• Journal of the Korean Chemical Society
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• v.39 no.6
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• pp.446-452
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• 1995

Lithium intercalates, $Li_xFeMoO_4Cl$ ($1{\leq}X{\leq}2$) prepared by electrochemical lithiation of $FeMoO_4Cl$ crystallizes in monoclinic structure for all x values as revealed by x-ray diffraction and galvanostatic discharge experiments. According to the x-ray photoelectron spectroscopic study, Fe(III) is at first reduced to Fe(II) upon lithium intercalation with the x domain of $0{\leq}X{\leq}1$, where the crystal symmetry is changed from tetragonal to monoclinic. On the other hand, Mo(VI) is reduced to lower valent state upon further lithium intercalation ($1{\leq}X{\leq}2$), where no crystal symmetry transformation and reduction of Fe(II) to lower valent state are observed. The Mo 3d spectrum for $Li_2FeMoO_4Cl$ appears as a complex shape, but can be deconvoluted into the three sets of the doublet on the basis of Gaussian function, those which correspond to Mo(VI), Mo(V) and Mo(IV) states, respectively. The mixed valent states of molybdenum after further lithiation may be due to a competitive reaction between the formation of Mo(V) and its disproportionation to Mo(IV) and Mo(VI).

• Geophysics and Geophysical Exploration
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• v.13 no.4
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• pp.315-322
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• 2010

The phase-screen and the split-step Fourier migrations, which are implemented in both the frequency-wavenumber and frequency-space domains by using one-way scalar wave equation, allow imaging in laterally heterogeneous media with less computing time and efficiency. The generalized-screen migration employs the series expansion of the exponential, unlike the phase-screen and the split-step Fourier migrations which assume the vertical propagation in frequency-wavenumber domain. In addition, since the generalized-screen migration generalizes the series expansion of the vertical slowness, it can utilize higher-order terms of that series expansion. As a result, the generalized-screen migration has higher accuracy in computing the propagation with wide angles than the phase-screen and split-step Fourier migrations for media with large and rapid lateral velocity variations. In this study, we developed a 2D prestack generalized-screen migration module for imaging a complex subsurface efficiently, which includes various dips and large lateral variations. We compared the generalized-screen propagator with the phase-screen propagator for a constant perturbation model and the SEG/EAGE salt dome model. The generalized-screen propagator was more accurate than the phase-screen propagator in computing the propagation with wide angles. Furthermore, the more the higher-order terms were added for the generalized-screen propagator, the more the accuracy was increased. Finally, we compared the results of the generalizedscreen migration with those of the phase-screen migration for a model which included various dips and large lateral velocity variations and the synthetic data of the SEG/EAGE salt dome model. In the generalized-screen migration section, reflectors were positioned more accurately than in the phase-screen migration section.

• Journal of the Korean Magnetics Society
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• v.21 no.2
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• pp.77-82
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• 2011

The use of soft magnetic materials have been increasing in the various industrial fields according to the increasing demand for high performance, automatic, miniaturing equipments in the recent our life. In this study, we investigated the effect of factors on the core loss and magnetic properties of electrical steel and soft magnetic composites. Furthermore, we reviewed the major efforts to reduce the core loss and improve the soft magnetic properties in the two main soft magnetic materials. Domain purification which results from reduced density of defects in cleaner electrical steels is combined with large grains to reduce hysteresis loss. The reduced thickness and the high electrical conductivity reduce the eddy current component of loss. Furthermore, the coating applied to the surface of electrical steel and texture control lead to improve high permeability and low core loss. There is an increasing interest in soft magnetic composite materials because of the demand for miniaturization of cores for power electronic applications. The SMC materials have a broad range of potential applications due to the possibility of true 3-D electromagnetic design and higher frequency operation. Grain size, sintering temperature, and the degree of porosity need to be carefully controlled in order to optimize structure-sensitive properties such as maximum permeability and low coercive force. The insulating coating on the powder particles in SMCs eliminates particle-to-particle eddy current paths hence minimizing eddy current losses, but it reduces the permeability and to a small extent the saturation magnetization. The combination of new chemical composition with optimum powder manufacturing processes will be able to result in improving the magnetic properties in soft magnetic composite materials, too.

• Korean Journal of Childcare and Education
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• v.7 no.2
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• pp.43-60
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• 2011

The purpose of this study is to investigate the principals' and teachers' assessment about the assistance program for the evaluative accreditation of child care centers. Subjects were 138 teachers and principal who work in private(family) child care center in D and G city. An instrument to survey of this study was 'Assistance Program Evaluation Scale for the Evaluative Accreditation of Child Care Centers'(Nam, 2010) and 'Self-Assessment of Developmental Levels for Kindergarten Teacher'(Baek & Jo, 2004). Data were analyzed by paired t-test and ANOVA With SPSS 18.0 Version. The results of this study were as follows: First, there were significant differences in the both 'assistance system category' and 'assistance content category' between child care teacher group and principal group. Second, there were significant differences in the 'assistance content category' between the high group and the low group in expertise level. Third, significant differences were found to exist between a second-grade certificate level of child care teacher and a first-grade certificate level of child care teacher in terms of 'assistance domain'.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.32 no.6
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• pp.367-374
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• 2019

We investigate the effect of soil-structure interaction (SSI) on the response of LNG storage tanks to vertical seismic excitation depending on the type of foundation. An LNG storage tank with a diameter of 71 m on a clay layer with a thickness of 30 m upon bedrock, was selected as an example. The nonlinear behavior of the soil was considered in an equivalent linear method. Four types of foundation were considered, including shallow, piled raft, and pile foundations (surface and floating types). In addition, the effect of soil compaction within the group pile on the seismic response of the tank was investigated. KIESSI-3D, an analysis package in the frequency domain, was used to study the SSI and the stress in the outer tank was calculated. Based on an analysis of the numerical results, we arrived at three main conclusions: (1) for a shallow foundation, the vertical stress in the outer tank is less than the fixed base response due to the SSI effect; (2) for foundations supported by piles, the vertical stress can be greater than the fixed base stress due to the increase in the vertical impedance due to the piles and the decrease in radiation damping; and (3) soil compaction had a miniscule impact on the seismic response of the outer tank.

• Journal of Life Science
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• v.27 no.12
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• pp.1410-1414
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• 2017

Escherichia coli tryptophan synthase (TS) contains ${\alpha}_2{\beta}_2$, which catalyzes the final two steps in Trp biosynthesis. A molecular tunnel exists between the two active sites of ${\alpha}$ and ${\beta}$ subunits in TS. Via intersubunit communication, TS increases catalytic efficiency, including substrate channeling. The ${\beta}$ subunit of TS is composed of two domains, one of which, the COMM (communication) domain, plays an important role in intersubunit communication. The ${\alpha}$ subunit has a TIM barrel structure. This protein has functional regions at the C terminal of ${\beta}$ pleated sheets and in its loop regions. Three regions of the ${\alpha}$ subunit (${\alpha}L6$ [${\alpha}-loop$ L6], ${\alpha}L2$, and ${\alpha}L3$) are implicated in intersubunit communication. In the present study, conformational changes in ${\alpha}L6$ were monitored by measuring the sensitivity of mutant proteins in these regions to trypsin. The addition of a ${\alpha}$ subunit-specific ligand, D,L-${\alpha}$-glycerophosphate (GP), partially restored the sensitivity of mutant proteins to trypsin. In contrast, the addition of the ${\beta}$ subunit-specific ligand L-serine (Ser) resulted in varied sensitivity to trypsin, with an increase in PT53 (substitution of Pro with Thr at residue 53) and DG56, decrease in NS104 and wild type, and no change in GD51 and PH53. This finding may be related to several reaction intermediates formed under this condition. The addition of both GP and Ser led to a highly stable state of the complex. The present results are consistent with the current model. The method used herein may be useful for screening residues involved in intersubunit communication.

• Journal of Society of Occupational Therapy for the Aged and Dementia
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• v.12 no.2
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• pp.57-65
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• 2018

Objective : The purpose of this study was to compare the demographic characteristics, health and quality of life between general adults and adults living with dementia. Method : The data were collected using raw data of the 2016 community health survey and compared between 2,592 adults living with dementia patients and 225,840 general adults. health were assessed for sleep time, stress level, depression, and subjective health status, and quality of life was measured by EQ-5D. Result : In comparison of demographic characteristics, age and family number of adults living with dementia patients were significantly higher than general adults (p<.001), income and eduation levels were low (p<.001), and marital status was higher rate of living with spouse (p<.05). In comparison of health status, adults living with dementia patients were significantly longer in sleep time than the general adults (p<.001), and stress level was higher (p<.001), the percentage of experience of depression was higher (p<.001), and the subjective health status was worse (p<.001). Adults living with dementia patients were significantly lower in quality of life total score and all sub-domain than general adults (p<.001). Conclusion : Based on the results of this study, it is necessary to seek ways to improve the health and quality of life of dementia patients' families.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.32 no.3
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• pp.155-164
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• 2019

In this study, the soil-structure interaction(SSI) effect on the seismic response of LNG storage tanks was investigated according to the type of foundation. For this purpose, a typical of LNG storage tank with a diameter of 71m, which is constructed on a 30m thick clay layer over bedrock was selected, and nonlinearity of the soil was taken into account by the equivalent linearization method. Four different types of foundations including shallow foundation, piled raft foundation, and pile foundations(surface and floating types) were considered. In addition, the effect of soil compaction in group piles on seismic response of the tank was investigated. The KIESSI-3D, which is a SSI analysis package in the frequency domain, was used for the SSI analysis. Stresses in the outer tank, and base shear and overturning moment in the inner tank were calculated. From the comparisons, the following conclusions could be made: (1) Conventional fixed base seismic responses of outer tank and inner tank can be much larger than those of considering the SSI effect; (2) The influence of SSI on the dynamic response of the inner tank and the outer tank depends on the foundation types; and (3) Change in the seismic response of the structure by soil compaction in the piled raft foundation is about 10% and its effect is not negligible in the seismic design of the structure.

• Geophysics and Geophysical Exploration
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• v.24 no.4
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• pp.180-193
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• 2021

The complex resistivity method is an exploration technique that can obtain various characteristic information of underground media by measuring resistivity and phase in the frequency domain, and its utilization has recently increased. In this paper, a three-dimensional inversion algorithm for the CR data was developed to increase the utilization of this method. The Poisson equation, which can be applied when the electromagnetic coupling effect is ignored, was applied to the modeling, and the inversion algorithm was developed by modifying the existing algorithm by adopting comlex variables. In order to increase the stability of the inversion, a technique was introduced to automatically adjust the Lagrangian multiplier according to the ratio of the error vector and the model update vector. Furthermore, to compensate for the loss of data due to noisy phase data, a two-step inversion method that conducts inversion iterations using only resistivity data in the beginning and both of resistivity and phase data in the second half was developed. As a result of the experiment for the synthetic data, stable inversion results were obtained, and the validity to real data was also confirmed by applying the developed 3D inversion algorithm to the analysis of field data acquired near a hydrothermal mine.

• Journal of Science Education
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• v.47 no.2
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• pp.211-224
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• 2023

The purpose of this study is to suggest how to investigate the reliability of the assessment, which consists of items generated by automatic item generation using empirical example data. To achieve this, we analyzed the illustrative assessment data by applying the multivariate generalizability theory, which can reflect the design of responding to different items for each student and multiple error sources in the assessment score. The result of the G-study showed that, in most designs, the student effect corresponding to the true score of the classical test theory was relatively large after residual effects. In addition, in the design where the content domain was fixed, the ranking of students did not change depending on the item types or items. Similarly, in the design where the item format was fixed, the difficulty showed little variation depending on the content domains. The result of the D-study indicated that the original assessment data achieved a sufficient level of reliability. It was also found that higher reliability than the original assessment data could be obtained by reducing the number of items in the content domains of operation, geometry, and probability and statistics, or by assigning higher weights to the domains of letters and formulas, and function. The efficient measurement conditions presented in this study are limited to the illustrative assessment data. However, the method applied in this study can be utilized to determine the reliability and to find efficient measurement conditions for the various assessment situations using automatic item generation based on measurement traits.