• Title/Summary/Keyword: Decrease rate

Search Result 6,181, Processing Time 0.044 seconds

Effects of Neutral Salts on Alkaline Hydrolysis of Poly(ethylene terephthalate) (II) - Anionic Effect - (중성염이 Poly(ethylene terephthalate) 직물의 알칼리 가수분해에 미치는 영향(II))

  • Do, Sung-Guk;Cho, Hwan
    • Textile Coloration and Finishing
    • /
    • v.6 no.2
    • /
    • pp.10-16
    • /
    • 1994
  • Neutral salts have negative or positive effects on the rates of many chemical reactions and also on the rates of acidic and alkaline hydrolysis of carboxylic esters. The direction of neutral salt effects on the hydrolysis of ester depends on the charge of esters. Neutral salts accelerate alkaline hydrolysis of esters with negative charge, but decelerate alkaline hydrolysis of esters with positive charge, and have little effect on the alkaline hydrolysis of neutral esters. It is expected that the rate of the alkaline hydrolysis of Poly(ethylene terephthalte) (PET), polymeric solid carboxylic polyester with carboxyl end group at the polymer end, is also influenced positively by neutral salts. In the present work, to clarify the mechanism of the neutral salt effect on the alkaline hydrolysis of PET, many salts with different anions like NaF, NACl, NaBr, NaI were added to the aqueous alkaline solutions. Then PET was hydrolyzed with aqueous solutions of many salts in alkali metal hydroxides under various conditions. Some conclusions obtained from the experimental results were summarized as follows. The reaction rate of the alkaline hydrolysis of PET was increased by the addition of neutral salts and In k was increased nearly linearly with the square root of ionic strength of reaction medium. This fact suggested that the ionic strength effect by Debye-Huckel and Bronsted theory was exerted on the reaction. The specific salt effect was also observed. The reaction rate was increased with the decrease in the nucleophilicity of anions of neutral salts, i.e., in the order of $F^-$ <$Cl^-$<$Br^-$<$I^-$. It was thought that the reaction rate was increased in the order of $F^-$ <$Cl^-$<$Br^-$<$I^-$. because the completion of anions with $OH^-$ for carbonyl carbon became weaker with the decrease in the nucleophilicity and with the increase in the size of anions.

  • PDF

Effects of a Smoking Cession Program Using Telephone Counselling and Text Messaging for Patients after Ischemic Heart Disease (전화상담과 문자메시지 제공이 허혈성 심질환자의 금연에 미치는 효과)

  • Kim, Eun-Shim;Choi, Hye-Ok
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.15 no.12
    • /
    • pp.7248-7258
    • /
    • 2014
  • The study was conducted as a quasi-experimental study targeting 60 patients with ischemic heart disease to determine how the smoking cessation program that uses telephone counseling and text messaging (short message) affects smoking cessation self-efficacy, nicotine dependence, co levels, and smoking cessation rate of the first, second experimental group at varying times of arbitration and control group. An examination of the effects of this program revealed the control group to have a significant increase in smoking cessation self-efficacy, smoking cessation rate than the first and second group but a significant decrease in the nicotine dependence, co levels. In addition, although the control group showed a significant increase in smoking cessation self efficacy, smoking cessation rate and a significant decrease in co levels than other groups, there was no difference in nicotine dependence. Therefore, a smoking cessation program that uses telephone counseling and text messaging (short message) for patients with ischemic heart disease worked for the smoking cessation rate and appeared to be more effective, depending on the times of arbitration.

Studies on variation of somatic cell in milk after administration of staphylococcus aureus vaccine and immunostimulant and antibiotics resistance of isolated staphylococcus spp in milk from dairy cow (유우에서 포도상구균 백신과 면역증강제 투여후 우유의 체세포수 변화 및 분리된 포도상구균의 항생제 내성에 관한 조사)

  • 성명숙;김규섭;김우현;박희주;배성수;권헌일
    • Korean Journal of Veterinary Service
    • /
    • v.23 no.1
    • /
    • pp.61-69
    • /
    • 2000
  • Thirty-one dairy cow from two farm(more than 500,000 cells/ml of bulk milk) in Kyongbuk northern province were selected because of their high somatic cell(more than 500,000 cells/ml of milk In individual cow). Each cow received. staphylococcus aureus vaccine(Labac Staph) and immunostimulant(Ultracon) by intramuscular injection to be repeated every fifteen days for S times. The present study was investigated variation of somatic cell after administration of Labac Staph and Ultracon, and antibiotics resistance of isolated staphylococcus spp from milk in selected cow. The results obtained through the survey were summarized as follows ; 1. Ten dairy cow was injected in A farm. Chronic mastitic two cow after 2rd injection was weeded out the herd. Decrease rate of somatic cell after 1st, 2nd, ,3rd, 4th and 5th administration were 41.4%, 35.6%, 56.4%, 65.4% and 36.7%, respectively. Twenty-one cow was injected in B farm. Chronic mastitic five cow after ,3rd injection was weeded out the herd. Decrease rate of somatic cell after 1st, 2nd, 3rd, 4th and 5th administration were 36.9%, 59.9%, 24.5%, 62.6% and 78.4%, respectively. 2. In A farm, isolated staphylococcus spp were identified as S hyicus 2 strains(11.8%), coagulase negative staphylococcus 15 stains(89.2%) and S epidermidis 6strain(35.3%). In B farm, isolated staphylococcus spp were identified as S aureus 19 strains(55.98%) and coagulase negative staphylococcus 15 strains (44.2%). 3. In A fm, antibiotics resistant rate of isolated staphylococcus spp was high at ampicillin, penicillin and kanamycin, and middle at neomycin, streptomycin and erythromycin. in B farm, antibiotics resistant rate was moderate at ampicillin, penicillin, gentamicin, ka-namycin, neomycin, streptomycin, erythromycin and tetracycline, and coagulase negative staphylococcus spp was moderate at streptomycin.

  • PDF

An Effect of Qi Gong Gymnastics Program on the Physiopsychological Parameter in Essential Hypertension (기공체조프로그램이 고혈압 환자의 생리.심리적 지수에 미치는 영향)

  • 이명숙;최의순
    • Journal of Korean Academy of Nursing
    • /
    • v.28 no.4
    • /
    • pp.856-868
    • /
    • 1998
  • The purpose of this study is to evaluate the effects of Qigong gymnastics exercise program on the physiopsychological parameter in essential hypertension. The design of the research was a one group pretest-posttest design. A total of 20 pateints with hypertension who were from forty to sixty-five years old participated in the study. The Qigong gymnastics program was carried out twice a week for thirty minutes or forty minutes for six weeks from 22, Sep. to 31, Oct. in 1997. In order to evaluate the effect of the Qigong gymnastics program physiological parameter (blood pressure, pulse rate, FVC, FEV1, Epinephrine, Norepinephrine, Cortisol) and psychological parameter(self-efficacy, Life satisfaction) were measured before and after the exercise program. Collected data was analyzed by the paired t-test with SAS package. The result are as follows : 1) There were significant decrease in systolic blood pressure and diastolic blood pressure, but there was no significant change in pulse rate. 2) There were no significant difference in FVC and FEV1 3) There were significant decrease in epinephrine, norepinephrine and cortisol. 4) There were significant improved in general self-efficacy and life satisfaction. 5) The effect of Qigong gymnastics program by measurement time on blood pressure and pulse rate were as follows : In a systolic blood pressure was gradually significant decreased from 1 week to 6 weeks and diastolic blood pressure was significantly decreased after 4weeks. But there was no significant change in pulse rate. This results suggest that Qigong gymnastics are an appropriate nursing intervention for clients with hypertension. For further research is necessary to reevaluate the effect with a letter experimental design and longer period than 8 weeks for the Qigong gymnastics program.

  • PDF

Studies on the Prevention of Excessive Drying Leaves during Burley Tobacco Curing II. Effect of the Shading Conditions on the Occurrence of Excessive Drying Leaves (버어리종 담배 건조시 급건엽 발생방지에 관한 연구 II. 차광의 영향)

  • 배성국;임해건;김경태
    • KOREAN JOURNAL OF CROP SCIENCE
    • /
    • v.32 no.1
    • /
    • pp.10-15
    • /
    • 1987
  • The experiment was designed to determine the proper shading rate and shading materials to decrease the excessive dried leaves during cure of burley tobacco. Five shading rates and seaven shading materials were applied on the pipe vinyl house from initial stage or yellow stage of cure. Temperature was lower and weight-loss of leaves delayed with shading from initial stage to browning stage of cure. Excessive dried leave were largely decreased as shading rate was increased to 70%. However, at shading rate more than 70%, its decreasing extent was fewer. Price per kg and physical properties improved considerably at shading rate of 50%. Shading materials alone could not completely prevent excessive dried leaves but it could decrease them. Orange, white and purple color vinyl among shading materials had so effects of shading as the black shading cloth during curing. However, white color vinyl didn't endure more than a few months due to sunshine. A difference of light quality in visible light was no significance on air curing.

  • PDF

Effect of Application Rate of a Slow-release Fertilizer in Three Media Containing Polyacrylic Acid Sodium Salt on Growth and Nutrient Contents of Potted Chrysanthemum 'Lima Honey' (Polyacrylic Acid Sodium Salt를 혼합한 세 종류 상토에 지효성 비료의 시비 수준이 포트-멈 'Lima Honey'의 생육과 무기원소 흡수에 미치는 영향)

  • Choi Jong-Myung;Wang Hyun-Jin
    • Journal of Bio-Environment Control
    • /
    • v.15 no.1
    • /
    • pp.35-46
    • /
    • 2006
  • Objective of this research was to determine the effect of application rate of a slow release fertilizer (SRF) in three root media, peatmoss+vermiculite (1:1, v/v; PV), peatmoss+composted rice hall (1:1, v/v; PR), and peatmoss+composted pine bark (1:1, v/v; PB), on growth and nutrient contents of potted chrysanthemum 'Lima Honey'. All media contained polyacrylic acid sodium salt at a rate of $4.5g L^{-1}$. The fresh and dry weights at 43 days after transplanting did not show statistical differences among treatments in each root media. Elevated application rate of SRF increased fresh and dry weights at 80 days after transplanting in PV and PB media, but not in PR medium. Elevated application rates of SRF resulted in the increase of tissue phosphorus content and decrease of tissue Ca, Na, and Zn contents at both 43 and 80 days after transplanting. Elevated application rates of SRF resulted in the decrease of pH and increase of EC and concentrations of ${NO_3}^-$ and ${P_2O_5}^{3-}$, K, Ca, and Mg in the soil solution of PV and PR media. The trends of those in PR media were also similar except ${NO_3}^-$. The differences among treatments in EC at 80 days after transplanting were less significant as compared to those at 43 days after transplanting in three media.

Theoretical Conception of Synergistic Interactions

  • Kim, Jin-Kyu;Vladislav G. Petin
    • Korean Journal of Environmental Biology
    • /
    • v.20 no.4
    • /
    • pp.277-286
    • /
    • 2002
  • An increase in the overall biological effect under the combined action of ionizing radiation with another inactivating agent can be explained in two ways. One is the supposition that synergism may attribute to a reduced cellular capacity of damn-ge repair after the combined action. The other is the hypothesis that synergism may be related to an additional lethal or potentially lethal damage that arises from the interaction of sublesions induced by both agents. These sublesions ave considered to be in-effective when each agent is applied separately. Based on this hypothesis, a simple mathematical model was established. The model can predict the greatest value of the synergistic effect, and the dependence of synergy on the intensity of agents applied, as well. This paper deals with the model validation and the peculiarity of simultaneous action of various factors with radiation on biological systems such as bacteriophage, bacterial spores, yeast and mammalian cells. The common rules of the synergism aye as follows. (1) For any constant rate of exposure, the synergy can be observed only within a certain temperature range. The temperature range which synergistically increases the effects of radiation is shifted to the lower temperature fer thermosensitive objects. Inside this range, there is a specific temperature that maximizes the synergistic effect. (2) A decrease in the exposure rate results in a decrease of this specific temperature to achieve the greatest synergy and vice versa. For a constant temperature at which the irradiation occurs, synergy can be observed within a certain dose rate range. Inside this range an optimal intensity of the physical agent may be indicated, which maximizes the synergy. As the exposure temperature reduces, the optimal intensity decreases and vice versa. (3) The recovery rate after combined action is decelerated due to an increased number of irreversible damages. The probability of recovery is independent of the exposure temperature for yeast cells irradiated with ionizing or UV radiation. Chemical inhibitors of cell recovery act through the formation of irreversible damage but not via damaging the recovery process itself.

Ketamine-Induced Blood Pressure Lowering in the Rat (흰쥐에서 Ketamine에 의한 혈압하강)

  • Yu Xian-Feng;Kim Shang-Jin;Lee Mun-Young;Kang Hyung-Sub;Kim Jin-Shang
    • Journal of Veterinary Clinics
    • /
    • v.22 no.3
    • /
    • pp.220-227
    • /
    • 2005
  • Although ketamine has been used in the field of anesthetic medicine for its safety and favourable respiratory effects, the cardiovascular effects of ketamine is still controversial. To clarify the action and mechanism of ketamine upon cardiovascular system, arterial blood pressure, tension of aortic ring, left ventricular developed pressure and heart rate were measured in rats, Ketamine produced two types of effects on arterial blood pressure in anesthetized rats; monophasic effect (blood pressure lowering) and biphasic effect (initial transient blood pressure increasing following sustained lowering), The ketamine-induced lowering of aterial blood pressure showed a concentration-dependent manner, inhibited by the pretreament of $MgCl_2$ and potentiated by the pretreatment of $CaCl_2$. The ketamine-induced lowering of aterial blood pressure was suppressed by the pretreatment of nifedipine, verapamil or lidocaine. In phenylephrine-precontracted endothelium intact (+E) aortic rings, ketamine sometimes caused a small enhancement of contraction ($112.5{\pm}3.6{\%}$). However, in many experiments, ketamine produced a concentration-dependent relaxation in +E aortic rings precontracted with either phenylephrine or KCl. Ketamine-induced relaxation was significantly greater in KCl-precontracted strips than phenylephrine-precontracted strips. In phenylephrine-precontracted +E aortic rings, the ketamine-induced vasorelaxation was not suppressed by endothelium removal or by the pretreatment of a nitric oxide synthase inhibitors, L-$N^G$-nitro-arginine and a guanylate cyclase inhibitors, methylene blue, suggesting that the ketamine-induced vasorelaxation is not dependent on the endothelial function. In addition, ketamine elicited an increase in left ventricular developed pressure in perfused hearts accompanied by decrease in heart rate. These results suggest that ketamine could evoke a hypotension due to vasorelaxation and decrease in heart rate in rats. The inhibitory effect of cardiovascular system might be associated with modulation of $Ca^{2+}$ homeostasis.

Experimental Studies on the Cardiovascular Effects of Haloperidol in Cat and Rabbit (Haloperidol 이 심혈관계에 미치는 영향)

  • Ahn, Young-Soo
    • The Korean Journal of Pharmacology
    • /
    • v.11 no.2
    • /
    • pp.19-27
    • /
    • 1975
  • Haloperidol, a butyrophenone, was synthetized by Janssen and introduced for the treatment of psychosis. Although structurally different from the phenothiazines, the butyrophenones share many of their pharmacological properties, such as inhibition of conditioned avoidance response, blocking effect of amphetamine reaction, producing catalepsy, antishock effect and protection against the lethal effects of catecholalmines. Chlorpromazine can lower the arterial blood pressure through its adrenergic blocking activity, its direct effect in relaxing vascular smooth muscle, its direct effect in depressing the myocardium and its action in a complex manner on the central nervous system. In the case of haloperidol, however, was not clarified the mechanism of lowering the blood pressure. The present paper describes the effects of haloperidol on cardiovascular system to investigate the mechanisms of its actions on the arterial blood pressure. The results are followings; 1. In anesthetized cats, intravenous administration of haloperidol and chlorpromazine in the dose of 0.1mg/kg produced a slight decrease in the blood pressure, which followed by complete recovery within $30{\sim}60$ minutes. In the dose of 3mg/kg, however, both produced an abrupt and marked decrease of the blood pressure, which followed by delayed recovery. 2. Haloperidol in the dose ranges of 0.1mg to 3.0mg/kg tended to produce the heart rate slowing in the cats, while chlorpromazine has no effect on the rate. 3. Following administration of haloperidol or chlorpromazine, epinephrine reversal in the arterial blood pressure was observed in the cat, however the responses of norepinephrine and acetylcholine were little affected. 4. In the isolated rabbit atrium the contractility was depressed by haloperidol in the doses over 0.5mg per 100ml, but the rate was not affected. In contrast, the epinephrine-induced contractility was not depressed after haloperidol treatment. However, the increased rate of atrium by epinephrine was partially blocked after haloperidol. 5. In the isolated rabbit aortic strip, epinephrine-induced contraction was blocked by haloperidol. With the above results, it may be concluded that the hypotensive effect of haloperidol was largely due to ${\alpha}$-adrenergic blocking properties and the direct effect in depressing the myocardium as well as its action on central nervous system.

  • PDF

Generation of Hydration Heat of the Concrete Combined Coarse Particle cement and Fly ash (조분시멘트와 플라이애시를 조합 사용한 콘크리트의 수화발열 특성)

  • Lee, Chung-Sub;Baek, Dae-Hyun;Cha, Wan-Ho;Kwon, O-Bong;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2008.04a
    • /
    • pp.889-892
    • /
    • 2008
  • This study, having combined and displaced fly ash known as admixture material that delays hydration reaction with coarse particle cement("CC" hereinafter) collected in particle classification method during ordinary portland cement("OPC" hereinafter), reviewed the hydration heat characteristics affecting the concrete. To reduce hydration heat, the study plain-mixed which used 100% OPC for WB 50% level 1, displaced CC at level 3 of 25%, 50% and 75% for OPC, and by displacing FA with admixture material at level 5 of 0%, 10%, 20%, 30% and 40%, experimented totally 16 batches. As a result of experiment, in the case of flow, the more CC displacement rate increased, the more it tended to decrease, and the more FA displacement rate increased, the more it decreased. As for simple adiabatic temperature rise by the CC and FA displacement rates, it decreased as displacement rate increased, and particularly in the case of FA40, temperature rise amount, $5.8{\sim}7.4^{\circ}C$, was very low. Compressive strength decreased in proportion to displacement rate, however strength reduction increment was shown to decrease with age progress.

  • PDF