• Title/Summary/Keyword: Deep blue

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Cross-verified Measurement of Sulfide Concentration in Anaerobic Conditions Using Spectroscopic, Electrochemical, and Mass Spectrometric Methods

  • Nakkyu Chae;Samuel Park;Sungyeol Choi
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.21 no.1
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    • pp.43-53
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    • 2023
  • Sulfide concentrations critically affect worker safety and the integrities of underground facilities, such as deep geological repositories for spent nuclear fuel. Sulfide is highly sensitive to oxygen, which can oxidize sulfide to sulfate. This can hinder precise measurement of the sulfide concentration. Hence, a literature review was conducted, which revealed that two methods are commonly used: the methylene blue and sulfide ion-selective electrode (ISE) methods. Inductively coupled plasma optical emission spectroscopy (ICP-OES) was used for comparison with the two methods. The sulfide ISE method was found to be superior as it yielded results with a higher degree of accuracy and involved fewer procedures for quantification of the sulfide concentration in solution. ICP-OES results can be distorted significantly when sulfide is present in solution owing to the formation of H2S gas in the ICP-OES nebulizer. Therefore, the ICP-OES must be used with caution when quantifying underground water to prevent any distortion in the measured results. The results also suggest important measures to avoid problems when using ICP-OES for site selection. Furthermore, the sulfide ISE method is useful in determining sulfide concentrations in the field to predict the lifetime of disposal canisters of spent nuclear fuel in deep geological repositories and other industries.

Synthesis and Characterization of 9,9'-Diethyl-2-diphenylaminofluorene Derivatives as Blue Fluorescent Materials for OLEDs

  • Oh, Suh-Yun;Lee, Kum-Hee;Seo, Ji-Hoon;Kim, Young-Kwan;Yoon, Seung-Soo
    • Bulletin of the Korean Chemical Society
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    • v.32 no.5
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    • pp.1593-1598
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    • 2011
  • Blue fluorescent materials based on 9,9'-diethyl-2-diphenylaminofluorene derivatives were synthesized and characterized. These materials were used as the blue dopant materials for the emitting layer of organic light-emitting diode devices with the following device structure: ITO/DNTPD (40 nm)/NPB (20 nm)/MADN: dopants (2%, 20 nm)/$Alq_3$ (40 nm)/Liq (1.0 nm)/Al. All devices exhibited highly efficient blue emission. One of these devices exhibited a maximum luminance, luminous efficiency, power efficiency and CIE x, y coordinates of 8400 $cd/m^2$, 8.10 cd/A at 20 $mA/cm^2$, 3.36 lm/W at 20 $mA/cm^2$ and (0.151, 0.159), respectively. A deep blue device with CIE coordinates of (0.152, 0.139) showed the maximum luminance, luminous efficiency and power efficiency of 8630 $cd/m^2$, 6.31 cd/A at 20$mA/cm^2$ and 2.62 lm/W at 20 $mA/cm^2$, respectively.

The process optimization for development of super deep black fiber (고심색용 폴리에스테르 섬유제품의 개발을 위한 공정최적화 연구)

  • Kim, Tae-Kyeong;Jeon, Jun-Hyung;Kim, Eun-Cheol
    • Textile Coloration and Finishing
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    • v.19 no.1 s.92
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    • pp.53-60
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    • 2007
  • In order to optimize the process for development of super deep black fiber, the silica-containing polyester fabric, SN2000, was investigated in terms of mass reduction process by sodium hydroxide, selection of high color strength dyes, and resin treatment. As the results, the mass reduction condition which used 15g/L of sodium hydroxide at $120^{\circ}C$ was determined and Dianix Deep Black Plus was selected for the best deep coloration at around 5% owf. Contrary to the prevailed understanding that the additional use of chromatic dyes would enhance the deep coloration, four kinds of chromatic dyes such as yellow, red, blue, and green dyes did not make great effect on the deep coloration. To increase the effect, the commercial resin that has low refractive index was used additionally and the resin made it possible to lower the lightness of the fabrics down to 8.7 which was generally accepted for super highly deep black fabric.

New Fluorescent Blue OLED Host and Dopant Materials Based on the Spirobenzofluorene

  • Lee, In-Ho;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.32 no.5
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    • pp.1475-1482
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    • 2011
  • New spiro[benzo[c]fluorene-7,9'-fluorene] (SBFF)-based blue host materials, 9-phenyl-SBFF (BH-4P) and 5,9-diphenyl-SBFF (BH-6DP), were successfully prepared by spiro-formation of 9-phenyl-7H-benzo[c]fluoren-7-one with 2-bromobiphenyl via lithiation and reaction of 5,9-dibromo-SBFF with phenylboronic acid through the Suzuki reaction, respectively. Diphenyl-[4-(2-[1,1;4,1]terphenyl-4-yl-vinyl)-phenyl]-amine (BD-1) and N,N-diphenyl-N',N'-diphenyl-SBFF-5,9-diamine (BD-6DPA) were used as dopant materials. Blue OLEDs with the configuration ITO/N,N'-bis-[4-(di-m-tolylamino)phenyl]-N,N'-diphenylbiphenyl-4,4'-diamine (DNTPD)/bis[N-(1-naphthyl)-N-phenyl]benzidine (NPB)/host:5% dopant/SFC-137/Al-LiF were prepared from the two host materials doped with BD-1 and BD-6DPA dopants and the devices composed of BH-4P and BH-6DP doped with BD-6DPA showed blue EL spectra at 458 and 463 nm at 7 V and luminance efficiencies of 4.58 and 4.88 cd/A, respectively.

Synthesis and Characterization of New Anthracene-Based Blue Host Material

  • So, Ki-Ho;Park, Hyun-Tae;Shin, Sung-Chul;Lee, Sang-Gyeong;Lee, Dong-Hui;Lee, Kyeong-Hoon;Oh, Hyeong-Yun;Kwon, Soon-Ki;Kim, Yun-Hi
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1611-1615
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    • 2009
  • We designed new anthracene-based host material to increase color purity as well as device efficiency. The new blue host, 9,10-bis(2,4-dimethylphenyl)anthracene (BDA), has highly twisted structure and wide band gap due to ortho interaction between anthracene and introduced 2,4-dimethylphenyl substituents. BDA exhibited deep blue fluorescence in solution (${\lambda}_{max}$ = 410 nm) and in solid state (${\lambda}_{max}$ = 429 nm), respectively, with the wide optical band gap (E = 3.12 eV). Blue-light-emitting OLEDs using obtained host and 2% Flu-DPAN as emitter showed 8 cd/A of high efficiency as well as high color purity [CIE coordinates = (0.15, 015)].

Geotechnical parameters from pressuremeter tests for MRT Blue Line extension in Bangkok

  • Likitlersuang, Suched;Surarak, Chanaton;Wanatowski, Dariusz;Oh, Erwin;Balasubramaniam, Arumugam
    • Geomechanics and Engineering
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    • v.5 no.2
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    • pp.99-118
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    • 2013
  • Construction of the extension project of the Bangkok MRT Blue Line underground railway was recently started in 2011. The construction of approximately 5 km long underground tunnel and 4 deep excavations of underground station are considered to be the most important geotechnical works. The pressuremeter was selected as a high-quality in situ testing of the soil to evaluate design parameters for the project. In addition, other field and laboratory tests such as vane shear and $CK_0U$ triaxial tests were included in the investigation programme. This paper aims to present the ground conditions encountered along the MRT Blue Line extension project as well as the site investigation and interpretation techniques with particular focus on the pressuremeter tests. The results are also compared with the pressuremeter investigation from the previous Bangkok MRT project.

On the two different sequences of the mass-size relation for early-type galaxies

  • Kim, Jin-Ah;Yoon, Suk-Jin
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.2
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    • pp.48.3-49
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    • 2015
  • Scaling relations of early-type galaxies (ETG) provide a deep insight into their formation and evolution. Interestingly enough, most relations extending into the dwarf regimes display non-linear or broken-linear features, unlike the linear relations for normal (i.e., intermediate-mass to giant) ETGs only. Here we investigate the mass-size scaling relation of ETGs using a massive database of galaxies from SDSS DR12. We divide ETGs into two groups by the indication of star formation such as colors, and examine their distinction along the mass-size relation. We find that the mass-size distribution of blue, young normal galaxies is in good agreement with that of dwarf ETGs. Our result suggests that blue, young normal ETGs may serve as links between (passive) normal ETGs and dwarfs. We discuss the possibility of blue, young ETGs being progenitors of dwarf ETGs.

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Enhancement of the efficiency stabilization and the color coordinates in blue organic light-emitting devices with double emitting layers

  • Bang, H.S.;Han, S.M.;Lee, D.U.;Kim, T.W.;Kim, J.H.;Seo, J.H.;Kim, Y.K.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1030-1033
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    • 2006
  • The efficiency stabilization and the color coordinates in blue organic light-emitting devices (OLEDs) with a double emitting layer (DEL) consisting of 4,4'-Bis(carbazol-9-yl)biphenyl (CBP) and 4,4'-Bis(2,2-diphenyl-ethen-1-yl)diphenyl were investigated. The efficiency of the OLEDs with a DEL did not significantly change with an increase in current density. The Commission Internationale de l'Eclairage coordinates of the OLEDs with a DEL 11 V were (0.150, 0.137), indicative of a deep blue color.

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Correlation between optimized thicknesses of capping layer and thin metal electrode for efficient top-emitting blue organic light-emitting diodes

  • Hyunsu Cho;Chul Woong Joo;Byoung-Hwa Kwon;Chan-mo Kang;Sukyung Choi;Jin Wook Sin
    • ETRI Journal
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    • v.45 no.6
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    • pp.1056-1064
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    • 2023
  • The optical properties of the materials composing organic light-emitting diodes (OLEDs) are considered when designing the optical structure of OLEDs. Optical design is related to the optical properties, such as the efficiency, emission spectra, and color coordinates of OLED devices because of the microcavity effect in top-emitting OLEDs. In this study, the properties of top-emitting blue OLEDs were optimized by adjusting the thicknesses of the thin metal layer and capping layer (CPL). Deep blue emission was achieved in an OLED structure with a second cavity length, even when the transmittance of the thin metal layer was high. The thin metal film thickness ranges applicable to OLEDs with a second microcavity structure are wide. Instead, the thickness of the thin metal layer determines the optimized thickness of the CPL for high efficiency. A thinner metal layer means that higher efficiency can be obtained in OLED devices with a second microcavity structure. In addition, OLEDs with a thinner metal layer showed less color change as a function of the viewing angle.