• Journal of Welding and Joining
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• v.24 no.6
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• pp.33-38
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• 2006

Since the 1990's, European shipbuilding industries introduced hybrid welding process in order to decrease thermal distortion of welded joints in passenger shipbuilding. In this study, we investigated effects of hybrid welding parameters on the toughness of weld metal using DH36 steel in order to obtain more sound welds in passenger shipbuilding. Type of leading process, joint gap distance and chemical composition of consumables were considerably correlated with the toughness of weld metal. Especially, the toughness was considerably increased with high-Ti containing consumables. In addition, hybrid welding speed increased by using plasma cut edges, the oxides layer of which increased absorption efficiency of laser beam.

• Journal of Welding and Joining
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• v.21 no.3
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• pp.30-34
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• 2003

This paper describes the heat distribution characteristics of ASTM A131DH36 high tensile steel for ship structures in 5㎾ $CO_2$ laser welding. In general, high energy of laser beam concentrates on the small area of the weldment instantaneously; therefore, this heat transfer mechanism induces the rapid changes of temperature and mechanical characteristics in laser welds this mechanism. So temperature distribution analysis is important to understand mechanical characteristics of laser welds. Authors have conducted finite element simulation to analyze the heat distribution characteristics in laser welds. The result of simulation has been verified by comparing with the metallurgical experiment result. From the result of this study, we can accurately predict the heat distribution characteristics in laser welds by using numerical simulation.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.333-333
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• 2011

We studied the H/D exchange kinetics of pure and acid dopped water-ice film by using the techniques of reactive ions scattering (RIS) and low energy sputtering (LES) with low kinetic energy cesium ion beam (<35 eV). From RIS, neutral water isotopomers were detected in the form of cesium-molecule ion clusters, $CsX^+$ (X= $H_2O$, HDO, $D_2O$). Ionic species, like $H_3O^+$, $DH_2O^+$, $D_2HO^+$, $D_3O^+$, adsorbed on the surface were ejected via LES process. Those techniques allowed us to trace the isotopomeric populations of water-ice film. To show the catalytic effect of excess proton in the H/D exchange reaction, our study was conducted with two types of water-ice films. In film 1, about 0.5 BL of $H_2O$ was adsorbed on HCl (0.1 ML) dopped $D_2O$ (8 BL) film. In film 2, similar amount of $H_2O$ used in film 1 was adsorbed on pure $D_2O$ film. Kinetic data were obtained from each film type for 90-110 K (film 1) and 110-130 K (film 2) and fitted with numerically integrated lines. Through the Arrhenius plot of kinetic coefficient deduced from fitting of the H/D exchange reaction, the activation energy of film 1 and 2 were estimated to be $10{\pm}3kJmol^{-1}$ and $17{\pm}4kJmol^{-1}$. This activation barrier difference could be understood from detailed pictures of H/D exchange. In film 2, both the formation of ion pair, $H_3O^+$ and OH. and proton transfer were needed for the H/D exchange. However, in film 1, only proton transfer was necessary but ion pair formation was not, so this might reduce the activation energy.