• Structural Engineering and Mechanics
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• v.66 no.2
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• pp.203-215
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• 2018

A large body of experiments have been conducted to date to evaluate the punching shear strength of flat slab-column connections, but it is noted that only a few of them have been considered for the development of the ACI Code provisions. The limited test results used for the development of the code provisions fall short of predicting accurately the punching shear strength of such connections. In an effort to address this shortfall and to gain an insight into the factors that control the punching shear strength of flat slab-column connections, we report a qualified database of 650 punching shear test results in this article. All slabs examined in this database were tested under gravity loading and do not contain shear reinforcement. In order to justify including any test result for evaluation punching shear database, we have developed an approved set of criteria. Carefully established set of criteria represent the actual characteristics of structures that include minimum compressive strength, effective depths of slab, flexural and compression reinforcement ratio and column size. The key parameters that significantly affect the punching shear strength of flat slab-column connections are then examined using ACI 318-14 expression. The results reported here have paramount significance on the range of applicability of the ACI Code provision and seem to indicate that the ACI provisions do not sufficiently capture many trends identified through regression of the principal parameters, and fall on the unsafe side for the prediction of the punching shear strength of flat slab-column connections.

• Electrical & Electronic Materials
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• v.7 no.4
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• pp.317-324
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• 1994

In this study, new preparation method of LiCoO$_{2}$ was applied to develop cathode active material for Li rechargeable cell, and followed by X-ray diffraction analysis, electrochemical properties and initial charge/discharge characteristics as function of current density. HC8A72- and CC9A24-LiCoO$_{2}$ were prepared by heating treatment of the mixture of LiOH H$_{2}$O/CoCO$_{3}$(1:1 mole ratio) and the mixture of Li$_{2}$CO$_{3}$/CoCO$_{3}$(1:2 mole ratio) at 850 and 900.deg. C, respectively. Two prepared LiCoO$_{2}$s were identified as same structure by X-ray diffraction analysis. a and c lattice constant were 2.816.angs. and 14.046.angs., respectively. The electrochemical potential of CFM-LiCoO$_{2}$(Cyprus Foote Mineral Co.'s product), HC8A72-LiCoO$_{2}$ and CC9A24 LiCoO$_{2}$ electrode were approximately between 3.32V and 3.42V vs. Li/Li reference electrode. Stable cycling behavior was obtained during the cyclic voltammetry of LiCoO$_{2}$ electrode. According as scan rate increases, cathodic capacity decreases, but redox coulombic efficiency was about 100% at potential range between 3.6V and 4.2V vs. Li/Li reference electrode. Cathodic capacity of HC8A72-LiCoO$_{2}$ was 32% higher than that of CFM-LiCoO$_{2}$ and that of CC9A24-LiCoO$_{2}$ was 47% lower than that of CFM-LiCoO$_{2}$ at 130th cycle in the condition of lmV/sec scan rate. Constant cur-rent charge/discharge characteristics of LiCoO$_{2}$/Li cell showed increasing Ah efficiency with initial charge/discharge cycle. Specific discharge capacities of CFM and HC8A72-LiCoO$_{2}$ cathode active materials were about 93mAh/g correspondent to 34% of theretical value, 110mAh/g correspondent to 40% of theretical value, respectively. In the view of reversibility, HC8A72-LiCoO$_{2}$ was also more excellent than CFM- and CC9A24-LiCoO$_{2}$.