• Journal of Environmental Health Sciences
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• v.33 no.1 s.94
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• pp.36-42
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• 2007

Diesel PM can be controlled using Diesel Particulate Filter, which can effectively reduce the level of soot emissions to ambient background levels. In the Heavy Duty Diesel area, the Continuously Regeneration trap has been widely applied in the retrofit market. As the Special act for the improvement of air quality in the capital area, the retrofit program for DPF to used diesel vehicle has progressed favorably and there are currently over 1,000 of these DPF in use in retrofit applications in korea. These DPF comprise a specially formulated Diesel Oxidation Catalyst upstream of a DPF. The $NO_2$ generated by the DOC is used to combust the carbon collected in the DPF at low temperature. To certificate DPF device that is suitable to domestic circumstances, it is necessary to evaluate exactly the DPF devices according to the regulation of DPF certificate test procedure for retrofit(ministry of environment(MOE) announcement NO. 2005-16). To do so the understand of that regulation like the standard of PM reduction rate is needed. In this study the test procedure including test cycle and BPT test condition was examined and also the test result for specific DPF was analyzed. In every test like field test, PM reduction efficiency test and seoul-10 mode test, no defect could be showed.

• Transactions of the Korean Society of Automotive Engineers
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• v.20 no.5
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• pp.71-80
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• 2012

To improve the $NO_X$ conversion over a SCR (selective catalytic reduction) catalyst, the DOC (diesel oxidation catalyst) is usually placed upstream of the SCR catalyst to enhance the fast SCR reaction ($4NH_3+2NO+2NO_2{\rightarrow}4N_2+6H_2O$) using equimolar amounts of NO and $NO_2$. Here, a ratio of $NO_2/NO_X$ above 50% should be avoided, because the reaction with $NO_2$ only ($4NH_3+4NO+O_2{\rightarrow}4N_2+6H_2O$) is slower than the standard SCR reaction ($4NH_3+4NO+O_2{\rightarrow}4N_2+6H_2O$). In order to accurately predict the performance characteristics of SCR catalysts, it is therefore desired to develop a more simple and reliable mathematical and kinetic models on the oxidation kinetics of nitric oxide over a DOC. In the present work, the prediction accuracy and limit of three different chemical reaction kinetics models are presented to describe the chemicophysical characteristics and conversion performance of DOCs. Steady-state experiments with DOCs mounted on a light-duty four-cylinder 2.0-L turbocharged diesel engine then are performed, using an engine-dynamometer system to calibrate the kinetic parameters such as activation energies and preexponential factors of heterogeneous reactions. The reaction kinetics for NO oxidation over Pt-based catalysts is determined in conjunction with a transient one-dimensional (1D) heterogeneous plug flow reactor (PFR) model with diesel exhaust gas temperatures in the range of 115~$525^{\circ}C$ and space velocities in the range of $(0.4{\sim}6.5){\times}10^5\;h^{-1}$.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.4
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• pp.110-119
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• 2008

Computer methods with simplified mathematical models in conjunction with empirical model parameters can be efficiently practiced into an optimization of a diesel aftertreatment system. Components of prime interests are diesel particulate filter, diesel oxidation catalyst and de-$NO_x$ catalytic converter. de-$NO_x$, de-PM, and de-HC processes in each part are individually modeled, formulated and then combined into an integrated analysis procedure for a unified simulation of the diesel emission aftertreatment. The model is empirically tuned and validated with comprehensive engine and laboratory data. The effects of emission species and space velocity on the $NO_x$ and soot reductions are parametrically investigated. A lowered $NO_2/NO_x$ ratio due to PM oxidation in DPF contributes to promote the $NO_x$ reduction by SCR at intermediate gas temperatures. $NO_x$ reduction is inert to the PM oxidation at high temperatures. Rate of PM trapping strongly depends on temperature and $NO_x$ concentration.

• Journal of Power System Engineering
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• v.17 no.5
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• pp.13-22
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• 2013

This paper reports the investigation of the physical and chemical characteristics of the prepared 3Pt-2MgO-$3ZrO_2$-$2CeO_2/Al_2O_3$ DOC, based on its hydrothermal aging. As a result of impregnating and reducing the $H_2PtCl_6$ $6H_2O$ precursor on a ${\gamma}-Al_2O_3$ basis, it was well dispersed into small particles with the range 2-3nm. This was because the $Al_2O_3$ acted as a barrier to prevent movement of the catalyst particles. For a hydrothermally aged catalyst for 9h at $700^{\circ}C$, its performance when purifying harmful gases decreased compared to a fresh catalyst, but its specific surface area was at the same level. This was because the performance of the catalyst was reduced by the sintering of the precious metal Pt, rather than by washcoat sintering and pore clogging. For an excessively hydrothermally aged catalyst for 9h at $850^{\circ}C$, Pt grew into an approximately 50nm class, formed a cluster compared to a fresh catalyst. The $CeO_2$ promoters also formed clusters among components of the same type, reducing their specific surface area to $114m^2/g$, which was 14% less than a fresh catalyst.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.5
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• pp.443-454
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• 1998

Pt-V catalytic converter was installed on a heavy duty diesel engine and the characteristics of the emission reduction were tested using a engine dynamometer at various operating conditions. The emission reduction performance of Pt-V catalyst was also compared with that of a commercialized Pt catalyst currently being used in some of the heavy duty diesel engines in advanced countries. The effects of Pt-V and Pt catalysts on regulated and unregulated emissions were investigated using a 0.05 weight percent sulfur content fuel with an engine dynamometer Experiments for gaseous emissions (CO, HC and aldehyde) as well as particulate emissions (TPM, SOF and sulfate) have been conducted at several operating conditions such as T-7 mode, D-13 mode and S-13 mode before and after installing the Pt-V and Pt catalysts in the exhaust system. The emission reduction performance of Pt catalyst with respect to CO, HC, SOF, PAHs and aldehyde was found to be a little higher than that of Pt-V catalyst, but the Pt catalyst showed innate disadvantage of causing an increase of PM due to the sulfate formation via high SO2 conversion at high exhaust temperature, especially above 45$0^{\circ}C$.

• Journal of Powder Materials
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• v.18 no.6
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• pp.517-525
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• 2011

In this study, the used DOCs, which could remove the air pollutants such as CO and HC in the exhaust gas from diesel vehicle, were remanufactured by various conditions. Their catalytic performances and characterization were also investigated. The remanufacturing process of the deactivated DOCs includes high temperature cleaning of incineration, ultrasonic cleaning for washing with acid/base solutions to remove deactivating materials deposited to the surface of the catalysts, and active component reimpregnation for reactivating catalytic activity of them. The catalytic performance tests of the remanufactured DOCs were carried out by the diesel engine dynamo systems and chassi dynamo systems in CVS-75 mode. All prepared catalysts were characterized by the optical microscopes, SEM, EDX, porosimeter and BET to investigate correlations between catalytic reactivity and surface characteristics of them. The remanufactured DOCs at various conditions showed the improved catalytic performances reaching to 90% of fresh DOC, which is attributed to remove the deactivating materials from the surface of the used DOC through the analysis of catalytic performance test and their characterization.

• Transactions of the Korean Society of Automotive Engineers
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• v.19 no.5
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• pp.76-81
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• 2011

Exhaust gas recirculation is the well-known and widely used NOx reduction technology for diesel engines. More effective EGR cooler has been developed and applied to diesel engines to meet the reinforced emission regulation. However, the contaminated EGR cooler by diesel exhaust gas reduces the performance of the engine and NOx reduction rate. The buildup of deposits in EGR coolers cause significant degradation in heat transfer performance, often on the order of 20~30%. Deposits also increase pressure drop across coolers and thus may degrade engine efficiency under some operation conditions. In this study, as a solution for this problem, DOC assisted EGR cooler is designed and then investigated to reduce fouling and its impact on cooler performance. A single channel EGR cooler fouling test apparatus and soot particle generator were developed to represent the real EGR cooler and exhaust gas of diesel engine. EGR cooler effectiveness of the case with catalyst of pt 30g/ft3 decreased just up to 5%. This value was 45% less compared to the case without catalyst which decreased up to 9% after 10hours experiments.

• Clean Technology
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• v.25 no.2
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• pp.153-160
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• 2019

As air pollution becomes more serious due to the increased number of diesel vessel operations, ship regulations on harmful emissions strengthen. Therefore, the development of a diesel exhaust after-treatment system for ships is required, and the higher the flow uniformity of the exhaust treatment system, the higher the treatment efficiency. With the computer software ANSYS Fluent, pressure drop and flow uniformity were used in this study to simulate flow rate with and without a baffle in both a Diesel Oxidation Catalyst (DOC) and Diesel Particulate Filter (DPF) system. The system pressure drop was found to be 38 to 40 mbar in the existing system condition, and the flow uniformity was approximately 84 to 92% at the inlet and outlet of the DOC. When the baffle was installed inside the system, the pressure increased and the flow uniformity was lowered due to an increase in flow rate. When the exhaust gas flow was reduced by 50% from $7,548kg\;h^{-1}$ to $3,772kg\;h^{-1}$, the flow uniformity at the inlet and outlet of the DOC increased by approximately 1 to 3% due to the low flow rate. In the case of DPF, the flow uniformity of exhaust gas was 98 to 99% because the uneven flow proceeded after uniformly flowing from the DOC.

• Journal of Korean Society for Atmospheric Environment
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• v.28 no.2
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• pp.203-210
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• 2012

The purpose of this study is to evaluate the diesel retrofit program which have been proceeded for the last 7 years in Gyeonggi-do. Diesel retrofit programs in Gyeonggi-do consist of the attachment of DPF (Diesel Particulate Filter), p-DPF (partial-DPF) and DOC (Diesel Oxidation Catalyst), switching to LPG engine, scraping an old cars. Emission reduction by diesel retrofit program was estimated $N_2O$ 8,313.4 ton/year, PM10 3,626.4 ton/year, VOC 8,078.5 ton/year in 2010. The benefit-cost analysis shows that the 964 billion wons of benefits are greater than the 853 billion wons of total costs. Diesel retrofit programs could be one of the most effective measures to improve PM10 concentration in metropolitan area. But retrofit programs also need to be properly maintained by each vehicle.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.8
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• pp.4723-4728
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• 2014

In this study, a thermoelectric module (TEM) and a diesel engine were modeled using 1-D commercial software AMESim, and the performance of the TEM was evaluated when the engine was operated under the NEDC driving cycle. The goal of TEM modeling was to investigate not only the waste heat recovery (WHR) rate and energy converting efficiency, but also the heat transfer rate by taking the materials characteristics into account. In addition, a diesel oxidation catalyst (DOC) was designed, and it was found that the waste heat recovery with TEM affects the activation of DOC and alters engine exhaust composition. The simulation indicated that the WHR using TEM is beneficial for decreasing the fuel consumption of vehicles, but the reduction in the exhaust temperature affects the activation of DOC, resulting in an approximately 14% increase in CO and HC emissions. Therefore, the effect of waste heat recovery on the automotive emission characteristics must be considered in the development of automotive engine WHR systems.