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Study of PSII-treated PMMA, PHEMA, and PHPMA ; Investigation of Their Surface Stabilities

  • Hyuneui Lim;Lee, Yeonhee;Seunghee Han;Jeonghee Cho;Moojin suh;Kem, Kang-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.204-204
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    • 1999
  • The plasma source ion implantation(PSII) technique which is a method using high negative voltage pulse in plasma system has the potential to change the surface properties of polymer. PSII technique increase the surface free energy by introducing polar functional groups on the surface so that it improves reactivity, hydrophilicity, adhension, biocompatability, etc. However, the mobility of polymer chains enables the modified surface layers to adapt their composition to interfacial force. This hydrophobic recovery interrupts the stability of modified surfaces to keep for the long time. In this study, poly(methyl methacrylate)(PMMA), poly(2-hydroxyethyl methacrylate)(PHEMA), and polu(2-hydroxypropyl methacylate)(PHPMA) for contact lens application, were modified to improve the wettability with PSII technique and were investigated the surface stabilities. Polymer film was prepared with solution casting(3 wt.% solution) and was annealed at 11$0^{\circ}C$ under vacuum oven to remove solvent completely and to eliminate physical ageing. The thickness of the film measured by scanning electron microscopy (SEM) and surface profilometer was about 10${\mu}{\textrm}{m}$. Polymers were treated with different kinds of gases, pulse frequency, pulse with, pulse voltage, and treatment time. Even though PMMA, PHEMA, and PHPMA have similar repeat unit structure, the optimal treatment conditions and the tendency to hydrophobic recovery were different. PHPMA, more hydrophilic polymer than PMMA and PHEMA showd better wettability and stability after mild treatment. Surface tensions were obtained by water and diiodomethane contact angle measurements to monitor the relation between hydrophobic recovery and polymer structure. Different ion species in plasma change the polar component and dispersion component of polymer surface. For better wettability surface, the increase of polar component was a dominant factor. We also characterized modified polymer surfaces using x-ray photoelectron spectroscopy(XPS), secondary ion mass spectrometry(SIMS), Fourier Transform infrared spectroscopy(FT-IR), and SEM.

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Monthly changes in the rate of bycatch fishes and their immature ratio caught by gape net with wings in the coast of Yeosu and Jindo Island, Korea (여수와 진도 연안 낭장망에 어획된 어류 혼획률 월 변화 및 미성어 비율)

  • YOO, Joon-Taek;KIM, Yeong Hye;SONG, Se Hyun;PARK, Seongwook
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.52 no.1
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    • pp.72-77
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    • 2016
  • We examined monthly changes in the rate of fishes by-caught by gape net with wings and their immature ratio in the coast of Yeosu and Jindo Island, Korea. A minus correlation between bycatch rate, the ratio of fishes except for anchovy, Engraulis japonicus, to all fishes collected by gape net with wings, and individuals of the collected anchovy was significantly observed, implying that as the anchovy catch decreased and the bycatch rate increased. Immature ratios by the dominant bycatch species during the study is the following; Leiognathus nuchalis was 72.7~99.0%, Sphyraena pinguis was 84.0%, Sardinella zunasi was 90.0%, others (Leptocephalus, Trichiurus lepturus, Ammodytes personatus, Sphyraena pinguis, Trachurus japonicas, Mugil cephalus and Erisphex pottii) were 100.0%. In order to decrease the high bycatch rates of immature fishes in spring and autumn, our study suggested increasing of codend mesh size and developing suitable bycatch reduction devices in a gape net with wings.

The Post-glacial Vegetation History of the Lowland in Korean Peninsula (한반도 후빙기의 저지대 식생사)

  • 최기룡
    • The Korean Journal of Ecology
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    • v.21 no.2
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    • pp.169-174
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    • 1998
  • This is the review of vegetational history of the post-glacial period in Korea. most of studies for vegetational changes are located in the lowland alluvial plain, especially below the hilly zone of western and eastern coastal regions of Korea. A couple of methods, pollen analysis and radiocarbon dating, have been employed in these studies. These results lead us to establish the pollen zonation in Korea as the followings. Yasuda et al.(1980) classified six period in Yongrang lake of sokcho. These are as follow I. 17,000-15,000yr B.P.: Picea, Abies, Pinus(Haploxylon), Larix stage, II.15,000-10,000yr B.P:Herb, Pteridophyta stage, III.10.000-6,700yr BP.:Quercus stage, IV.6,700-4,500yr B.P.:Pinus, Quercus, Carpinus stage, V.4,500-1,400yr B.P.:Quercus. Pinus stage, VI.1,400yr B.P.-present: Pinus, Herbs stage. Jo(1979) also divided the period into two stages from the outcomes of analysis done in Jumoonjin and other sites I.10,000-6,000yr B.P.:Quercus stage, II.6,000-present: Pinus-Quercus stage, and three substages: IIa.6,000-3,400 yr B.P.:lower Pinus stage, IIb.3,400-2,000yr B.P.:Pinus-Quercus stage, IIc.2,000-present: Pinus stage. Choi(1993, 1996) divided the period into three stages: I.6,000-5,000yr B.P.:Alnus, Quercus stage, II.5,000-4,000yr B.P.: Alnus, Quercus, Pinus stage, III.4,500-2,600yr B.P.: Alnus, Pinus stage. In the period around 6,000yr B.P. distinct dominant species clearly occupied the lowland of the eastern and western coasts. Thus, this strongly supports the fact that even if Korea experienced its warm and wet climate after the lateglacial, it underwent a different environmental change, dry climate, compared to the regions of Japan.

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A Study on the Source Apportionment of the Atmospheric Fine Particles in Jeju area (제주지역 미세먼지의 오염원 규명에 관한 연구)

  • Hu, Chul-Goo;Yang, Su-Mi;Lee, Ki-Ho
    • Journal of Environmental Science International
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    • v.12 no.2
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    • pp.217-225
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    • 2003
  • Samples of size-fractionated PM10 (airborne particulate matter with aerodynamic diameter less than $10\mu\textrm{m}$) were collected at an urban site in Jeju city from May to September 2002. The mass concentration and chemical composition of the samples were measured. The data sets were then applied to the CMB receptor model to estimate the source contribution of PM10 in Jeju area. The average PM10 mass concentration was 28.80$\mu\textrm{g}/m^3$ ($24.6~33.49\mu\textrm{g}/m^3$), and the FP (fine particle with aerodynamic diameter less than $2.l\mu\textrm{m}$ fraction in PM10 was approximately 8% higher than the CP (coarse particle with aerodynamic diameter greater than $2.l\mu\textrm{m}$ and less than $10\mu\textrm{m}$ fraction in PM10. The CP composition was obviously different from the FP composition, that is, the most abundant water soluble species was nitrate ion in the FP, but sulfate ion in the CP. Also sulfur was the most dominant element in the FP, however, sodium was that in the CP. From CMB receptor model results, it was found that road dust was the largest contributor to the CP mass concentration (45% of the CP) and ammonium nitrate, domestic boiler, and marine aerosol were major sources to the CP mass. However, the secondary aerosol was the most significant contributor to the FP mass concentration (45% of the FP). In this study, it was suggested that the contributions of soil dust and gasoline vehicle became very low due to collinearity with road dust and diesel vehicle, respectively.

Effects of simulated acid rain on microbial activities and litter decomposition

  • Lim, Sung-Min;Cha, Sang-Seob;Shim, Jae-Kuk
    • Journal of Ecology and Environment
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    • v.34 no.4
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    • pp.401-410
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    • 2011
  • We assayed the effects of simulated acid rain on the mass loss, $CO_2$ evolution, dehydrogenase activity, and microbial biomass-C of decomposing Sorbus alnifolia leaf litter at the microcosm. The dilute sulfuric acid solution composed the simulated acid rain, and the microcosm decomposition experiment was performed at 23$^{\circ}C$ and 40% humidity. During the early decomposition stage, decomposition rate of S. alnifolia leaf litter, and microbial biomass, $CO_2$ evolution and dehydrogenase activity were inhibited at a lower pH; however, during the late decomposition stage, these characteristics were not affected by pH level. The fungal component of the microbial community was conspicuous at lower pH levels and at the late decomposition stage. Conversely, the bacterial community was most evident during the initial decomposition phase and was especially dominant at higher pH levels. These changes in microbial community structure resulting from changes in microcosm acidity suggest that pH is an important aspect in the maintenance of the decomposition process. Litter decomposition exhibited a positive, linear relationship with both microbial respiration and microbial biomass. Fungal biomass exhibited a significant, positive relationship with $CO_2$ evolution from the decaying litter. Acid rain had a significant effect on microbial biomass and microbial community structure according to acid tolerance of each microbial species. Fungal biomass and decomposition activities were not only more important at a low pH than at a high pH but also fungal activity, such as $CO_2$ evolution, was closely related with litter decomposition rate.

Post-Last Glacial Sea-Level Change and Time-Averaging appeared from the Molluscan Thanatocoenoses in the Southern Sea of Korea (한국 남해해역 패류군집에서 나타나는 시간평균화 현상과 최종 빙하기 이후 해수면 변동)

  • Lee, Yeon-Gyu
    • Journal of the Korean earth science society
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    • v.26 no.6
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    • pp.541-550
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    • 2005
  • Molluscan shells were sampled from the continental shelf of South Sea: 19 stations in the southeast continental shelf and 5 in the southwest sea, in order to understand characteristics of sea level changes and time-averaging since the last glacial age. Radiocarbon dates were made on 42 dominant and specific species which were sampled from 24 stations. Time-averaging was observed and showed to be 11,939 years in age difference. The sea-level ranged from 150 to 160 m below sea level during the LGM (about 15,000 yrs B.P). The sea-level significantly rose to 60 m at around 9,000 yrs B.P. and became stable at 50 to 60 m between periods between 4,000 and 5,000 yrs B.P. Between 3,000 and 4,000 yrs B.P, the sea-level rapidly rose to a depth of $10\~20m$ below today’s present sea level.

Analysis of the Restoration Actual Conditions on the Quarries II (토석채취지의 복구 실태 분석 II)

  • Park, Jae Hyeon
    • Journal of Korean Society of Forest Science
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    • v.101 no.4
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    • pp.558-566
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    • 2012
  • This study was conducted to offer preliminary data for a natural restoration by the actual condition survey of quarries after extracting rock materials. The mountain restoration area according to a farming and fishing village organize project was restored by green landscape after quarry. However, planting tree species were died due to poor maintenance and administration after restoration works and surface soil loss and erosion occurred during a summer rainfall season because of poor slope greening. It will be needed to review restoration constructions to establish a natural friendly and flawless construction through the selection of optimum restoration works and the examination of soil and geological characteristics. In addition, it is necessary to apply cost-reducing program of restoration constructions. Quarry areas could be restored by the selection of simple and optimum construction works because the most areas were dominant in earth-sand rocks, soft-rocks, and weather-rocks. In addition, the restoration construction project should be examined thoroughly by restoration specialists during green restoration planning and review processes.

Seasonal Changes of Phytoplankton Communities in the Paksil and Jungyang Marshes (박실지와 정양지의 식물플랑크톤 군집의 계절 변동)

  • Lee, Gyeong-Rak;Choe, Jae-Sin;Kim, Han-Sun
    • ALGAE
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    • v.18 no.4
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    • pp.273-280
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    • 2003
  • The physico-chemical characteristics and seasonal variations of phytoplankton community were investigated in the Paksil and Jungyang marshes. Water and phytoplankton samples for analyses were collected monthly from April 2002 to March 2003. A total of 421 taxa of phytoplankton belonging to eight classes identified. The number of taxa was highest in Bacillariophyceae, followed by Chlorophyceae, Euglenophyceae, Cyanophyceae, Chrysophyceae, Dinophyceae, Xanthophyceae and Cryptophyceae. The standing crops ranged from 1.25 ${\times}$ $10^6$ to 5.85 ${\times}$ $10^6$ cells ${\cdot}l^{-1}$ in Paksil marsh and 0.25 to 9.63 ${\times}$ $10^6$ cells ${\cdot}l^{-1}$ in Jungyang marsh. The highest algal density at Paksil marsh was recorded in October during the high development of Chlorococcales while the lowest value occured in July. In the Jungyang marsh, the maximum algal density was recorded in October when Cryptomonas sp. and Mallomonas sp. accounted for 64% to total cell numbers and the lowest cell density was observed in January due to the decrease of Chlorophyceae. The dominant species were represented by Euglena proxima, Trachelomonas oblonga, Trachelomonas volvocina of Euglenophyceae, Dictyosphaerium pulchellum, Monoraphidium griffithii, Oocystis parva of Chlorophyceae, Dinobryon sertularia, Kephyrion rubri-claustri of Chrysophyceae, Achnanthes minutissima of Bacillariophyceae and Cryptomonas sp. of Cryptophyceae in the Paksil and Jungyang marshes. Phytoplankton diversity(H’) and dominance index varied rather irregularly throughout the sampling period but they were significantly correlated. The highest diversity(H’Paksil = 3.68, H’Jungyang = 3.63) coincided with the lowest values of dominance(DPaksil = 0.05, DJungyang = 0.05)

Feeding Habits of Javelin Goby Synechogobius hasta on Tide Flat in Sangnae-ri Suncheon, Korea (순천 상내리 갯벌역에 출현하는 풀망둑(Synechogobius hasta)의 식성)

  • Park, Jong Hyeok;Jeong, Jae Mook;Kim, Hyeon Ji;Ye, Sang Jin;Baeck, Gun Wook
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.48 no.6
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    • pp.982-987
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    • 2015
  • During the study period, a total of 158 individuals of Synechogobius hasta were collected. The range of body length (BL) was 15.4-44.5 cm. The stomachs of 26.6% of the individuals were empty. The most abundant prey was shrimp. Among shrimp, Exopalaemon orientis was the most abundant species, being present in 27% in %IRI (index of relative importance). Fishes and crabs were also abundant prey. Analysis of ontogenetic changes, suggested that shrimp were the main prey of S. hasta of two size classes (<20 and 20-25 cm). The proportion of shrimp decreased, but that of fishes and crabs increased, with increasing body length, beginning at the 25-30 cm size class. In spring, fishes were the dominant prey, while shrimps, and crabs and fishes dominated in autumn and winter, respectively.

Ecological Evaluation of Marine National Parks Based on Seaweed Community Index (해조류 군집지수에 기초한 해양국립공원의 생태학적 평가)

  • Oh, Ji Chul;Choi, Han Gil;Kim, Cheol Do;Ahn, Jung Kwan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.49 no.3
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    • pp.385-392
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    • 2016
  • Seasonal variability in the algal community structure of intertidal zones was examined at six study sites in Marine National Parks, on the western and southern coasts of Korea from March to November 2015. A total of 193 species of algae, comprising 27 green, 40 brown and 126 red algae, were identified. Algal biomass averaged 101.50 g dry wt./m2 with a maximal at Tonggae (168.12 g dry wt./m2) and minimum at Haseom (54.49 g dry wt./m2). The dominant seaweeds by biomass were Sargassum thunbergii at five sites (Tonggae, Haseom, Namdongri, Ando amd Sinjeonri), and S. fusiforme at Soando. Community indices measured as follows: dominance index (DI), 0.31–0.69; richness index (R), 7.30–11.43; evenness index (J'), 0.33–0.49; and diversity index (H'), 1.15–1.86. As evaluated using community indices and environmental states, the EEI (Ecological Evaluation Index) of the Marine National Park was “normal”. The present results indicate that seaweed community structures and indices could be used to evaluate the environmental status of coastal ecosystems.