• Title/Summary/Keyword: DOC

Search Result 778, Processing Time 0.025 seconds

Decomposition of Organic Matters by Ozonation in Advanced Water Treatment Process (고도정수처리공정에서 오존의 유기물 분해능)

  • Yoon Taekyung;Lee Gangchoon;Noh Byeongjil
    • Journal of Environmental Science International
    • /
    • v.14 no.3
    • /
    • pp.327-333
    • /
    • 2005
  • The performance of ozone contactor in ozone-BAC advanced water treatment process was evaluated by the degree of decomposition of organic matters. The degree was measured by the analyses of $UV_{254}$ absorbance and the concentrations of DOC and BDOC for the sand filtered water and the ozone treated water, respectively. In addition, the ozone concentration in the contactor, required for the maximum BDOC concentration, was selected as the optimum concentration, and the appropriate residential time of ozone treated water in a reservoir was recommended based on the residual ozone concentration in the treated water. The following results were obtained from the pilot scale experiments. By ozonation $UV_{254}$ absorbance was decreased, and BDOC concentration was increased. The change of DOC concentration by ozonation was negligible, but the excess input of ozone resulted in the removal of the small amount of BDOC by complete oxidation. The optimum ozone concentration was 0.58mg $O_3/mg$ DOC. In order to remove residual ozone, 20minutes of the residential time were enough after ozonation.

An Experimental Study on Engine Performance, Exhaust Emissions and PM with a DOC by Appling Biodiesel in a Heavy Duty Diesel Engine (대형디젤 기관에서 바이오디젤을 적용한 DOC에 의한 기관성능, 배출가스 및 PM에 관한 실험적 연구)

  • Park, Man-Jae;Han, Young-Chool;Eom, Myung-Do;Kim, Mi-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.28 no.12
    • /
    • pp.1467-1474
    • /
    • 2004
  • Recently, with respect to an increase of energy consumption, many countries have tried to develop alternative fuels. In the United States, less than 10 percent of motor fuels will be displaced by alternative fuels by year 2010, with about 25 percent of the replacement fuels from renewable resources. But the level of exhaust gas is not decreased to the result of an increase of diesel vehicles. Moreover, emission regulations are being intensified by advanced countries such as America and Europe. Because Biodiesel is similar to diesel fuel, it is essential to judge the environmental and health effects deriving from the use of Biodiesel in diesel engine. Therefore, this research could be conformed whether both Biodiesel 20% and Biodiesel 100% are influenced on emission according to sulfur contents by applying DOC. As a result of using the Biodiesel, this research could be conformed though Nox was increased, CO, HC and PM were decreased, and also estimated to compare diesel fuel with the Biodiesel in accordance with engine performance and emission characteristics.

Emission Characteristics of Diesel Oxidation Catalysts for a Commercial Diesel Engine (상용 디젤엔진용 산화촉매의 배출가스 저감 특성)

  • Choi, B.C.;Lee, C.H.;Park, H.J.;Jung, M.K.;Kwon, G.M.;Shin, B.S.;Kim, S.S.
    • Journal of Power System Engineering
    • /
    • v.6 no.2
    • /
    • pp.18-23
    • /
    • 2002
  • Recently, as people pay attention to the environmental pollution, the emission of diesel engine has become a serious problem. Diesel Oxidation Catalysts(DOC) were experimentally investigated for the purification of pollutants exhaust emission from the diesel engine. In this study, the conversion efficiency of exhaust gas was investigated with various washcoat materials of the DOC. It was formed that CO conversion efficiency depended on temperature, but THC conversion was dominated by temperature and space velocity. Conversion efficiency of THC and CO increased with the addition of ZSM-5 in the washcoat, whereas these conversion efficiency decreased by adding Nd and Ba additives. $V_2O_5$ additive had the thermal stability for high temperature. Thermal durability of the catalyst was improved as increase of $V_2O_5$ additive.

  • PDF

Optimum Design of the Shock Absorber Position Using ADAMS and VisualDOC (ADAMS와 VisualDOC를 사용한 쇽업쇼버 위치의 최적설계)

  • Ok, Jin-Kyu;Baek, Woon-Kyung;Sohn, Jeong-Hyun
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.14 no.2
    • /
    • pp.1-8
    • /
    • 2006
  • In this paper, an optimum design technology is developed to find an optimal position of the shock absorber using ADAMS and VisualDOC. A vehicle with a torsion-beam rear suspension is modeled by using ADAMS. Design variables for the optimal positioning of the shock absorber are defined considering the hard points of the chassis structure and design positioning are specified through the sensitivity analysis using a bump-crossing simulation. The objective function is defined as the joint reaction forces of the shock absorber connecting joints of the chassis structure. Sequential Quadratic Programming and Genetic Algorithms are used for this study. To validate the optimized design variables, pothole simulations are performed. GA showed better results than SQP algorithms for this design purpose.

Efficiency Evaluation of Different Processes in Drinking Water Treatment (정수처리에서 서로 다른 공정의 처리효율에 대한 비교분석연구)

  • Kim, Hyung-Suk;Lee, Byoung-Ho
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.25 no.4
    • /
    • pp.597-604
    • /
    • 2011
  • This study was performed to compare finished water quality among three different processes. A detailed assessment of performance was carried out during the five months of operation. Finished water quality was evaluated on the basis of parameters such as Dissolved organic carbon (DOC), $UV_{254}$ absorbance, haloacetic acid formation potential (HAAFP), geosmin, 2-methylisoborneol (2-MIB), heterotrophic bacteria and total coliform bacteria. The treatment processes were Process 1 (coagulation-flocculation-sedimentation-sand filtration-ozone-GAC), Process 2 (coagulation-flocculation-sedimentation -microfiltration-ozone-GAC), and Process 3 (coagulation-flocculation-sedimentation- sand filtration-GAC), compared side by side in the pilot testing. Process 2 was found to have better removal efficiency of DOC, $UV_{254}$ absorbance, HAAFP and heterotrophic bacteria in comparison with process 1 and process 3 under identical conditions. Geosmin, 2-MIB and total coliform bacteria were not detected in finished water from each process.

EMISSION CHARACTERISTICS IN ULTRA LOW SULFUR DIESEL

  • Oh, S.-K.;Baik, D.-S.;Han, Y.C.
    • International Journal of Automotive Technology
    • /
    • v.4 no.2
    • /
    • pp.95-100
    • /
    • 2003
  • Automobile industry has been developed rapidly as a key manufacturing industry in Korea. Meanwhile, air pollution is getting worse noticeably than ever. In the diesel emission, PM (Particulate Matter) and NOx (Nitrogen Oxides) have been exhausted with a great amount and the corresponding emission regulations are getting stringent. In order to develop low emission engines, it is necessary to research on better qualified fuels. Sulfur contained in fuel is transformed to sulfur compound by DOC (Diesel Oxidation Catalyst) and then it causes to the increase of sulfate-laden PM on the surface of catalyst. In this research, ULSD (Ultra Low Sulfur Diesel) is used as a fuel and some experimental results are investigated. ULSD can reduce not only PM but also gas materials because cetane value, flash point, distillation 90%, pour point and viscosity are improved in the process of desulfurization. However, excessively reduced sulfur may cause to decease lubricity of fuel and engine performance in fuel injection system. Therefore, it requires only modest adjusted amount of sulfur can improve engine performance and DOC, as well as decrease of emission.

Physicochemical Characteristics Based on Hydrothermal Aging of Prepared DOC

  • Seo, Choong-Kil
    • Journal of Power System Engineering
    • /
    • v.17 no.5
    • /
    • pp.13-22
    • /
    • 2013
  • This paper reports the investigation of the physical and chemical characteristics of the prepared 3Pt-2MgO-$3ZrO_2$-$2CeO_2/Al_2O_3$ DOC, based on its hydrothermal aging. As a result of impregnating and reducing the $H_2PtCl_6$ $6H_2O$ precursor on a ${\gamma}-Al_2O_3$ basis, it was well dispersed into small particles with the range 2-3nm. This was because the $Al_2O_3$ acted as a barrier to prevent movement of the catalyst particles. For a hydrothermally aged catalyst for 9h at $700^{\circ}C$, its performance when purifying harmful gases decreased compared to a fresh catalyst, but its specific surface area was at the same level. This was because the performance of the catalyst was reduced by the sintering of the precious metal Pt, rather than by washcoat sintering and pore clogging. For an excessively hydrothermally aged catalyst for 9h at $850^{\circ}C$, Pt grew into an approximately 50nm class, formed a cluster compared to a fresh catalyst. The $CeO_2$ promoters also formed clusters among components of the same type, reducing their specific surface area to $114m^2/g$, which was 14% less than a fresh catalyst.

Characteristics of Organic Matters in the Suyeong River During Rainfall Event (강우 시 수영강 유역 내 유기물질의 특성)

  • Kim, Suhyun;Kim, Jungsun;Kang, Limseok
    • Journal of Korean Society on Water Environment
    • /
    • v.34 no.5
    • /
    • pp.487-493
    • /
    • 2018
  • Urban stormwater runoff is the one of the most extensive causes of deterioration of water quality in streams in urban areas. Especially, in the Suyeong River watershed, non-point sources from urban-residential areas are the most common cause of water pollution. Also, it has been ascertained that BOD and COD as indexes of organic matter, have limitation on management of Suyeong River's water quality. In this study, changes of organic matter properties of Suyeong River from inflow of non-point source during rainfall were investigated. Fractions of organic matters were analyzed using water samples collected at two sites (Suyeong River and Oncheon Stream) during a rain event. Variations of dissolved organic carbon (DOC) concentration by rainfall were similar to flow rate change in the river. Distribution of organic matter fraction according to change of rain duration revealed that while hydrophilic component increased at initial rainfall, the hydrophobic component was similar to change in dissolved organic carbon (DOC) concentration. Also, the relative proportion of hydrophilic components in organic matter in river water increased, due to rainfall. Results of biodegradation of organic matters revealed that decomposition rate of organic matters during rainfall was higher than that of during a non-rainfall event.

Applying methane and carbon flow balances for determination of first-order landfill gas model parameters

  • Park, Jin-Kyu;Chong, Yong-Gil;Tameda, Kazuo;Lee, Nam-Hoon
    • Environmental Engineering Research
    • /
    • v.25 no.3
    • /
    • pp.374-383
    • /
    • 2020
  • Landfill gas (LFG) emissions from a given amount of landfill waste depend on the carbon flows in the waste. The objective of this study was to more accurately estimate the first-order decay parameters through methane (CH4) and carbon flow balances based on the analysis of a full-scale landfill with long-term data and detailed field records on LFG and leachate. The carbon storage factor for the case-study landfill was 0.055 g-degradable organic carbon (DOC) stored per g-wet waste and the amounts of DOC lost with the leachate were less than 1.3%. The appropriate CH4 generation rate constant (k) for bulk waste was 0.24 y-1. The the CH4 generation potential (L0) values ranged 33.7-46.7 m3-CH4 Mg-1, based on the fraction of DOC that can decompose (DOCf) value of 0.40. Results show that CH4 and carbon flow balance methods can be used to estimate model parameters appropriately and to predict long-term carbon emissions from landfills.

Evaluation of Advanced Oxidation Process(AOP) as a Pretreatment Process of Biological Activated Carbon in Drinking Water Treatment (정수처리에서 생물활성탄의 전처리로서 고급산화처리법의 평가)

  • Kim Woo-Hang
    • Journal of Environmental Science International
    • /
    • v.8 no.6
    • /
    • pp.725-730
    • /
    • 1999
  • The advanced oxidation process (AOP) using ozone combined with hydrogen peroxide and ultraviolet treatment were evaluated for biodegradable dissolved organic carbon (EDOC) formation and dissolved organic carbon (DOC) removal. Oxidation treatment were conducted alone or combination with ozone, hydrogen peroxide and ultraviolet processes. Ozone dosage of ozone process was varied from $0.5mg/l{\ell}\cdot}min$ to $5mg/{\ell}{\cdot}min$. Ozone/hydrogen peroxide process was done using $20mg/{\ell}{\cdot}min$ of hydrogen peroxide concentration. Ozone/ultraviolet process was irradiated with $12mW/cm^2$ of density and 254nm. Ozone dosage was varied from $0.5mg/{\ell}{\cdot}min$ to $5mg/{\ell}{\cdot}min$ at the ozone/hydrogen peroxide and ozone/ultraviolet processes too. Contact time of all the process was 20 minutes. Oxidation treatment were performed on microfiltration effluent samples. BDOC formation was reached to an optimum at ozone dosage of $1.5mg/{\ell}{\cdot}min$ in the ozone/hydrogen peroxide process and $1mg/{\ell}{\cdot}min$ in ozone/ultraviolet process, after which BDOC formation was decreased at higher ozone dosages. But BDOC formation was increased with ozone dosages increasing in ozone process. The efficiency of DOC removal was higher AOPs than ozone process. Ozone/ultraviolet proces was the highest for DOC removal efficiency in each process. THMFP. removal efficiency by ozone/ultraviolet process was higher than that by each of ozone process and ozone/hydrogen peroxide process.

  • PDF