• 제목/요약/키워드: DDE

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천일염 중 유기염소계 잔류성 유기오염물질(POPs) 잔류분석 (Quantitative Analysis of Residual 24 Organochlorine POPs in Sundried Salts)

  • 최근형;박미란;박종민;홍수명;권오경;박연기;김진효
    • 농약과학회지
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    • 제15권4호
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    • pp.502-506
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    • 2011
  • 최근 국내외 환경규제를 강력히 받고 있는 잔류성 유기오염물질(POPs)의 농식품에 대한 잔류 허용기준은 설정되어 있으나, 천일염은 제조특성상 환경으로부터 이들 유해물질의 오염 가능성이 매우 높음에도 불구하고 지금까지 관련 조사 및 연구가 이루어지지 않았다. 따라서, 본 논문에서는 천일염에 잔류 가능한 24종의 유기염소계 POPs(${\alpha}$-HCH 1, ${\beta}$-HCH 2, ${\gamma}$-HCH 3, ${\delta}$-HCH 4, trans-chlrodane 5, 2,4'-DDE 6, ${\alpha}$-endosulfan 7, cis-chlordane 8, 2,4'-DDD 9, endrin 10, ${\beta}$-endosulfan 11, 2,4'-DDT 12, endosulfan sulfate 13, HCB 14, aldrin 15, trans-nonachlor 16, 4,4'-DDE 17, dieldrin 18, 4,4'-DDD 19, cis-nonachlor 20, 4,4'-DDT 21, heptachlor 22, heptachlor epoxide 23 and mirex 24)를 대상으로 GC-ECD(DB-5, $30m{\times}250{\mu}m{\times}0.25{\mu}m$)를 활용한 정량분석을 실시하였다. 24종 POPs 물질의 retention time은 19.18 min의 ${\alpha}$-HCH를 시작으로 34.69 min의 mirex 순서로 검출되었으며, 각각의 peak간 간격은 최소 0.05 min 이상인 것으로 확인되었다. 이들 POPs의 LOQ는 0.003 ~ 0.033 ng/g 범위에서 확인되었고, 0.1 ng/g 수준에서 측정한 회수율은 60.9% ~ 120.8%로 나타났다. 본 연구에서 분석한 모든 천일염 시료에서 이들 POPs 물질이 정량한계 이상 검출된 시료는 없었다.

일부 한국 성인 여성들의 혈중 내분비계 장애물질 농도 및 그 노출요인의 연구 (The Concentrations of Endocrine Disrupter (PCBs and DDE) in the Serumand Their Predictors of Exposure in Korean Women)

  • 민선영;정문호
    • 한국환경보건학회지
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    • 제27권2호
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    • pp.127-137
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    • 2001
  • Polychlorinated biphenyls(PCBs) are halogenated aromatic compounds with the empirical formula $C_{12}$ $H_{10-n}$C $l_{n}$(n=1~10), and are a mixture of possible 209 different chlorinated congeners. PCBs were widely used as dielectric fluids for capacitors and transformers, plasticizers, lubricant inks and paint addirives. Once released into the environment, PCBs persist for years because they are so resistant to degradation. In addition to their persistence in the environment, PCBs in ecological food chains undergo biomagnification because of their high degree of lipophilicity. In 1970s, the worldwide production of PCBs was ceased and the import of PCBs was prohibited since 1983 in Korea. In spite of these actions, many PCBs seems to be still in use. The environmental load of PCBs will continue to be recycled through air, land, water, and the biosphere for decades to come. This study was conducted to measure the concentrations of PCBs in the serum samples of 112 women by GC/MSD and GC/ECD. The main results of this study were as follows. 1. PCBs were detected in all samples. The mean $\pm$SD levels of PCBs in the serum were 3.613$\pm$0.759 ppb, and median were 3.828 ppb. 2. The correlation coefficients of the concentrations of 13 PCB congeners were from minimum, 0.7913 to maximum, 0.9985, and all was significant(p=0.0001). The correlation coefficient between the concentrations of PCBs and p,p'-DDE was 0.9641(p=0.0001). 3. There was a positive association between age and PCBs' concentrations (simple linear regression ; $R^2$=0.86, $\beta$=0.08023, p<0.001). 4. There was a positive association between total lipids in the serum and PCBs' concentrations (simple linear regression ; $R^2$=0.7058, $\beta$=0.00486, p<0.001). 5. For possible predictors of PCBs and p,p' -DDE levels in the serum, age adjusted model (Y=$\beta$$_{0}$+$\beta$$_1$age+ $B_2$X) was applied. For BMI, major residential area, wether to eat caught fish by angling, where to eat caught fish by angling(by parents in the past), fish consumption, meat consumption, meat consumption, and dairy consumption, there was no association. For total conception frequency and lactation frequency and lactation period, there was negative association.ion.

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붕어 및 황소개구리 체내의 유기염소계 농약류의 분석 및 분포 특성

  • 이선화;송희영;김영복;정기호
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2004년도 봄 학술발표회 발표논문집
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    • pp.101-102
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    • 2004
  • 유기염소계 농약류 14종을 분석한 결과 황소개구리의 경우 모든 시료에서 검출되지 않았다. 붕어의 경우 11종의 분석대상물질이 검출되지 않았고, heptachlor epoxide B, trans-nonachlor, p,p´-DDE가 각각 3개 지점, 7개 지점, 5개 지점에서 검출되었다.

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경북지역 인삼 중 유기염소계 농약의 다성분 분석 (Multi-analysis of the Organochlorine Pesticides in Ginseng at Gyeongbuk, Korea)

  • 박문기;김정호
    • 한국환경과학회지
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    • 제14권2호
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    • pp.193-199
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    • 2005
  • To obtain the residual organochlorine pesticides in the ginseng, the methods of multi-analysis for BHC's isomer, DDT's isomer and other organochlorine pesticides by GC-ECD are surveyed. The relative retention time for $\alpha-BHC,\;\beta-BHC,\;\delta-BHC\;and\;\gamma-BHC$ is 1.000, 1.025, 1.034 and 1.056, respectively. The relative retention time for o,p-DDE, p,p-DDE, o,o-DDD, o,p-DDT, o,p-DDD, and p,p-DDT is 1.199, 1.230, 1.242, 1.286, 1.329 and 1.333, respectively. The BHC isomers, DDT's isomer and other organochlorine pesticides are separated with multianalysis condition. The qualified defection concentration for $\alpha-BHC$, Quintozene, Aldrin, Captan, $\alpha-Endosulfan$, and Dieldrin is 0.95ng/g, 0.27ng/g, 1.04ng/g, 0.63ng/g, 0.55ng/g and 0.62ng/g, respectively. The qualified defection concentration for Fenhexamid, Endrin, $\beta-Endosulfan$, o,p-DDT, Endosulfan-sulfate is 5.71ng/g, 0.61ng/g, 0.48ng/g, 0.44ng/g and 0.51ng/g, respectively. BHC, Aldrin, Dieldrin, Endrin and DDT, which were Korea Food & Drug Administration advisory pesticides, are not detected in soil environment. Also it's residual organochlorine pesticides are not polluted in the ginseng on Sangju Korea.

진공증착중합법을 이용한 6FDA/4-4'DDE 폴리이미드 박막의 제조와 전기적 특성 (Electrical Properties and Preparation of 6FDA/4-4'DDE Polyimide Thin Films by Vapor Deposition Polymerization Method)

  • 황선양;이붕주;김형권;김영봉;박강식;임헌찬;강대하;박광현;이덕출
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 하계학술대회 논문집 D
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    • pp.1487-1489
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    • 1998
  • In this paper, thin films of PI were fabricated VDPM of dry processes which are easy to control the film's thickness and hard to pollute due to volatile solvents. From FT-lR, PAA thin films fabricated by VDP were changed to PI thin films by thermal curing. From SEM, AFM and Ellipsometer experimental, as the higher curing temperatures the films thickness decreases and reflectance increases. Therefore, Pl could be fabricated stable by increasing curing temperature. The relative permitivity and dissipation loss factor were 3.7 and 0.008. Also, the resistivity was about $1.05{\times}10^{15}{\Omega}cm$ at $30^{\circ}C$.

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Biodiversity of Microalgae and Their Elemental Components from Veeranam Lake, Tamilnadu, India

  • Sivakumar, K.;Senthilkumar, R.
    • 생태와환경
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    • 제41권2호
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    • pp.128-136
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    • 2008
  • An attempt was made in the Veeranam freshwater lake with the objectives to collect, identify, describe and document the algae occurring from March 2007 to August 2007. Qualitative and quantitative characterization of phytoplankton and analysis of physico-chemical parameters of water samples were carried out at monthly intervals during the study period in the western and eastern sides of the lake. It was found that the phytoplankton community embraced 68 genera belonging to four classes viz., Bacillariophyceae (40), Chlorophyceae (22), Cynophyceae (4) and Euglenophyceae (2). There were significant influences of various physico-chemical parameters on the phytoplankton population density. Commonly occurred genera, Oscillatoria (Cyanophyceae), Navicula (Bacillariophyceae) and Scenedesmus (Chlorophyceae), were subjected to energy dispersive spectroscopic analysis (EDS). They were found to accumulate different elements such as Zn, P, S, Ca, Mg, Fe, N, Si, Cl and Mn. Among these the member Cyanophyceae contained Zn, P, Mg, Ca, Mn, S and N. Bacillariophyceae Si, Zn, Mg, Cl, N, Fe, and Ca. Chlorophyceae Ca, Mg, N, Fe, Cl, Zn, Si and Mn. Thus these observations would determine the chemical dialogue between the cell structures and role of the elements. Further, it gives the clue about the phytoplankton growth requirements.

Application of GIS Technique for Fire Drill in Hillside Area

  • Chung Yeong-Jin
    • Spatial Information Research
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    • 제12권4호
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    • pp.321-328
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    • 2004
  • 본 연구는 PhotoModeler Pro를 이용하여 공간 정보를 자동적으로 추출하기 위한 기법에 관한 것이다. PhotoModeler Pro는 Windows시스템에서 개인용 컴퓨터 상에서 3차원 공간 정보를 취득할 수 있는 우수한 도구이나 스테레오 이미지를 자동적으로 병행하여 처리하는 데는 충분하지 않은 단점이 있다. 따라서 본 연구는 PhotoModeler Pro상에서 자동생성 프로그램과 DDE인터페이스를 이용한 스테레오 매칭 연구에 관한 것으로, 적용 지역은 사면과 계단이 많은 타테야마 지역(일본 나가사키 시)을 대상으로 하였다. 연구 대상 지역에 대한 자동 스테레오 매칭 결과 $100\%$의 적중률을 보였다.

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제주마의 혈액형에 관한 연구 I. 적혈구 항원형 (Genetic studies of blood markers in Cheju horses I. Red blood cell types)

  • 조길재;김택수;엄영호;김봉환;유재선
    • 대한수의학회지
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    • 제39권6호
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    • pp.1066-1072
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    • 1999
  • The present study was carried out to investigate the blood markers of Cheju horses. The red cell types (blood groups) were tested from 73 Cheju native horses and 118 Cheju racehorses by serological procedures with 23 reagents. The blood group phenotypes observed with high frequency were Pb(34.3%), Qc(56.2%), Qb(15.1%) and genotypes Dbcm/dghm(12.3%), Dde/dghm(9.6%), Dad/bcm(6.8%), Dcgm/de(6.8%) in Cheju native horses, while Aa(63.6%), Pa(44.9%), P-(28.8%), Qabc(36.4%), Dbcm/cgm(14.4%), Dbcm/bcm(10.2%), Dbcm/de(7.6%), Dbcm/dghm(5.1%), Dde/dk(5.1%) in Cheju racehorses. Alleles observed with high frequency were Ab(0.128), Ac(0.169), Dad(0.103), Dadn(0.075), Ddghm(0.226), Pb(0.316), Qc(0.494) in Cheju native horses and Aa(0.529), Dbcm(0.306), P-(0.531), Qabc(0.197), Q-(0.504) in Cheju racehorses. No specific variation of blood groups and allele frequencies of C,K,U system were observed in Cheju native horses and Cheju racehorses. The mean heterozygosity in Cheju native horses and Cheju racehorses was observed 0.5344 and 0.5102, respectively.

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$\textsc{k}$-ary n-큐브 상에서의 동적 부하 균등 알고리즘 (Dynamic Load Balancing Algorithm for $\textsc{k}$-ary n-cubes)

  • 박경욱;임형석
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 1998년도 추계종합학술대회 논문집
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    • pp.483-486
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    • 1998
  • In parallel system, the execution times of tasks cannot be accurately estimated and tasks may arrive at any time. In case, processors are overweighted with workload, the system utilization deteriorates. To solve this problem, dynamic load balancing that rearranges tasks in overloaded processors is required. We prospose the improved dynamic load balancing algorithm for $\textsc{k}-ary$ n-cubes using the property of ring and MWA which is the dynamic load balancing one for mesh. The proposed algorithm which uses the global load information has less communication cost than GDE, DDE and load difference within 1.

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STUDY OF BRÜCK CONJECTURE AND UNIQUENESS OF RATIONAL FUNCTION AND DIFFERENTIAL POLYNOMIAL OF A MEROMORPHIC FUNCTION

  • Pramanik, Dilip Chandra;Roy, Jayanta
    • Korean Journal of Mathematics
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    • 제30권2호
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    • pp.249-261
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    • 2022
  • Let f be a non-constant meromorphic function in the open complex plane ℂ. In this paper we prove under certain essential conditions that R(f) and P[f], rational function and differential polynomial of f respectively, share a small function of f and obtain a conclusion related to Brück conjecture. We give some examples in support to our result.