• 제목/요약/키워드: DEGRADATION

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고온 등온환경하의 탄소섬유/에폭시 단일방향 복합재료의 열화 예측모델 개발 (Study on Thermal Degradation Behavior of Unidirectional Carbon Fiber/Epoxy Composite Due to Isothermal Environment)

  • 정기모;최흥섭;김창호;한중원;남재도
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2002년도 추계학술발표대회 논문집
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    • pp.43-47
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    • 2002
  • Weight loss experiments have been performed for unidirectional carbon fiber/epoxy laminates under both isothermal and cyclic thermal conditions. It was found that weight losses were the result of both specimen-geometry dependent oxidative degradation and volumetric geometry dependent thermal degradation. Thermal degradation was found to play a major role in the overall weight loss process, and photomicrographs of cross-sectioned, aged specimens confirmed this fact. A method to predict the effect of isothermal environment on the weight loss was introduced and found to be in good agreement with experimental data at temperatures near Tg (glass transition temperature).

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모델식품계에서 무산소 가열시 토코페롤의 열분해 패턴 (Thermal Degradation Pattern of Tocopherols on Heating without Oxygen in a Model Food System)

  • 정혜영
    • 한국식품영양학회지
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    • 제11권6호
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    • pp.635-639
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    • 1998
  • The thermal degradation pattern of $\alpha$-, ${\gamma}$-and $\delta$-tocopherols in glycerol was investigated during heating at 100~25$0^{\circ}C$ for 5-60 min in the absence of oxyge. The tocopherols and thermally decomposed products were separated by HPLC with a reversed phase $\mu$-Bondapak C18-column. The degradation pattern of $\alpha$-tocopherol during the heating in the absence of oxygen was different from those of ${\gamma}$-and $\delta$-tocopherols. But the degradation patterns of ${\gamma}$-and $\delta$-tocopherols were similar to each other. The residual content of $\alpha$-tocopherol during the heating in the absence of oxygen decreased to the range 12~65% and those of ${\gamma}$-and $\delta$-tocopherols decreased to the range 4~96%. The thermal degradation of tocopherols in the absence of oxygen was less than that in the presence of oxygen.

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Fundamental Study on the Photocatalytic Degradation of Organics in Industrial Waste Water with the Presence of Titanium Dioxide

  • Kusaka, Eishi;Izawa, Mihiro;Fukunaka, Yasuhiro;Ishii, Ryuji
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.286-291
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    • 2001
  • As part of fundamental studies on the degradation of the organic compounds in industrial waste water, the photocatalytic degradation properties of the organic compound by means of the UV/TiO$_2$degradation process have been investigated. The test organic compound of acetic acid was chosen in this study. The testing of photo catalytic degradation were performed under various operation conditions such as TiO$_2$dosages, initial concentration of the organic, the aqueous pH's, etc. The effects of various parameters on the short time activity of the present acetic acid-UV/TiO$_2$system could be demonstrated from this investigation.

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LED 칩 열화특성에 적합한 열화모델 기반의 수명예측 시스템 구현

  • 유기훈;이재훈;김달석;이무석;윤양기;한지훈;장중순
    • 한국신뢰성학회:학술대회논문집
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    • 한국신뢰성학회 2011년도 춘계학술발표대회 논문집
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    • pp.79-85
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    • 2011
  • LED(Light Emitting Diode) is a powerful device used in applications as diverse as replacements for aviation lighting, automotive lighting as well as in traffic signals. This study is to propose a prediction system based on the degradation model of LED which is determined by combining scale and shape parameter. The degradation model is analysed goodness of fit test using calculated R-square, and is compared with previous models. A LED prediction system using degradation model is developed to automate estimations of degradation parameters and lifetimes.

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탈질촉매 내 열화특성과 유동상태에 관한 연구 (A Study on Degradation Characteristic and Flow Behavior in De-NOx Catalyst)

  • 황승민
    • 한국환경과학회지
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    • 제19권9호
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    • pp.1093-1101
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    • 2010
  • In this study, the indirect correlation of degradation characteristic and flow behavior in the de-NOx catalyst is investigated experimentally. The inner flow behavior in the de-NOx catalyst is varied from turbulent flow to laminar flow and the degradation of the de-NOx catalyst is remarkably affected by the inner flow. The degradation of the catalyst is increased in the upstream region near the inlet because injected turbulent flow enhances the adhesion of ash particle on the catalyst surface. The degradation of the catalyst near the inlet also governs the overall efficiency of the catalyst. The amount of adhered ash particles on the catalyst surface decreases as they progress downstream. This is due to the inner flow transition from turbulent flow to laminar flow.

철도차량 견인전동기의 가속열화수명평가 기술현황 (A technology State of Accelerating Degradation and Life Estimation on the Traction Motor for Railway Rolling Stock)

  • 왕종배;김기준;최영찬
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 제2회 학술대회 논문집 일렉트렛트 및 응용기술전문연구회
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    • pp.25-28
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    • 2000
  • In this paper, the technology for accelerating degradation & life estimation on the traction motor was introduced with the stator form-winding sample coils of the 200 Class insulation system The accelerative degradation was performed in 10 cycles, which were composed of thermal stress, fast rising surge voltage, vibration, water immersion and overvoltage applying. After aging of 10 cycles, condition diagnosis test such as insulation resistance & polarization index, capacitance & dielectric loss and partial discharge properties were investigated in the temperature range of $20{\sim}160^{\circ}C$. Relationship between degradation conditions and diagnosis results were analyzed to find an dominative degradation factor at the end-life point

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초음파를 이용한 재질열화의 비파괴적 평가 (Nondestructive Evaluation for Material Degradation of 2.25Cr-1Mo steel by Ultrasonic Wave)

  • 김정석;박은수;박인근;김현묵
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 2000년도 추계학술대회논문집 - 한국공작기계학회
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    • pp.369-374
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    • 2000
  • This study has been achieved on the characteristics of ultrasonic wave in 2.25Cr-1Mo steel to evaluate the feasibility of ultrasonic nondestructive technique on the assessment of aging degradation. The measured values were used find a relationship between the ultrasonic propagation properties and degradation such as coarsening of carbides and precipitates. The ultrasonic attenuation coefficient was mainly affected by the grain size of prior austenitic phase as well as degradation. In this results, degradation and grain size in 2.25Cr-1Mo steel was able to cope with the changes in ultrasonic wave properties by applying the nondestructive evaluation method

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가속열화시험에 의한 건축용 도료의 신뢰성 평가 (Reliability Assessment of Anticorrosive Paints with Accelerated Degradation Test)

  • 권영일;김승진
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제9권4호
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    • pp.291-302
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    • 2009
  • Accelerated and field degradation tests are performed for reliability assessment of an anticorrosive paint for steel structures. Test data were analyzed to obtain the degradation model and the life time distributions of the paint. A power law degradation model and lognormal performance distribution were used to predict the lifetime of the anticorrosive paint and the method of finding an acceleration factor is provided.

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Relationship between Barcol hardness and flexural modulus degradation of composite sheets subjected to flexural fatigue

  • Sakin, Raif
    • Steel and Composite Structures
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    • 제19권6호
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    • pp.1531-1548
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    • 2015
  • The aim of this study is to investigate the relationship between Barcol hardness (H) and flexural modulus (E) degradation of composite sheets subjected to flexural fatigue. The resin transfer molding (RTM) method was used to produce 3-mm-thick composite sheets with fiber volume fraction of 44%. The composite sheets were subjected to flexural fatigue tests and Barcol scale hardness measurements. After these tests, the stiffness and hardness degradations were investigated in the composite sheets that failed after around one million cycles (stage III). Flexural modulus degradation values were in the range of 0.41-0.42 with the corresponding measured hardness degradation values in the range of 0.25-0.32 for the all fatigued composite sheets. Thus, a 25% reduction in the initial hardness and a 41% reduction in the initial flexural modulus can be taken as the failure criteria. The results showed that a reasonably well-defined relationship between Barcol hardness and flexural modulus degradation in the distance range.

A Kinetic Study of Thermal Degradations of Chitosan/Polycaprolactam Blends

  • Liao, Shen-Kun;Hung, Chi-Chih;Lim, Ming-Fung
    • Macromolecular Research
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    • 제12권5호
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    • pp.466-473
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    • 2004
  • We have used FT-IR spectra to explain the effects of hydrogen bonding between chitosan and polycaprolactam (PA6). A dynamic mechanical analysis study suggested that the optimum chitosan and PA6 miscibility under the conditions of this experiment were obtained at a blending ratio of 40:60. We studied the thermal degradation of chitosan blended with PA6 (chitosan/PA6) by thermogravimetric analysis and kinetic analysis (by the Ozawa method). Dry chitosan and PA6 exhibited a single stage of thermal degradation and chitosan/PA6 blends having> 20 wt% PA6 exhibited at least two stages of degradation. In chitosan/PA6 blends, chitosan underwent the first stage of thermal degradation; the second stage proceeded at a temperature lower than that of PA6, because the decomposition product of chitosan accelerated the degradation of PA6. The activation energies of the blends were between 130 and 165 kJ/mol, which are also lower than that of PA6.