• 제목/요약/키워드: Decolorization

검색결과 322건 처리시간 0.027초

큰느타리(Pleurotus eryngii)의 방향족 합성염료 분해 특성 (Synthetic aromatic dye degradation by white rot fungus, Pleurotus eryngii)

  • 임경환;백승아;이태수
    • 한국버섯학회지
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    • 제20권2호
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    • pp.86-91
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    • 2022
  • 큰느타리(Pleurotus eryngii)는 azo계 염료인 CR, heterocyclic계 염료인 MB, triphenyl methane계 염료인 CV와 MG를 고체와 액체 배양 상태에서 모두 분해할 수 있었으며 고체 배양 조건에서는 CR을, 액체 배양 상태에서는 MG을 가장 효과적으로 분해했다. MB는 고체와 액체 배양 조건에서 모두 가정 적게 분해되었다. 4 종류의 염료 모두 균사의 생장을 저해했으나 MG의 영향이 가장 크게 나타났다. 활성을 측정한 두 종류의 리그닌 분해 효소 중 모두 laccase의 활성이 훨씬 높았으며 MnP 역시 활성은 낮았으나 laccsse와 비슷한 경향을 보였다. 따라서 큰느타리는 주로 laccase를 사용하여 방향족 합성염료를 분해하는 것으로 추정된다. CR, MB, CV는 laccase의 활성과 염료 분해 정도가 양의 상관관계를 보인 반면 MG의 경우 높은 효소 활성을 나타낸 후 염료의 분해가 진행되었다. 또한 MG가 모두 분해되었을 때의 laccase 활성(0.07 U/ml)이 다른 염료가 가장 많이 분해되었을 때의 활성(0.10 U/ml)보다 낮았는데 이는 큰느타리의 균사체가 MG를 분해하는 기작이 CR, MB 및 CR 등의 염료를 분해하는 기작과 차이를 보인다는 것을 알 수 있었다. 본 연구에서는 큰느타리의 방향족 합성염료 분해 능력에 대해 밝힘으로써 앞으로 국내산 버섯균주를 이용한 친환경적인 합성염료 처리 기술 개발에 도움을 줄 것으로 기대된다.

Novel Bi2S3/TiO2 Heterogeneous Catalyst: Photocatalytic Mechanism for Decolorization of Texbrite Dye and Evaluation of Oxygen Species

  • Zhu, Lei;Oh, Won-Chun
    • 한국세라믹학회지
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    • 제53권1호
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    • pp.56-62
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    • 2016
  • A heterogeneous $Bi_2S_3/TiO_2$ composite catalyst was synthesized via a green ultrasonic-assisted method and characterized by XRD, SEM, EDX, TEM analysis. The results clearly show that the $TiO_2$ particles were homogenously coated with $Bi_2S_3$ particles, indicating that $Bi_2S_3$ particle agglomeration was effectively inhibited after the introduction of anatase $TiO_2$. The Texbrite BA-L (TBA) degradation rate constant for $Bi_2S_3/TiO_2$ composites reached $8.27{\times}10^{-3}min^{-1}$ under visible light, much higher than the corresponding value of $1.04{\times}10^{-3}min^{-1}$ for $TiO_2$. The quantities of generated hydroxyl radicals can be analyzed by DPCI degradation, which shows that under visible light irradiation, more electron-hole pairs can be generated. Finally, the possible mechanism for the generation of reactive oxygen species under visible-light irradiation was proposed as well. Our result shows the significant potential of $Bi_2S_3$-semiconductor-based $TiO_2$ hybrid materials as catalysts under visible light for the degradation of industry dye effluent substances.

Microbiological Purification of L-Arabitol from Xylitol Mother Liquor

  • Jiang, Mingguo;Wang, Ben;Yang, Lifang;Lin, Shuangjun;Cheng, Hairong
    • Journal of Microbiology and Biotechnology
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    • 제21권1호
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    • pp.43-49
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    • 2011
  • As a rare sugar alcohol, L-arabitol can be used in food and can prevent extra fat deposits in the intestinal tract. Commercially, L-arabitol is prepared from pure L-arabinose by hydrogenation, which needs a high temperature and high pressure, leading to a high production cost for Larabitol. Therefore, this study describes a novel L-arabitol production method based on biological purification from the xylitol mother liquor, a cheap and readily available raw material that contains a high concentration of Larabitol. First, a novel Bacillus megaterium strain was screened that can utilize xylitol, sorbitol, and mannitol, yet not L-arabitol. The isolated strain was inoculated into a medium containing the xylitol mother liquor under formulated culture conditions, where a high L-arabitol yield (95%) and high purity (80%) were obtained when the medium was supplemented with 50 g/l of xylitol mother liquor. Upon further purification of the fermentation broth by ion exchange and decolorization, L-arabitol was crystallized with a purity of 98.5%.

유한요소법에 의한 평면 TV 새도우마스크의 열변형해석 및 전자빔 오착 예측 (Thermal Deformation Analysis of Shadow Mask in a Flat TV and Prediction of Electron Beam Landing Shift by FEM)

  • 김정;박수길;강범수
    • 대한기계학회논문집A
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    • 제26권11호
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    • pp.2297-2304
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    • 2002
  • Two-dimensional and three-dimensional finite element methods have been used to analyze the deformation behavior of a shadow mask due to thermal and tension load. The shadow mask inside the Braun tube of a TV set has numerous slits through which the electron beams are guided to land on the designed phosphor of red, green or blue. Its thermal deformation therefore causes landing shift of the electron beam and results in decolorization of a screen. For the realistic finite element analysis, the effective thermal conductivity and the effective elastic modulus arc calculated, and then the shadow mask is modeled as shell without slits. Next a transient thermal analysis of the shadow mask is performed, wherein thermal radiation is a major heat transfer mechanism. Analysis of the resulting thermal deformation is followed, from which the landing shift of the electron beam is obtained. The present finite element scheme may be efficiently used to reduce thermal deformation of a shadow mask and in developing prototypes of a large screen flat TV.

직접 산화와 간접 산화용 전극의 Dye 제거 성능 비교 (Comparison of Dye Removal Performance of Direct and Indirect Oxidation Electrode)

  • 김동석;박영식
    • 한국물환경학회지
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    • 제26권6호
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    • pp.963-968
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    • 2010
  • This study has carried out to evaluate the performance of direct and indirect oxidation electrode for the purpose of decolorization of Rhodamine B (RhB) in water. Four kinds of electrodes were used for comparison: Pt and JP202 (indirect oxidation electrode), Pb and boron doping diamond (BDD, direct oxidation electrode). The effect of applied current (0.5 ~ 2.5 A), electrolyte type (NaCl, KCl, HCl, $Na_2SO_4$ and $H_2SO_4$) and electrolyte concentration (0.5 ~ 2.5 g/L), solution pH (3 ~ 11) and initial RhB concentration (25 ~ 125 mg/L) were evaluated. Experimental results showed that RhB removal efficiency were increased with increase of current, NaCl dosage and decrease of the pH. However, the effect of operating parameter on the RhB removal were different with the electrode type. JP202 electrode was the best electrode from the point of view of performance and energy consumption. The order of removed RhB concentration per energy lie in: JP202>Pt>Pb>BDD.

칼럼크로마토그라피에 의한 아스퍼질러스 계통의 .alpha.-아미라제 및 프로테아제의 결정화 1 (Crystallization of a-Amylase and Protease of Aspergillus oryzae from Columm Chromatography (I))

  • 서항원
    • 미생물학회지
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    • 제9권4호
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    • pp.163-168
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    • 1971
  • Neutral protease which was obtained from a genus of Aspergilli as the crystal form were investigated for their purification and properties. The results of biochemical and enzymatic studies for their purification and properties in this enzyme were as follows. 1) On the wheat media containing 70%-water and $CaCo_{3}$, Aspergilus oryzae S.H.W. 131 is satisfactorily grown under the basic optimum conditions temperature $27^{\circ}C$- $30^{\circ}C$at relative humidity 100% for three days. 2) The enzyme solution extracted with water is successively purified through the passing on column of Asmti-177N for decolorization of it. And ion exchanger such as DEAAE Sphadex A-50 or Shepadex G-100 and fraction collector is necessary for the sepearte treatments of this enzyme. After washing it with organic solvents as aceton-EtOH, etc., it should be dried on the vacuum dryer at $40^{\circ}C$) The protease activity is determined by the amounts of amino acids, tyrosine. 4) The optimum pH of neutral protease is 6.0-8.0. 5) In effectively decomposing with this neutral protease, the optimum temperature is $35^{\circ}C$. 6) It is interesting that the amounts of metal ion affects the activity of neutral protease. For examples, if it were treated with manganic ion, its activity would be more effective than any other that.

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석영관 광촉매 반응기를 이용한 Rhodamine B의 색도 제거 (Decolorization of Rhodamine B Using Quartz Tube Photocatalytic Reactor)

  • 박영식
    • 한국환경보건학회지
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    • 제30권5호
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    • pp.358-365
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    • 2004
  • The photocatalytic oxidation of Rhodamine B(RhB) was studied using photocatalytic reactor filled with module of quartz tube. Module of quartz tube consisted of small quartz tube (inner diameter, 1.5 mm; outer diameter, 3 mm) bundle coated with powder $TiO_2$ and uncoated large quartz tube (inner diameter, 20 mm; outer diameter, 22 mm). Two 30 W germicidal lamp was used as the light source and the reactor volume was 0.5 l. The effects of parameters such as the coating materials and numbers, initial concentration, $H_{2}O_2$ dose and metal deposition (Ag, Pt and Fe) and simultaneous application of $H_{2}O_2$ and metal deposition. The results showed that the initial reaction constant of quartz module coated with powder $TiO_2$ was higher 1.4 time than that of the $TiO_2$ sol and optimum coating number is twice. In order to increase reaction rate, simultaneous application of photocatalytic and photo-fenton reaction using Fe coating and dose $H_{2}O_2$ dose increased reaction rate largely.

키틴의 염료 흡착에 의한 염액의 색소제거에 관한 연구(제1보) (Decoloration in Dyebath by Dye Absorption of Chitin(Part I))

  • 유혜자;이혜자;이전숙
    • 한국의류학회지
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    • 제24권3호
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    • pp.385-392
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    • 2000
  • The adsorption ability of dyes on chitin, a natural polymer was investigated for decolorization of dye wastewater. Chitin was manufactured in lab by decalcification in dilute aqueous HCI solution and deproteination in dilute aqueous NaOH solution with shrimp shells. Absorbance of residue solution of dyebaths after dye adsorptions of chitin were measured in varieties of dye concentration and dipping periods. Four kinds of dyestuffs were used, C.I.Acid Blue 29. C.I.Direct Blue 6, C.I.Reactive Orange 12 and C.I.Basic Red 18. When chtin 1g was dipped in 0.05% of dyebath with stirring, maximum adsorption ratio of each kind of dyes was exhibited as 91.6% for C.I.Acid Blue 29, 95% for C.I.Direct Blue 6, 58.2% for C.I.Reactive Orange 13 and 75.8% for C.I.Basic Red 19. It shows that chitin has better adsorption abilities of ionic dyes of acid, direct and basic dye than non-ionic reactive dye. And chitin has better adsorption abilities of anionic acid direct dyes than cationic basic dye because of the presence of nitrogen atoms. All kinds of dyestuffs used showed speedy absorption effects by chitin, so chitin can absorb much amount of dyes in 5 mimutes reach to equilibrium of adsorption in 2 hours after dipping. Basic dye was absorbed the most speedily in 5 minutes, although maximum adsorption ratio is not high. That reason can be thought that chitin surface is essentially negatively charged due to polar funtional groups.

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의류제품의 소비자 피해 사례에 대한 실증분석 (An Empirical Analysis on Consumer Damage Cases of Clothing Products)

  • 박영희
    • 패션비즈니스
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    • 제18권1호
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    • pp.149-163
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    • 2014
  • The purpose of this study is to investigate and analyze the actual conditions of consumer damage occuring in the use of clothing products. The data used for analysis included 470 cases, which were deliberated by requesting consumer disputes deliberation at the consumer consultation room of Masan YWCA at the Kyeongsangnamdo Consumer Life Center belonging to the Kyeongnam provincial office. The disputes regarding the clothing products insisted that consumers suffered damage for the period from March, 2011 to June, 2013. The data processing was carried out by SPSS 14 and the statistics techniques used went through a cross tabulation analysis and ${\chi}^2$-test. The results are as follows. The difference in the analysis result of purchase path and material as to kinds of clothing products showed a significant difference. The damage types of clothing products were classified into five types: change of color, change of style, change of surface and touch, breakage of subsidiary materials, and others. The damaged clothing products showed a difference for damage frequency according to the items of clothing products; in particular, damage frequency for change of color appeared high. The damage contents of change of color were identified as metachromatism, discoloration and yellowing, stain occurrence, and decolorization. The damage responsibility for these clothing products appeared to be various as to clothing items, but was higher at dry cleaners and manufacturers.

오존의 살균 및 탈취와 오존발생기의 발생농도 변화

  • 윤영미;고명석;김현종;이은미;정봉우;이현철
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2000년도 추계학술발표대회 및 bio-venture fair
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    • pp.473-474
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    • 2000
  • 오존의 강력한 산화력은 돈사 내 공기중에 부유하는 세균에 대하여 큰 살균효과를 나타냈는데, 이는 $0.05{\sim}0.07ppm$의 작업자와 돼지에게 피해를 최소화 할 수 있는 오존 농도 범위여서 그 효과가 크다 하겠다. 본 실험에서 오존은 발생장치 내에서의 원료공기(산소)의 체류시간에 따라 각기 다른 발생농도를 나타냈으며, 풍량이 14.7m^3/min$ 일 때 가장 높은 오존 농도를 보임을 알 수 있었다. 또한 오존 발생기를 개방형에서 폐쇄형으로 변형함으로써 같은 조건에서 더 높은 오존발생농도(폐쇄형: 0.13ppm, 개방형: 0.08ppm)를 얻을 수 있었다.

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