• 공업화학
• /
• 제2권4호
• /
• pp.311-329
• /
• 1991

산화주석전극 위에 LB 법에 의해 단분자층상으로 흡착된 양친매성 Os 착체의 전기화학적 거동을 살펴보았다. 또한 단분자막형태로 흡착된 redox 종의 전극반응의 이론식을 가역, 비가역, 준가역파에 대하여 검토하였고, 이들막이 진공증착된 $SnO_2$ 전극 위로 전이될 때, 그 전극에서 흐른 전체 전하를 cyclic voltammogram 의 그림적분법에 의해 구하였다. 그리고 이들 단분자막을 이용한 전자이동 중개반응의 응용면도 $Fe^{2+}$, TEMPOL 등을 이용해 해석하였다. 이들 측정된 cyclic voltammogram을 이론식으로부터 유도하여 분자들간의 상호작용 parameter를 고려해서 simultation 하였다. 이들로부터 구해진 parameter 들은 측정된 cyclic voltammogram 과 거의 일치함을 확인할수 있었다. 마지막으로 LB 법을 이용한 최근의 연구동향 및 응용분야를 소개하였다.

• 전기화학회지
• /
• 제16권4호
• /
• pp.217-224
• /
• 2013

본 연구에서는 금 나노입자로 전착된 전극위에 3-MPA로 개질된 자가조립 단층 전극의 순환전위법의 특성을 조사하였다. 또한 전극 주변에서 전자와 이온의 이동현상을 해석하였다. 반무한 확산모델을 채택하여, 물질전달 지배계에 대하여 지배방정식과 경계조건을 유도하였다. 자가조립단층 전극에 대한 순환전위법의 수치해를 구하기 위하여, 양함수 유한차분법을 적용하여 MATLAB 프로그램을 작성하여 해를 구현하였다. 자가조립으로 개질된 전극에 대한 본 CV 용 프로그램은 3-MPA으로 개질된 금 나노입자 SAM 전극의 순환전위법 실험결과를 잘 설명하고 있음을 확인할 수 있었다.

• 분석과학
• /
• 제15권6호
• /
• pp.550-555
• /
• 2002

Cyclic voltammetry를 이용하여 boratabenzene의 산화반응을 연구하였다. (${\eta}^6$-1-Methylboratabenzene) (${\eta}^5$-pentamethylcyclopentadiennyl)iron 3을 모델분자로 하여 methanol 용매상에서 산화제 ($Hg(OAc)_2$, $HgSO_4$, $Cu(OH)_2$, $AgCF_3SO_3$, $FeCl_3$)와 반응시킴으로서 mechanism을 조사하였다. Boratabenzene 고리에 ortho proton이, boron에는 methyl기가 그르고 nucleophile로서 methanol이 존재할 때 반응은 비가역적으로 진행되었다. 중간 전이단계로 [3]을 거치는 것으로 추측되며, 우선적으로 6과 7이 생성되었고, 그 다음 6은 8로, 7은 9로 변환되어감을 알 수 있었다.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2009년도 하계학술대회 논문집
• /
• pp.486-486
• /
• 2009

In this paper, the current-voltage (I-V) curves, such as linear sweep voltammetry (LSV) and cyclic voltammetry (CV), were employed to evaluate the effect of electrolyte concentration on the electrochemical reaction trend. From the I-V curve, the electrochemical states of active, passive, transient and trans-passive could be characterized. And then, we investigated that how this chemical affect the process of voltage-induced material removal in electrochemical mechanical polishing (ECMP) of Copper. The scanning electron microscopy (SEM) and energy dispersive spectroscopy EDS) analyses were used to observe the surface profile. Finally, we monitored the oxidation and reduction process of the Cu surface by the repetition of anodic and cathodic potential from cyclic voltammetry (CV) method in acid- and alkali-based electrolyte. From these analyses, it was important to understand the electrochemical mechanisms of the ECMP technology.

• 한국전기전자재료학회논문지
• /
• 제18권6호
• /
• pp.560-570
• /
• 2005

In this paper, a microelectrode away DNA chip was fabricated on glass slide using photolithography technology. Several probe DNAs consisting of mercaptohexyl moiety at their 5' end were immobilized on the gold electrodes by DNA arrayer utilizing the affinity between gold and sulfu. Then target DNAs were hybridized and reacted with Hoechst 33258, which is a DNA minor groove binder and electrochemically active dye. Cyclic voltammetry in 5mA ferricyanide/ferrocyanide solution at 100 mV/s confirmed the immobilization of probe DNA on the gold electrodes. Linear sweep voltammetry or cyclic voltammetry showed a difference between target DNA and control DNA in the anodic peak current values. It was derived from Hoechst 33258 concentrated at the electrode surface through association with formed hybrid. It suggested that this DNA chip could recognize the sequence specific genes. It suggested that multichannel electrochemical DNA microarray is useful to develop a portable device for clinical gene diagnostic system.

• Corrosion Science and Technology
• /
• 제2권1호
• /
• pp.12-17
• /
• 2003

The effects of Cr content and film formation potential on electronic behaviors of the passive film on Fe-Cr alloys were investigated in borate buffer solution. Influence of pH on passive films of both Fe-Cr and Fe-Cr-Mo alloys was also investigated. Mott-Schottky and cyclic voltammetry techniques were used to elucidate electronic behaviors of passive films and their electrochemical characteristics. AES analysis of passive films was carried out. Results showed that doping density decreased as Cr content and film formation potentials increased. The addition of Mo to Fe-Cr alloy had little influence on donor densities in pH 9.2 solution but some effects on the decrease in donor densities in pH 1.6 acidic solution.

• Journal of Electrochemical Science and Technology
• /
• 제11권1호
• /
• pp.41-49
• /
• 2020

In this study poly(carbazole) films deposited on stainless steel have been investigated as electrode material for supercapacitor applications. Poly(carbazole) films were electrodeposited using cyclic voltammetry in presence of lithium, sodium and tetrabutylammonium perchlorate salts. Poly(carbazole) films doped with perchlorate anions having different counter cations were characterized by SEM, ATR-FTIR and solid state conductivity measurements. Capacitive behaviours of PCz coated steel electrodes were tested by cyclic voltammetry, charge-discharge analysis and electrochemical impedance spectroscopy. It was found that counter cation of the dopant is significantly effective on the capacitive performance on the obtained PCz films and the PCz film synthesized from lithium perchlorate has the better capacitive performance than the poly(carbazole)s synthesized from sodium perchlorate and tetrabutylammonium perchlorate salts.

• 한국응용과학기술학회지
• /
• 제30권1호
• /
• pp.139-145
• /
• 2013

The electrochemical analysis of silver ion was performed using cyclic voltammetry (CV) and square-wave (SW) stripping voltammetry, and electrode cell systems were fabricated with graphite pencil electrode (GE) of working, reference and counter electrodes. Also electrolyte was the use of sea water as electrolyte solutions instead of ionic controlled solutions. The optimum analytical conditions for the cyclic and stripping parameters were determined using GE. The results approached the microgram working ranges of SW(ug/L) and CV(ug/L) Ag, and the optimum conditions were applied to frog's tissue and the food samples.

• 대한전기학회논문지:전기물성ㆍ응용부문C
• /
• 제55권3호
• /
• pp.107-110
• /
• 2006

We fabricated the monolayers onto QCM by self-assembly using viologen, which has been widely used as electron acceptor. A gold electrode of the QCM was cleaned by piranha solution and prepared the ethanol-acetonitrile(1:1) solution with 2 m mol/l viololgen compounding of pure hi gas. We determined the time dependence to resonant frequency shift during self-assembly process and the electrochemical behavior of the self-assembled viologen monolayers by cyclic voltammetry. With increasing scan rate, the redox peak current of the viologen increased linearly. This was signified that the redox reaction was reversible. The EQCM measurements revealed the anions transfer during redox reactions, respectively. From the EQCM data, the well-defined shape peaks were nearly equal charges by cyclic voltammetry.

• 한국환경과학회:학술대회논문집
• /
• 한국환경과학회 2001년도 정기총회 및 봄 학술발표회 초록집
• /
• pp.193-194
• /
• 2001

To determine for the hybridization, we have investigated by UV spectroscopic method. This complex behavior as nonelectrolytes in polar aprotic solution with molar conductivities. The technoques of pulse and cyclic voltammetry have been applied to the determination of $(E_{1/2})_{2}$-$(E_{1/2})_{1}$ for two-step electrochemical charge transfers. A simple amplitude has been derived for the dependence of the differential-pulse response on $(E_{1/2})_{1}$ and $(E_{1/2})_{2}$. The use of the peak-to-peak separation in cyclic voltammetry has also been evaluated. Comparison with a differential pulse and cyclic voltammetry methods shows agreement of comproportionation constant$(K_{c})$ within 50%.