• 제목/요약/키워드: Decolorization

검색결과 322건 처리시간 0.029초

광촉매-분산 실리카 함침 콘크리트의 내구성 및 정화성능 평가 (Evaluation of Durability and Self-clearing in Concrete Impregnated with Photocatalyst-colloidal Silica)

  • 김혁중;김영기;권성준
    • 한국구조물진단유지관리공학회 논문집
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    • 제22권5호
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    • pp.47-54
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    • 2018
  • 콘크리트는 장기간 사용환경에 노출되면서 다양한 표면열화과정을 거친다. 실리케이트 기반 함침제는 콘크리트 표면에 적용되어 불용성 수화물을 형성하는데, 이 과정에서 다양한 공학적 장점을 기대할 수 있다. 본 연구는 분산형 실리케이트를 사용하여 표면의 내구성능을 강화하고 이후 광촉매를 분무함으로서 표면 함침된 콘크리트의 자기정화능력을 평가하는 것이다. 이를 위해 실리케이트 함침 콘크리트에 대하여 압축강도 뿐 아니라, 흡수성, 건조 수축, 염소이온저항성, 황산저항성, 동결융해 저항성 등과 같은 내구성 실험이 수행되었다. 또한 아세트 알데이드 및 메틸렌블루 반응 평가를 통하여 독성카스의 제거와 자기정화성능을 평가하였다. 실리케이트 함침 후 광촉매 도포를 함으로서 광촉매의 부착성을 확보할 수 있었으며, 콘크리트의 내구성 개선과 광촉매 고유의 정화성능을 유지할 수 있었다.

Novel Photocatalytic and Antibacterial Activities of Three-Dimensional (3D) Polycrystalline Anatase TiO2 Structures

  • Lee, Hyun Uk;Yun, Hyung Joong;Son, Byoungchul;Seo, Jung Hye;Kim, Hyeran;Choi, Saehae;Jeon, Cheolho;Kim, Hae Jin;Lee, Jouhahn
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.635-635
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    • 2013
  • We report three-dimensional polycrystalline anatase TiO2 structures (3D a-TiO2) for environmental and bio-medical applications. The 3D a-TiO2 was synthesized without thermal treatment by the growth of rod-like polycrystals on Degussa P25 (P25) via low temperature (< $85^{\circ}C$) modified alkali hydrothermal processing. X-ray diffraction and high-resolution transmission electron microscopic results showed that the rod-like polycrystals of 3D a-TiO2 possessed the highly anatase nanostructures. The photocatalytic activity of 3D a-TiO2 was found to be 2.2 times higher than that of P25. The recyclability of the 3D a-TiO2 was found to be high: the decolorization rate was 94.8% of the initial value after fifteen cycles. In addition, 3D a-TiO2 exhibited excellent antibacterial activities for the sterilization of gram-negative Escherichia coli (E. coli) and gram-positive Staphylococcus aureus (S. aureus). Even at the 10th recycled use, more than 98.4% of E. coli and S. aureus can be killed. These results indicated that 3D a-TiO2 might have utility in several promising applications such as photocatalytic water/air purification and bactericidal agents.

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고추의 열풍건조(熱風乾燥)가 품질(品質)에 미치는 영향(影響) (The Effects of the Hot Air Drying of Red Pepper on the Quality)

  • 김공환;전재근
    • 한국식품과학회지
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    • 제7권2호
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    • pp.69-73
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    • 1975
  • 고추의 열풍건조방법(熱風乾燥方法)이 품질(品質)에 미치는 영향을 연구한 결과는 다음과 같이 요약할 수 있다. 1. 절단건조(切斷乾燥)의 경우 생기는 부분적(部分的)인 탈색(脫色)은 묽은 염산의 처리로 방지(防止)할 수 있었으며 염산처리가 capsaicine 함량(含量)에는 별 영향(影響)을 주지 않았다. 2. 건조온도(乾燥溫度)는 고추의 capsanthin 함량(含量)에 영향을 주어 온도(溫度)의 상승은 capsanthin 함량(含量)의 감소(減少)를 초래(招來)하였다. 건조방법(乾燥方法)에 있어서 절단건조(切斷乾燥)고추는 원형건조(原形乾燥) 고추보다 capsanthin 함량(含量)이 높았고 장기(長期) 저장 후의 외관적색도(外觀赤色度)가 원형건조(原形乾燥)에 비하여 높았다. 또한 $60^{\circ}C$에서 절단건조(切斷乾燥)를 하면 일광건조(日光乾燥)보다 오히려 높은 capsanthin 함량(含量)을 보였다. 3. 건조온도(乾燥溫度)는 capsaicine 함량(含量)에는 별로 큰 영향이 없었으나 건조방법(乾燥方法)에 따라서는 상당한 차이를 보여 절단건조(切斷乾燥)의 경우 원형건조(原形乾燥)에 비하여 $20{\sim}30%$의 capsaicine 감소(減少)가 있었다. 한편 원형건조(原形乾燥)고추는 일광건조(日光乾燥)고추보다 높은 capsaicine 함량(含量)을 보였다.

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오존 기상처리방법에 의한 비스코스 레이온의 탈색효과 (Decoloring Effect of Viscose Rayon by Using Vapor Type Ozone Processing)

  • 김경아;이문수
    • 자연과학논문집
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    • 제10권1호
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    • pp.103-109
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    • 1998
  • 본 연구는 오존의 강한 산화력을 이용하여 기상의 처리방법에 따른 비스코스 레이온의 탈색효과를 연구하였다. 오존이 발생할 때는 기체상태로 고농도이지만, 수용액 상태로 물에 녹이는 과정에서 기화요인에 의하여 오존의 손실이 많았다. 따라서 기존의 오존처리방법인 수용액상태의 처리방법이 아니라 기상의 오존을 직접 직물에 처리하므로 고농도의 오존을 단시간동안 처리하여 직물에 존재하는 색소를 산화시켜 탈색하는 방법을 사용하였다. 기상의 오존은 직접 유기색소와 반응하지 않기 때문에 물을 매개체로 하여 pick up ratio를 60%, 50%, 40%, 30%, 20%로 변화시키면서 비스코스 레이온의 탈색에 대하여 연구하였다. Pick up ratio가 40%일 때가 유기색소를 분해하는데 필요한 최적의 수산기가 발생하므로 처리포의 탈색효과가 가장 좋았다. 그러나 처리기간이 길수록 너무 과다하게 오존에 의해 산화되므로 강도와 신도의 저하를 초래하였다. 따라서 최적의 기상오존 처리시간은 60분정도에서 처리하는 것이 강도와 신도의 저하를 가장 적게 할 수 있고 백도도 향상시킬 수 있는 것으로 사료된다.

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반룡환의 흰쥐태아중뇌에서의 도파민세포 보호효과 (Neuroprotective Effects of Banryong-hwan in Primary Rat Mesencephalic Dopaminergic Neurons)

  • 주미선;김효근;심진섭;오명숙
    • 대한본초학회지
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    • 제23권3호
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    • pp.53-60
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    • 2008
  • Objectives : Oxidative stress has a critical role in neurodegenerative diseases. In this study, we investigated the antioxidant and neuroprotective effects of the ethanolic extract of Banryong-hwan (BRHE) in SH-SY5Y cells and primary rat mesencephalic dopaminergic neurons. Methods : To assess the antioxidant effects, we carried out 1,1-diphenyl-2-picrylhydrazyl(DPPH) free radical scavenging assay, 2,2'-azino-bis(3-ethylbenzthiazoline-6-sulphonic acid)(ABTS) radical cation decolorization assay, and determination of total polyphenolic content. We evaluated the effect of BRHE treatment on neuroprotection against 6-hydroxydopamine(6-OHDA) toxicity using thiazolyl blue tetrazolium bromide(MTT) assay, nitric oxide(NO) assay, reactive oxygen species(ROS) assay in SH-SY5Y cells and tyrosine hydroxylase(TH) immunocytochemistry in primary rat mesencephalic dopaminergic neurons. Results : BRHE showed IC50 values of 328.10 ${\mu}g/mL$ and 43.12 ${\mu}g/mL$ in DPPH assay and in ABTS assay, respectively. Total polyphenolic content was 180.76 ${\mu}g/mL$. In SH-SY5Y cells, BRHE significantly attenuated the toxicity induced by 6-OHDA at the concentrations of 25-100 ${\mu}g/mL$ pre- and post- treatment in MTT assay. While 6-OHDA increased the NO and ROS contents, BRHE decreased them in a dose dependent manner. Moreover, in primary dopaminergic neuron culture, BRHE significantly protect-ed the dopaminergic cell loss against 6-OHDA toxicity up to 136% at the concentration of 75 ${\mu}g/mL$. Conclusions : These results demonstrate that BRHE has neuroprotective effect against 6-OHDA induced neurotoxicity through decreasing NO and ROS generation.

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초오 약침 개발을 위한 백서 독성 연구 및 생리활성에 대한 연구 (The Study on toxicity and biological activities of Aconiti ciliare tuber Pharmacopuncture in Rats Original Articles)

  • 김성철;안성훈;김성하;이상관;송봉근
    • 대한약침학회지
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    • 제14권1호
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    • pp.25-33
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    • 2011
  • Objective : We investigate toxicity of Aconiti ciliare tuber and antioxidant activity of Aconiti ciliare tuber Pharmacopuncture to develop safe Aconiti ciliare tuber Pharmacopuncture and find out the effect. Methods : In order to investigate toxicity of Aconiti ciliare tuberm, we administered Aconiti ciliare tuberm orally to rats and examined the survival rate, comparing with the survival rate of rats administered by Radix aconitum simmered with Semen Glycine and Radix Glycyrrhizae. We examined the in vitro biological activity of Aconiti ciliare tuber Pharmacopuncture, including the total polyphenol content, and ABTS radical scavenging. Results and Conclusions : The $LD_{50}$ of Radix aconitum simmered with Semen Glycine and Radix Glycyrrhizae was 9.0g/kg, on the other hand, the $LD_{50}$ of Aconiti ciliare tuberm was more than 15g/kg. The total polyphenol contents of Aconiti ciliare tuberm Pharmacopuncture was 2.31mg/L. The 2,2'-azinobis-3-ehtlbezothiazoline-6-sulfonic acid radical decolorization (ABTS) was 10.26%. We conclude that Aconiti ciliare tuberm is not highly toxic, Aconiti ciliare tuber Pharmacopuncture has a little antioxidant effect.

아조염료 분해균 Citrobacter sp. MB2 생육특성 (Growth Characteristics of Citrobacter sp. MB2, Azo Dyes Decolorizing Bacterium)

  • 권대준;지원대;권오준;이태종;이난희;손동화;최웅규
    • Applied Biological Chemistry
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    • 제49권3호
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    • pp.165-169
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    • 2006
  • 염색공단 주변의 토양과 하수로부터 아조염료 분해 탈색능이 우수한 MB2균을 분리하여 Citrobacter sp.로 동정하였다. Citrobacter sp. MB2의 성장 최적배지 및 배양조건은 sucrose 0.5%, yeast extract 1.0%, $K_2HPO_4$ 0.1%, $NaHCO_3$ 0.1%, pH 7.0, 배양온도 $30^{\circ}C$에서 호기적 진탕배양이었으며, 최적배지에서의 균성장은 분리용 배지나 nutrient broth에서의 균성장보다 각각 7배 및 50배 이상 개체수가 증가하였다. Citrobacter sp MB2는 금속염에 대해 강한 내성을 보였으며, 항생제 ampcillin과 penicillin G에 대해서 강한 내성을 보였다.

붕소가 도핑된 다이아몬드 전극을 이용한 오존발생과 발생된 오존에 의한 미생물 살균 효과 (Disinfaction effect of bacteria with ozone generation by BDD electrode)

  • 유지영;인진경;영진태명;등도소;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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    • pp.607-610
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    • 2003
  • Ozonic use of sterilization and heat treatment of raw material to extend the conservation period of food recently is increased by hard vegetable or microorganism sterilization purpose of fruit. If ozone can create as is easy comparatively because do air or oxygen by raw material and schedule period passes, there is advantage that do not leave the second contaminant because being gotten restored by oxygen. Also, because the effect is big to decolorization beside disinfection effect about microorganism, deodorization, disjointing of venomousness hazardous substance, food save, Indoor air purge, good hand processing, hydrospace agricultural chemicals processing etc. the use extent is wide. This research ran parallel a sterilization experiment of E.coli colitis germs by ozone that manufacture ozonizer that use doped diamond maund electrode (BDD) by boron and searched special quality electrochemistry enemy of the ozonizer and is created. After cultivate E.coli colitis germs during 37C 1 day is LB ship, after do ozonation, was sterilized more than 90% by ozone as result that examine disinfection effect by substance microscope and could confirm excellency of diamond electrode.

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Highly Photocatalytic Performance of flexible 3 Dimensional (3D) ZnO nanocomposite

  • Lee, Hyun Uk;Seo, Jung Hye;Son, Byoungchul;Kim, Hyeran;Yun, Hyung Joong;Jeon, Cheolho;Lee, Jouhahn
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.270.1-270.1
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    • 2013
  • Zinc oxide (ZnO) is one of the most powerful materials for purifying organic pollutants using photocatalytic activity. In this study, we have introduced a novel method to design highly photoreactive flexible 3 dimensional (3D) ZnO nanocomposite [F-ZnO-m (m: reaction time, min)] by electrospinning and simple-step ZnO growth processing (one-step ZnO seed coating/growth processing). Significantly, the F-ZnO-m could be a new platform (or candidate) as a photocatalytic technology for both morphology control and largearea production. The highest photocatalytic degradation rate ([k]) was observed for F-ZnO-m at 2.552 h-1, which was 8.1 times higher than that of ZnO nanoparticles (NPs; [k] = 0.316 h-1). The enhanced photocatalytic activity of F-ZnO-m may be attributed to factors such as large surface area. The F-ZnO-m is highly recyclable and retained 98.6% of the initial decolorization rate after fifteen cycles. Interestingly, the F-ZnO-m samples show very strong antibacterial properties against both Gram-negative Escherichia coli (E. coli) and Gram-positive Staphylococcus aureus (S. aureus) after exposure to UV-light for 30 min. The antibacterial properties of F-ZnO-m samples are more effective than those of ZnO NPs. More than 96.6% of the E. coli is sterilized after ten cycles. These results indicate that F-ZnO-m samples might have utility in several promising applications such as highly efficient water/air treatment and inactivation of pathogenic microorganisms.

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리그닌의 분해가 우수한 Streptomyces halstedii ssp. scabies SA1-27과 Streptomyces violaceusinger C1-6에서 생성되는 효소들에 관한 연구 (The Study of Enzymes Produced by Streptomyces halstedii ssp. scabies SA1-27 and Streptomyces violaceusinger C1-6 Which Have Good Lignolytic Activity)

  • 김태전
    • 대한임상검사과학회지
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    • 제38권2호
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    • pp.87-93
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    • 2006
  • This study was done to know a kind and change (transition) of enzymes produceed by Streptomyces halstedii ssp. scabies SA1-27 and Streptomyces violaceusinger C1-6 which showed good lignolytic activity and a good decolorization ratio of remazol brilliant blue R(RBBR) dye. These strains were isolated from soil and identified by the author. The basal medium containg 0.2% glucose was used to measure enzyme activity, Lignin peroxidase 1 (Lip 1) was measured by the methods of Choi, and Bourbonnais and Paice. Lignin peroxidase 2 (Lip 2) was measured by the methods of Ishida et al and Ramachandra et al using 2.4-dichlorophenol(2.4 DCP), manganese peroxidase(Mnp), veratryl alcohol oxidase (VAO), and laccase. They were measured by each of the methods of Choi and Paszczynski et al, and Bourbonnais and Paice, and De Jong et al. In the results, the kind of enzymes produced by Streptomyces halstedii ssp. scabies SA1-27 were Lip 1, Lip 2, VAO, and laccase, and their activities indicated the highest value as each 4.95 nmol/mg protein, $8.45({\times}100^{-3})unit$, 10.25 nmol/mg protein, 9.20 nmol/mg protein on the sixth day of the culture and decreased gradually over time. The kind of enzymes produced by Streptomyces violaceusinger C1-6 were Lip 1, Lip 2, Mnp, VAO, and laccase, and their activities indicated the highest value as each 4.90 nmol/mg protein, $13.85({\times}100^{-3})unit$, 3.10 nmol/mg protein, 11.30 nmol/mg protein, 4.45 nmol/mg protein on the sixth day of the culture and decreased gradually over time. Consequently, the author knew the fact that there were few differences in the kind and quantity of enzymes produced by the two Streptomyces strains, but all enzyme activities indicated the highest value on the sixth day of the culture and decreased gradually over time.

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