• Title/Summary/Keyword: DSC analysis

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Verification for the Cyclic Shear Behavior of Rough Granite Joint Using Constitutive Equation (구성방정식을 이용한 거친 화강암 절리면의 주기전단거동 특성규명)

  • 김대상;박인준;이희석
    • Journal of the Korean Geotechnical Society
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    • v.18 no.1
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    • pp.141-152
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    • 2002
  • Although a number of constitutive models have been proposed to define the behavior of geotechnical materials including elastic, plastic, and dynamic response, flew numerical models have been developed for the cyclic shear behavior of rock joints or interfaces. Such realistic constitutive models play an important role in analyzing and predicting the response of joints under dynamic loads. The purpose of this research is to verify the constitutive model modified for rough granite joints based on Disturbed State Concept(DSC) model, which has been successfully verified with respect to other materials such as dry sand-steel interface and wet sand-concrete interface. Furthermore, DSC model is compared and verified with respect to cyclic shear tests and numerical analysis results based on Plesha model. Based on the results of this research, it can be stated that DSC model is capable of characterizing the cyclic shear behavior of rough granite joints under dynamic loads.

Electrical Conduction Mechanism of AZO Thin Film and Photo-Electric Conversion Efficiency of Film-Typed Dye Sensitized Solar Cell (AZO 박막의 전기전도특성 및 필름형 염료 태양전지의 광전 변환 특성)

  • Kwak, Dong-Joo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.4
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    • pp.66-72
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    • 2010
  • In this paper, AZO thin film was deposited on polyethylene terephthalate(PET) substrate by r. f. magnetron sputtering method from a ZnO target mixed with 2[wt%] Al2O3. The flexible film-typed dye sensitized solar cell(F-DSC) was fabricated and photo-electric conversion efficiency was investigated. The results showed that the minimum resistivity and the maximum deposition rate of AZO conducting film were recorded as $1.8{\times}10^{-3}[{\Omega}{\cdot}cm]$ and 25.5[nm/min], respectively at r.f. power of 220[W]. From the analysis of XPS data an improvement of electrical resistivity or an increase in carrier concentration with increasing sputtering power may be related to the generation of lattice imperfections as a result of increasing component ratio of O1s/Zn2p, which generates donor carriers or active growth of crystalline grain. The photo-electric conversion efficiency of F-DSC with AZO conducting electrode was over 2.79[%], which was comparable as that with commercially available ITO electrode.

Thermal Behavior of Hwangto and Wood Flour Reinforced High Density Polyethylene (HDPE) Composites

  • Lee, Sun-Young;Doh, Geum-Hyun;Kang, In-Aeh
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.5
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    • pp.59-66
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    • 2006
  • The thermal properties of wood flour, Hwangto, and maleated polyethylene (MAPE) reinforced HDPE composites were investigated in this study. The thermal behavior of reinforced wood polymer composites was characterized by means of thermogravimetric (TGA) and differential scanning calorimetric (DSC) analyses. Hwangto and MAPE were used as an inorganic filler and a coupling agent, respectively. According to TGA analysis, the increase of wood flour level increased the thermal degradation of composites in the early stage, but decreased in the late stage. On the other hand, Hwangto reinforced composites showed the higher thermal stability than virgin HDPE, from the determination of differential peak temperature ($DT_p$). Decomposition temperature of wood flour and/or Hwangto reinforced composites increased with increase of heating rate. From DSC analysis, melting temperature of reinforced composites little bit increased with the addition of wood flour or Hwangto. As the loading of wood flour or Hwangto to HDPE increased, overall enthalpy decreased. It showed that wood flour and Hwangto absorbed more heat energy for melting the reinforced composites. Hwangto reinforced composites required more heat energy than wood flour reinforced composites and virgin HDPE. Coupling agent gave no significant effect on the thermal properties of composites. Thermal analyses indicate that composites with Hwangto are more thermally stable than those without Hwangto.

Cure Kinetics of DGEBA/MDA/HQ-PGE System (DGEBA/MDA/HQ-PGE계의 경화 반응 속도론)

  • Song, Young-Wook;Shim, Mi-Ja;Kim, Sang-Wook
    • Applied Chemistry for Engineering
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    • v.7 no.2
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    • pp.356-361
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    • 1996
  • Cure kinetics of diglycidyl ether of bisphenol A(DGEBA)/4,4'-methylene dianiline(MDA) with hydroquinone-phenyl glycidyl ether(HQ-PGE) as a reactive additive, which was preliminarily synthesized, was investigated by DSC and FT-IR analyses. Kissinger equation and Arrhenius' equation were used to calculate activation energy and pre-exponential factor. When HQ-PGE was added to DGEBA/MDA system, it reduced activation energy of system. When the 5 phr of HQ-PGE was added to DGEBA/MDA system, activation energy was 7.8 kcal/mol by FT-IR analysis and 11.3 kcal/mol by DSC, in comparison with the system without HQ-PGE, activation energy decreased about 30% and 9%, respectively. According to these results, HQ-PGE, introducing agent of this system, acted as a catalyst.

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Estimation of Thermal History in Power Cable Insulation Core Using by DSC Thermal Analysis (DSC를 이용한 전력케이블 절연체 열이력 추정법)

  • Jung, Sun-Young;Choi, A-Leum;Lee, Kyoung-Yong;Kim, Dong-Hun;Kang, Seung-Hun;Park, Keun-Ryong;Kim, Do-Young;Chang, Woo-Seog
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1467-1468
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    • 2011
  • 본 논문에서는 전력케이블 절연 코어의 열이력을 추정하기 위해 DSC를 이용한 열 이력 분석을 진행하였다. 일반적으로 전력케이블 절연코어에 인가된 열이력은 온도이력, 시간에 따라 그 열적거동이 달라지며, 이러한 특성을 이용하여, 제조공정 이력 및 운영시 부하온도 추정이 가능하다. 현재까지 보고된 열이력 추정연구는 XLPE절연체에 국한 되어 있으며, 온도 이력과 시간이 열적거동에 미치는 영향 및 반도전층 자재까지 확대하여 적용한 사례는 거의 보고되어 있지 않다. 본 논문에서는 DSC 모의실험을 통한 절연코어 샘플에 대하여, 열이력 추정 분석법의 유효성을 평가할 수 있었다.

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Kinetic Measurements on Elastomer by Differential Scanning Calorimetry (Differential Scanning Calorimetry에 의(依)한 탄성체(彈性體)의 속도론적(速度論的) 연구(硏究))

  • Choi, Sei-Young
    • Elastomers and Composites
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    • v.22 no.4
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    • pp.333-339
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    • 1987
  • A modern kinetic evaluation method for nonisothermal reactions measured with Differential Scanning Calorimetry(DSC) is presented. It is based on multiple linear regression analysis using a number of curve points in a selectable range of conversion. The obtained kinetic data are the basis to compute a reaction process under any condition e.g. isothermal or adiabatic. The DSC measurements was performed on a Mettler TA3000 SYSTEM with the built in evaluation software. Mainly the following reactions are discussed: vulcanization of natural rubber compounds containing vulcanizing accelerators. The purpose of this work is to analyse the vulcanization kinetics of typical NR vulcanization systems using DSC. These systems were chosen because they are typically reactive elastomer and are commercially important.

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Crystal Form of A Camptothecin Derivative (Camptothecin 유도체의 결정형)

  • Sohn, Young-Taek;Moon, Hyun-Young
    • Journal of Pharmaceutical Investigation
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    • v.32 no.2
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    • pp.81-85
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    • 2002
  • Three polymorphic modifications of CKD-602, water soluble derivative of camptothecin, were obtained by the recrystallization from different organic solvents and characterized by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and X-ray powder diffraction (XRPD). The major endothermic peaks of the DSC curve of Form 1, Form 2 and Form 3 was shown at $268.71^{\circ}C$, $247.83^{\circ}C$, $244.76^{\circ}C$, respectively. Form 2 was elucidated to be an acetic acid solvate and Form 3 was elucidated to be a methanol solvate. The dissolution patterns of these three modifications were also checked in distilled water at $37{\pm}0.5^{\circ}C$, for 30 minutes. The polymorphic modifications showed differences in the dissolution rate. The dissolution rate of Form 1 was faster than that of other polymorphic modifications. When stored at different relative humidity over the period of 3 months, all of the polymorphic modifications did not undergo transformation.

Robust Flight Control System Using Neural Networks: Dynamic Surface Design Approach (신경 회로망을 이용한 강인 비행 제어 시스템: 동적 표면 설계 접근)

  • Yoo, Sung-Jin;Choi, Yoon-Ho;Park, Jin-Bae
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.55 no.12
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    • pp.518-525
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    • 2006
  • This paper presents the adaptive robust control method for the flight control systems with model uncertainties. The proposed control system can be composed simply by a combination of the adaptive dynamic surface control (DSC) technique and the self recurrent wavelet neural network (SRWNN). The adaptive DSC technique provides us with the ability to overcome the 'explosion of complexity' problem of the backstepping controller. The SRWNNs are used to observe the arbitrary model uncertainties of flight systems, and all their weights are trained on-line. From the Lyapunov stability analysis, their adaptation laws are induced and the uniformly ultimately boundedness of all signals in a closed-loop adaptive system is proved. Finally, simulation results for a high performance aircraft (F-16) are utilized to validate the good tracking performance and robustness of the proposed control system.

Accelerating Effect of Organic Acid Treatment on Weight Reduction Characteristics of Sea-Island Type PET Supermicrofiber (1) (유기산 처리가 해도형 초극세 폴리에스터 섬유의 용출 특성에 미치는 영향 (1))

  • Kim, Hea-In;Jeong, Cheon-Hee;Min, Mun-Hong
    • Textile Coloration and Finishing
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    • v.24 no.1
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    • pp.45-53
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    • 2012
  • In order to make a supermicrofiber fabric with PET/co-PET sea-island type filament fiber, the optimum conditions of dissolution of co-PET composite filament fiber was examined. The data set was made at various organic acid concentration and steam temperature with treated time as a main variable. At the same time, the microstructure changes by organic acid treatment of sea-island type PET supermicrofibers were monitored by thermal analysis morphology, DSC thermgrams and SEM images. Weight reduction behavior of supermicrofibers by caustic treatment was investigated in a comparative method. The termination of dissolution was also confirmed using DSC thermgrams and SEM images.

A Study on Standard Testing Method for Type Approval of DSC Using MF/HF (MF/HF용 DSC의 형식검정을 위한 표준 시험방법)

  • 이동식;김기문
    • Journal of the Korean Institute of Navigation
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    • v.19 no.4
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    • pp.63-82
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    • 1995
  • This paper is a study on standard testing method for type approval of DSC which is the main structure of the terrestrial communication. As authority inspecting offices and producers have no experience for type approval of relative equipments as adapting GMDSS. In this paper, it is to be improved the understanding for type approval ; a system, standard of technic and testing methods, etc and make better quality of relative equipments. Additionally it could help quality and quantity improvement in all radiocommunication parts. Of course, the regulation for type approval had made but most makers didn't know it correctly, so the method of solution have been studied. By result of this study, with comparision and analysis of structure and a condition of efficiency with adapting GMDSS is could help some problems slove in the field and gave testing method of machinery and tools, electrical conditions, came out measurement and did ways standard efficiency.

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