• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2003.04a
• /
• pp.43-46
• /
• 2003

We consider influences of the aperture variation and the ambient groundwater flow on the migration of DNAPL within a fracture network. In context of a modified invasion percolation (MIP) growth algorithm, we formulate a mechanistic model that includes capillary and gravity forces as well as viscous forces within the DNAPL and the ambient groundwater. The MIP model is verified against laboratory experiments, which is conducted using a two-dimensional random fracture network model. The results show that the aperture variation and ambient groundwater flow can be significant factors controlling DNAPL migration path within fracture networks.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2003.09a
• /
• pp.543-547
• /
• 2003

We applied the modified invasion percolation (MIP) model to the migration of DNAPL within a two-dimensional random fracture network. The MIP model was verified against laboratory experiments, which was conducted using a two-dimensional random fracture network model. The results showed that the MIP needs modification. To remove TCE trapped in a random fracture network, the density-surfactant-motivated removal method was applied and found very effective to remove TCE from dead-end fractures.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2005.04a
• /
• pp.68-71
• /
• 2005

We conducted simple experiments to consider the influence of nonlinear groundwater flow on Trichloroethylene (TCE) as Dense Non-Aqueous Phase Liquid (DNAPL) migration in a rough walled single fracture. A glass replica of a granite sample containing a rough single fracture was made and experiments were conducted over a range of Re. Observations are compared to the results of TCE migration tests that were conducted in two parallel glass plates over the same range of Re. Results show nonlinear groundwater flow in a single fracture affect TCE migration path and residual saturation of TCE.

• Proceedings of the KSEEG Conference
• /
• 2004.12a
• /
• pp.48-51
• /
• 2004

• Journal of Soil and Groundwater Environment
• /
• v.18 no.2
• /
• pp.27-35
• /
• 2013

In this study, three dimensional and two dimensional laboratory experiments were conducted to investigate the effect of water table rising on DNAPL migration, contaminants mass discharge ($M_d$), and residual NAPL distribution. The accumulation of TCE in unsaturated zone was observed in both two and three dimensional experiments. This implies DNAPL sources could exist in unsaturated zone at contaminated sites. It has been investigated that the TCE concentration is proportional to the areal ratio of residual TCE. This means the residual TCE obviously could affect the TCE concentration in aquifer system. The results of the two-dimensional experiment indicated that the contaminant sources in unsaturated zone could lead the $M_d$ increasing with water table rising and the source zone heterogeneity could also highly affect the $M_d$.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2003.09a
• /
• pp.479-482
• /
• 2003

In this study, the solubilization of dense nonaqueous phase liquid (DNAPL) using oil-based emulsion was investigated for aquifer remediation. The micro-sized oil emulsion has large surface areas and buoyancy force, therefore it can be effective in treating DNAPL pool of the aquifer without downward migration of DNAPLs. The emulsion was prepared using silicone oil and mechanical homogenization. And the prepared emulsion had micro-sized similar distribution: 99 % in number and 80 % in volume were less than 10${\mu}{\textrm}{m}$. As target pollutants, trichloroethylene and 1, 2 dichlorobenzene were selected. All of used DNAPLs were solubilized successfully in oil-based emulsion. Even at low oil percentage, emulsion showed good solubility against pollutants. Therefore, the remediation using oil-based emulsion was considered as an effective alternative in dealing with DNAPLs of the aquifer.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2002.09a
• /
• pp.32-35
• /
• 2002

In order to characterize the migration of DNAPL in rock fractures, the dynamic macromodified invasion percolation (DMMIP) model, that is able to reflect the viscous force of groundwater in a fracture network, is suggested. DMMIP simulations are verified against the laboratory expenments, which shows a good qualitative and quantitative agreement.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2005.09a
• /
• pp.515-516
• /
• 2005

• Journal of Soil and Groundwater Environment
• /
• v.27 no.spc
• /
• pp.75-91
• /
• 2022

Differences in subsurface migration of LNAPL/DNAPL contaminants caused by a selection of 3-phase (aqueous, NAPL, and gas) relative permeability function (RPF) models in numerical modeling were investigated. Several types of RPF models developed from both experimental and theoretical backgrounds were introduced prior to conducting numerical modeling. Among the RPF models, two representative models (Stone I and Parker model) were employed to simulate subsurface LNAPLs/DNAPLs migration through numerical calculation. For each model, the spatiotemporal distribution of individual phases and the mole fractions of 6 NAPL components (4 LNAPL and 2 DNAPL components) were calculated through a multi-phase and multi-component numerical simulator. The simulation results indicated that both spilled LNAPLs and DNAPLs in the unsaturated zone migrated faster and reached the groundwater table sooner for Stone I model than Parker model while LNAPLs migrated faster on the groundwater table under Parker model. This results signified the crucial effect of 3-phase relative permeability on the prediction of NAPL contamination and suggested that RPF models should be carefully selected based on adequate verification processes for proper implementation of numerical models.

• Journal of Soil and Groundwater Environment
• /
• v.27 no.spc
• /
• pp.64-74
• /
• 2022

The conceptual site model (CSM) is used as a key tool to support decision making in risk based management of contaminated sites. In this work, CSM was applied in Jeonju Industrial Complex where site investigation for groundwater contamination was conducted. Site background information including facility types, physical conditions, contaminants spill history, receptor exposure, and ecological information were collected and cross-checked with tabulated checklist necessary for CSM application. The CSM for contaminants migration utilized DNAPL transport model and narrative CSMs were constructed for source to receptor pathway, ecological exposure route, and contaminants fate and transport in the form of a diagram or flowchart. The component and uncertainty of preliminary CSM were reviewed using the data gap analysis while taking into account the purpose of the survey and the site management stage at the time of the survey. Through this approach, the potential utility of CSM was demonstrated in the site management process, such as assessing site conditions and planning follow-up survey work.