TEM, and XRD. Maximum power density of CCM type was higher than that of CCS type. Meanwhile, an increase of particle size of catalyst and an increase of impedance resistance after long term operation were observed. In the case of using CCM type MEA, the performance was deteriorated 38% of initial performance. In the case of using CCS type MEA, the performance was deteriorated 43% of initial performance. In consideration of difference of initial performance, performance of CCM type is higher than that of CCS type but both types had similar problems during degradation test.

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Evaluation of Mechanical Property and Fatigue Damage in A Practical Superconducting Cable for Magnet (초전도 마그네트용 실용 초전도 복합선재의 기계적 특성 및 피로손상 평가에 관한 연구)

  • Sin, Hyeong-Seop;O, Sang-Su
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.3 s.174
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    • pp.761-768
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    • 2000
  • In order to investigate how the fatigue damage effects on the critical properties of superconductor, a fatigue test at room temperature and an Ic measurement test at 4.2K were carried out in this study, respectively, using a 9 strand Cu-Ni/NbTi/Cu composite cable. Through the fatigue test of a 9 strand Cu-NUNbTi/Cu composite cable, a conventional S-N curve was plotted even though there was a possibility of fretting among strands. It was found that the maximum stress corresponding to the inflection point on the S-N curve obtained was nearly the same value as the yielding strength of cable obtained from the static tensile test. However, the effect of cabling in multi-strands superconducting cable on the fatigue strength was not noticeable. The critical current(Ic) measurement was carried out at 4.2K in a NbTi strand out of the fatigued cable. It showed a degradation of lc at high stress amplitude regions over 380NTa, and the degradation became significant as the applied stress amplitude increased.

Study on the Thermal Degradation Behavior of FKM O-rings

  • Lee, Jin Hyok;Bae, Jong Woo;Choi, Myoung Chan;Yoon, Yoo-Mi;Park, Sung Han;Jo, Nam-Ju
    • Elastomers and Composites
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    • v.53 no.4
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    • pp.213-219
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    • 2018
  • The degradation mechanism and physical properties of an FKM O-ring were observed with thermal aging in this experiment. From X-ray photoelectron spectroscopy (XPS) analysis, we could observe carbon (285 eV), fluoro (688 eV), and oxygen (531 eV) peaks. Before thermal aging, the concentration of fluoro atoms was 51.23%, which decreased to 8.29% after thermal aging. The concentration of oxygen atoms increased from 3.16% to 20.39%. Under thermal aging, the FKM O-ring exhibited debonding of the fluoro-bond by oxidation. Analysis of the C1s, O1s, and F1s peaks revealed that the degradation reaction usually occurred at the C-F, C-F2, and C-F3 bonds, and generated a carboxyl group (-COOH) by oxidation. Due to the debonding reaction and decreasing mobility, the glass transition temperature of the FKM O-ring increased from $-15.91^{\circ}C$ to $-13.79^{\circ}C$. From the intermittent CSR test, the initial sealing force was 2,149.6 N, which decreased to 1,156.2 N after thermal aging. Thus, under thermal aging, the sealing force decreased to 46.2%, compared with its initial state. This phenomenon was caused by the debonding reaction and decreasing mobility of the FKM O-ring. The S-S curve exhibited a 50% increase in modulus, with break at a low strain and stress state. This was also attributed to the decreasing mobility due to thermal aging degradation.

Model Development for Specific Degradation Using Data Mining and Geospatial Analysis of Erosion and Sedimentation Features

  • Kang, Woochul;Kang, Joongu;Jang, Eunkyung;Julien, Piere Y.
    • Proceedings of the Korea Water Resources Association Conference
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    • 2020.06a
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    • pp.85-85
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    • 2020
  • South Korea experiences few large scale erosion and sedimentation problems, however, there are numerous local sedimentation problems. A reliable and consistent approach to modelling and management for sediment processes are desirable in the country. In this study, field measurements of sediment concentration from 34 alluvial river basins in South Korea were used with the Modified Einstein Procedure (MEP) to determine the total sediment load at the sampling locations. And then the Flow Duration-Sediment Rating Curve (FD-SRC) method was used to estimate the specific degradation for all gauging stations. The specific degradation of most rivers were found to be typically 50-300 tons/㎢·yr. A model tree data mining technique was applied to develop a model for the specific degradation based on various watershed characteristics of each watershed from GIS analysis. The meaningful parameters are: 1) elevation at the middle relative area of the hypsometric curve [m], 2) percentage of wetland and water [%], 3) percentage of urbanized area [%], and 4) Main stream length [km]. The Root Mean Square Error (RMSE) of existing models is in excess of 1,250 tons/㎢·yr and the RMSE of the proposed model with 6 additional validations decreased to 65 tons/㎢·yr. Erosion loss maps from the Revised Universal Soil Loss Equation (RUSLE), satellite images, and aerial photographs were used to delineate the geospatial features affecting erosion and sedimentation. The results of the geospatial analysis clearly shows that the high risk erosion area (hill slopes and construction sites at urbanized area) and sedimentation features (wetlands and agricultural reservoirs). The result of physiographical analysis also indicates that the watershed morphometric characteristic well explain the sediment transport. Sustainable management with the data mining methodologies and geospatial analysis could be helpful to solve various erosion and sedimentation problems under different conditions.

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Evaluation of 1Cr-1Mo-0.25V Steel Degradation Using Magnetic Barkhausen Noise (Magnetic Barkhausen Noise를 이용한 1Cr-1Mo-0.25V강의 열화도 평가)

  • Lee, J.M.;Ahn, B.Y.;Nam, Y.H.;Nahm, S.H.;Lee, S.S.;Lee, O.S.
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.250-255
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    • 2001
  • It is inevitable to evaluate the life of turbine rotor because the operating periods of power plants need to be extended. The magnetic methods utilizing Magnetic Barkhausen noise curve were applied to detect the degradation caused by thermal aging. The Magnetic property of material depends on the domain dynamics and it is affected by the microstructure of material. Therefore the magnetic property is very sensitive to the microstructure change of the material. It is, thus, very useful to detect the state of degradation of varying materials. The test specimen made of 1Cr-1Mo-0.25V steel was used widely for turbine rotor material, and seven kinds of specimens with different degradation levels were prepared by the isothermal heat treatment at $630^{\circ}C$. With the increase of degradation, BHN was decreased. The result was compared with coercive force and vickers hardness.

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Estimation of Shear Moduli Degradation Characteristics from Pressuremeter Tests (프레셔미터 시험을 이용한 전단탄성계수 감쇠 특성 평가)

  • Kwon, Hyung Min;Chung, Choong Ki
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.3C
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    • pp.105-113
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    • 2009
  • Pressuremeter test estimates deformational properties of soil from the relationship between applied pressure and the displacement of cavity wall, and the results reflect the in-situ stress condition and the structure of soil particles. This study suggests the overall process of test and analysis for the evaluation of nonlinear degradation characteristics of shear moduli, based on the reloading curve of pressuremeter test. The method estimates the maximum shear modulus, taking into account the difference between the stress states around the probe in reloading and that of the in-situ state, and then combines the degradation characteristics of shear moduli taken from reloading curve. This procedure derives the shear moduli in overall strain range. Pressuremeter tests were carried out in various ground conditions using large calibration chamber, together with various reference tests. Shear moduli taken from pressuremeter tests were compared with bender element test and resonant column test results.

Ductility Degradation Assessment of Baffle Former Assembly Considering the Stress Triaxiality Effect (응력 삼축성을 고려한 원자로 내부구조물 배플포머 집합체의 연성저하 평가)

  • Kim, Jong-Sung;Park, Jeong Soon;Kang, Sung-Sik
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.12 no.2
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    • pp.50-57
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    • 2016
  • The study presents structural integrity assessment of ductility degradation of a baffle former assembly by performing finite element analysis considering real loading conditions and stress triaxiality. Variations of fracture strain curves of type 304 austenitic stainless steel with stress triaxiality are derived based on the previous study results. Temperature distributions during normal operation such as heat-up, steady state, and cool-down are calculated via finite element temperature analysis considering gamma heating and heat convection with reactor coolant. Variations of stress and strain state during long operation period are also calculated by performing sequentially coupled temperature-stress analysis. Fracture strain is derived by using the fracture curve and the stress triaxility. Finally, variations of ductility degradation damage indicator with the fracture strain and the equivalent inelastic strain are investigated. It is found that maximum value of the ductility degradation damage index continuously increases and becomes 0.4877 at 40 EFPYs. Also, the maximum value occurs at top and middle inner parts of the baffle former assembly before and after 20 EFPYs, respectively.

Contact Damage and Strength Degradation of Yttria doped Tetragonal Zirconia Polycrystal (Y$_2$O$_3$ 를 첨가한 정방정 지르코니아에서의 접촉손상 및 강도저하)

  • 정연길;최성철
    • Journal of the Korean Ceramic Society
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    • v.35 no.5
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    • pp.429-436
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    • 1998
  • The mechanical properties and damage mode of {{{{ {Y}_{2 } {O}_{3} }}-doped tetragonal (Y-TZP) can-didated as biomaterials were performed under indentation stress-strain curve critical load for yield and cracking strength degradation and fatigue behavior with Hertzian indentation tests. This material shows the brittle behavior which is confirmed by indentation stress-strain response. The critical load for cracking(Pc) is much higher than that for yields (Py) indicating crack resistance Strength were strongly dependant on contact area and there were no degradation when the indenter size was ${\gamma}$=3.18 mm suggesting that Y-TZP should be highly damage tolerant to the blunt contacts. Multi-cycle contact were found to be innocuous up to {{{{ {10 }^{6 } }} cycles at 500N and {{{{ {10 }^{5 } }} cycles at 1000N in water. On the other hand contacts at {{{{ {10 }^{6 } }} cycles at 1000 N in water did show some signs of incipient degradation. By contrast contacts with Vickers indenter pro-duced substantial strength losses at much lower loads suggesting that the mechanical integrity of this ma-terial would be compromised by inadvertent sharp contacts.

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Seismic performances of steel reinforced concrete bridge piers

  • Deng, Jiangdong;Liu, Airong;Yu, Qicai;Peng, Guoxing
    • Steel and Composite Structures
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    • v.21 no.3
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    • pp.661-677
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    • 2016
  • The quasi static test of the steel reinforced concrete (SRC) bridge piers and rigid frame arch bridge structure with SRC piers was conducted in the laboratory, and the seismic performance of SRC piers was compared with that of reinforced concrete (RC) bridge piers. In the test, the failure process, the failure mechanism, hysteretic curves, skeleton curves, ductility coefficient, stiffness degradation curves and the energy dissipation curves were analyzed. According to the $M-{\Phi}$ relationship of fiber section, the three-wire type theoretical skeleton curve of the lateral force and the pier top displacement was proposed, and the theoretical skeleton curves are well consistent with the experimental curves. Based on the theoretical model, the effects of the concrete strength, axial compression ratio, slenderness ratio, reinforcement ratio, and the stiffness ratio of arch to pier on the skeleton curve were analyzed.

Effects of Soil Nonlinearity Characteristics on the Seismic Response of KNGRStructures (지반의 비선형 특성이 차세대원전 구조물의 지진응답에 미치는 영향)

  • 장영선
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 1999.10a
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    • pp.137-146
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    • 1999
  • The SSI(Soil-Structure Interaction) analyses are being performed for the KNGR(Korean Next Generation Reactor) design because the KNGR is developed as a standard nuclear power plant concept enveloping various soil conditions. the SASSI program which adopts the flexible volume method is used for the SSI analyses. The soil curves used in the three dimensional SSI analyses of KNGR Nuclear Island(NI) structures are based on the upper bound shear modulus curve and lower bound damping degradation on SSI response the average shear modulus curve with average damping curve was used for two soil cases. This study presents the results of the variances by using different soil nonlinearity parameters based on the paametric SSI analyses. The results include the maximum member forces(shear and axial force) at the base of the NI structures and the 5% damping Floor Response Spectra (FRS) at some representative locations at the top of the NI superstructures. They are also compared together with the enveloped SSI results for eight soil cases and fixed-base analysis for rock case by using two control motions.

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