• Title/Summary/Keyword: Cyclic Rate

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Effect of Temperature on Electrochemical Characteristics of Stainless Steel in Green Death Solution Using Cyclic Potentiodynamic Polarization Test (순환동전위 분극실험을 이용한 스테인리스강의 그린데스용액에서 전기화학적 특성에 미치는 온도의 영향)

  • Hwang, Hyun-Kyu;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.20 no.5
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    • pp.266-280
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    • 2021
  • Since 2020, the International Maritime Organization (IMO) has updated regulations on the sulfur content to be less than 0.5% in exhaust gas emitted from ships. Accordingly, the exhaust gas post-treatment device for ships, which is SOx/NOx reduction technology, was introduced. However, the exhaust gas post-treatment device is suffering corrosion because of the harsh corrosive environment formed by sulfate and chlorine oxide through the desulfurization process. In this investigation, cyclic potentiodynamic polarization (CPDP) experiment for UNS S31603 and UNS N08367 was performed in a green death solution that simulates the environment of a desulfurization device. The corrosion rate of UNS S31603 at the highest temperature was about 3 times higher than that of UNS N83067. Also, electron microscope scan revealed corrosion type UNS N83067 presents intergranular corrosion tendency. On the other hand, UNS S31603 was observed as general corrosion. The α values of UNS N08367 at 30 ℃ and 60 ℃ were higher than those of UNS S31603, thus UNS N08367 is considered to have a higher local damage tendency. Whereas, since the α value of UNS S31603 at 90 ℃ is larger than that of UNS N08367, UNS S31603 is considered to have a higher local damage trend.

Cyclic Shift Based Tone Reservation PAPR Reduction Scheme with Embedding Side Information for FBMC-OQAM Systems

  • Shi, Yongpeng;Xia, Yujie;Gao, Ya;Cui, Jianhua
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.15 no.8
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    • pp.2879-2899
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    • 2021
  • The tone reservation (TR) scheme is an attractive method to reduce peak-to-average power ratio (PAPR) in the filter bank multicarrier with offset quadrature amplitude modulation (FBMC-OQAM) systems. However, the high PAPR of FBMC signal will severely degrades system performance. To address this issue, a cyclic shift based TR (CS-TR) scheme with embedding side information (SI) is proposed to reduce the PAPR of FBMC signals. At the transmitter, four candidate signals are first generated based on cyclic shift of the output of inverse discrete Fourier transform (IDFT), and the SI of the selected signal with minimum peak power among the four candidate signals is embedded in sparse symbols with quadrature phase-shift keying constellation. Then, the TR weighted by optimal scaling factor is employed to further reduce PAPR of the selected signal. At the receiver, a reliable SI detector is presented by determining the phase rotation of SI embedding symbols, and the transmitted data blocks can be correctly demodulated according to the detected SI. Simulation results show that the proposed scheme significantly outperforms the existing TR schemes in both PAPR reduction and bit error rate (BER) performances. In addition, the proposed scheme with detected SI can achieve the same BER performance compared to the one with perfect SI.

Effects of Cyclic Nucleotides and Glipizide on the Cardiovascular Response of Baclofen in the Rats (흰쥐의 척수에서 Cyclic Nucleotides 및 Glipizide가 Baclofen의 심혈관반응에 미치는 영향)

  • Koh, Hyun-Chul;Ha, Ji-Hee;Shin, In-Chul
    • The Korean Journal of Physiology and Pharmacology
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    • v.1 no.6
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    • pp.647-655
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    • 1997
  • The purpose of present study is to investigate the influence of a spinal gamma-aminobutyric acid B($GABA_B$) receptor on a central regulation of blood pressure(BP) and heart rate(HR), and to define its mechanism in the spinal cord. In urethane-anesthetized, d-tubocurarine-paralyzed and artificially ventilated male Sprague-Dawley rats, intrathecal administration of drugs were carried out using injection cannula(33-gauge stainless steel) through the guide cannula(PE 10) which was inserted intrathecally at lower thoracic level through the puncture of a atlantooccipital membrane. Intrathecal injection of an $GABA_B$ receptor agonist, baclofen(30, 60, 100 nmol) decreased both BP and HR dose-dependently. Pretreatment with 8-bromo-cAMP(50 nmol), a cAMP analog, or glipizide(50 nmol), a ATP-sensitive $K^+$ channel blocker, attenuated the depressor and bradycardic effects of baclofen(100 nmol), but not with 8-bromo-cGMP(50 nmol), a cGMP analog. These results suggest that the $GABA_B$ receptor in the spinal cord plays an inhibitory role in central cardiovascular regulation and that this depressor and bradycardic actions are mediated by the decrease of cAMP via the inhibition of adenylate cyclase and the opening of $K^+$ channel.

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A Electron-Transfer Study on Self-Assembled Viologen Monolayer In different Electrolytes Using Electrochemical Process (전기화학법을 이용한 전해질 변화에 따른 Viologen 자기조립박막의 전하이동 특성 연구)

  • Lee, Dong-Yun;Park, Sang-Hyun;Shin, Hoon-Kyu;Park, Jae-Chul;Chang, Jeong-Soo;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.878-881
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    • 2004
  • When it converted solar energy or light energy into chemical energy, it studied the electric charge transfer property of the viologen which is used widely as the electron acceptor for the electric charge delivery mediation of the devices. It was formed monolayer in QCM by self-assembled viologen. The absorbed quantities of viologen's electron through peak current and to analyze the electron transfer property of viologen in redox reaction made experiments in cyclic voltammetry among the electrochemical process. It studied the electron transfer relation of viologen from changing the anion in 0.1M NaCl and $NaClO_4$ electrolyte and the interrelation between scan rate and peak current when scan rate increased twice.

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The Reliability and Comparison of ICR Network Based on SCI (SCI에 근거한 ICR 네트워크의 신뢰도와 비교)

  • Kim Dong-Chul
    • Journal of Digital Contents Society
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    • v.6 no.1
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    • pp.7-12
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    • 2005
  • The purpose of this study is to study the relability of degree 2 ICR(Interleaved Cydic Ring) network and to compare with the other rings. Two node reliability is the probability that source node communicates with the destination node through a specified time interval for ICR network. The impact for change of failure rate is studied for ICR network for small size of network, the exact value of reliability is calculated but the approximation of average reliability general function from upper bound and lower bound reliability is obtained for large size of it. The reliability of ICR network is compared with it of the other rings according to changing the cycle value of ICR.

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Effects of KATP Channel Blocker, cAMP and cGMP on the Cardiovascular Response of Adenosine A1 Agonist in the Spinal Cord of the Rats

  • Shin In-Chul
    • Biomolecules & Therapeutics
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    • v.14 no.2
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    • pp.119-124
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    • 2006
  • This study was performed to investigate the influence of the spinal adenosine $A_1$ receptors on the central regulation of blood pressure (BP) and heart rate (HR), and to define whether its mechanism is mediated by cyclic AMP (cAMP), cyclic GMP (cGMP) or potassium channel. Intrathecal (i.t.) administration of drugs at the thoracic level were performed in anesthetized, artificially ventilated male Sprague-Dawley rats. I.t. injection of adenosine $A_1$ receptor agonist, $N^6$-cyclohexyladenosine (CHA; 1, 5 and 10 nmol) produced dose dependent decrease of BP and HR and it was attenuated by pretreatment of 50 nmol of 8-cyclopentyl-1,3-dimethylxanthine, a specific adenosine $A_1$ receptor antagonist. Pretreatment with a cAMP analogue, 8-bromo-cAMP, also attenuated the depressor and bradycardiac effects of CHA (10 nmol), but not with cGMP analogue, 8-bromo-cGMP. Pretreatment with a ATP-sensitive potassium channel blocker, glipizide (20 nmol) also attenuated the depressor and bradycardiac effects of CHA (10 nmol). These results suggest that adenosine $A_1$ receptor in the spinal cord plays an inhibitory role in the central cardiovascular regulation and that this depressor and bradycardiac actions are mediated by cAMP and potassium channel.

Analysis of Delamination Behavior on the Stacking Sequence of Prosthetic Foot Keel in Glass fiber Reinforced Laminates (인공발(Prosthetic Foot) 스프링용 유리섬유강화 적층재의 적층배향에 따른 층간분리거동 해석)

  • Song, Sam-Hong;Kim, Cheol-Woong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.4
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    • pp.623-631
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    • 2003
  • It is considered that the application of advanced composite materials to the prostheses for the disables is important to improve their bio-mechanical performance. Particularly, energy storing foot prosthesis is mostly important to restore gait ability of the disables with low-extremity amputation since it could provide propulsion at terminal stance enhancing the disables ability to walk long distance even run and jump. Therefore, the energy storing spring of Prosthetic foot keel under cyclic bending moment use mainly of high strength glass fiber reinforced plastic. The main objective of this study was to evaluate the stacking sequence effect using the delamination growth rate(dA$_{D}$/dN) of energy storing spring in glass fiber reinforced plastic under cyclic bending moment. The test results indicated that the shape of delamination zone depends on stacking sequence in GFRP laminates. Delamination area(A$_{D}$) turns out that variable types with the contour increased non-linearly toward the damage zones.nes.

The senstivity characteristics of cholesterol sensor by immobilization methods of the enzyme (효소 고정화 방법에 따른 콜레스테롤 센서의 감도 특성)

  • Song, Min-Jung;Yoon, Dong-Hwa;Jin, Joon-Hyung;Min, Nam-Ki;Hong, Suk-In
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1935-1937
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    • 2003
  • 최근 콜레스테롤 센서는 전극 상에 효소를 고정화 하는 방식을 이용하여 센서의 집적도를 높이는 시도가 이루어지고 있다. 이러한 전극 상의 효소고정화 방식으로 entrapment, cross liking, covalently binding 등이 있다. 본 논문에서는 이러한 효소 고정화 방식-전도성 고분자인 P3MT를 사용하여 entrap시키는 방법과 silanization을 이용한 covalent bonding 시키는 방법-에 따른 전기화학 센서의 감도 특성에 관한 연구를 수행하였다. 전도성 고분자를 사용한 고정화 방법은 cyclic voltammograms으로 scan rate 10 mA/s, potential 0.5-1.3V의 조건하에서 P3MT를 Polymerization하고, 효소 고정화를 위해 chromoampermeter로 potential 0.6V에서 900초 동안 수행하였다. silanization을 이용한 covalent bonding 시키는 방법은 nitric acid로 Pt 전극표면을 산화시키고, APTER로 silanization 공정을 시행하였다. 효소 고정화를 위해 전해질로는 0.1M Phosphate buffer solution을 사용하여 cyclic voltammograms으로 scan rate 50 mA/s 전위 0.0-0.7V의 조건 하에서 수행하였다. 이 결과 전도성 고분자를 이용한 고정화 방법에서의 senstivity가 0.89 ${\mu}A/mM{\cdot}cm^2$이고, silanization을 이용한 효소 고정화 방법에서는 1.51 ${\mu}A/mM{\cdot}cm^2$였다. 이처럼 후자의 방법에서 더 좋은 감도 특성이 나타났다. 따라서, silanization을 이용한 고정화 방법이 센서 제작 방식으로 더 적합하다고 사료된다.

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A Study on the Inhibition Effect of Metal Corrosion Using Organic Compound Containing an Amine Group (아민기를 가진 유기물을 사용한 금속의 부식억제효과)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.3
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    • pp.361-369
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    • 2010
  • A study on the corrosion inhibition of metals is important in many industrial applications (carbon steel, copper, aluminum, SUS 304, nickel). In this study, we investigated the C-V diagrams related to the surface corrosion of metals. It was observed through the SEM that the surface corrosion state of the various metals had the corrosion potential by the scan rate and the organic inhibitor containing an amine group. We determined to measure cyclic voltammetry using the three-electrode system. The measurement of oxidation and reduction ranged from -1350mV to 1650mV. The scan rate was 50, 100, 150, and 200mV/s. It turned out that the C-V characterization of SUS 304 was irreversible process caused by the oxidation current from the cyclic voltammogram. After adding organic inhibitors, the adsorption film was constituted, and the passive phenomena happened. As a result, it was revealed that the inhibition effect of metal corrosion depends on the molecular interaction, and the interaction has influence on the adsorption complex.

A Study on the Alkali Hydrolysis of PET fabrics with Ultrasonic Application(II)- Surface Porosity and Oligomer Analysis - (초음파를 적용한 PET 직물의 알칼리 가수분해에 관한 연구(II) - 기공특성과 올리고머 분석 -)

  • 김삼수;서말용;박성우;윤태희;이승구;허만우
    • Textile Coloration and Finishing
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    • v.14 no.6
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    • pp.305-312
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    • 2002
  • In order to give a silk-like touch to PET fabrics, the PET fabrics were treated with NaOH alkaline solution in various conditions. In alkaline treatment, the liquor flow type pilot weight reduction apparatus with magnetostrictive ultrasonic transducer was used for the study. The effects of ultrasonic application, treatment time and temperature at NaOH 4% and 6"A solution on the decomposition rate of PET fabrics. From the results of the decomposition rate of PET fabrics, the qualitative and quantitative analysis of oligomer after decomposition of PET fabrics carried out by the HPLC. On the other hand, the surface pore characteristics of decomposition PET fabrics measured by porosimetery. The pore characteristics on the surface of treated PET fiber depended on the decomposition rate and did not depend on the ultrasonic cavitation. The pore diameter of alkaline untreated PET fiber were 15A and those of treated PET fibers were 5~6$\AA$ at the maximum pore volume. The average pore sizes of fiber before and after treatment were 141 h and 160h, respectively. Total amount of oligomer of the untreated PET fibers were 1.70wt% and 67.7% of total oligomer occupied with PET cyclic trimer and PET cyclic tetramer. Total amount of oligomer of fiber with 26.9% and 48.0% of weight loss without ultrasonic application were 1.78wt% and 1.79wt%, respectively. Also total amount oligomer of fibers which were reduced 27.7% and 48.2% of weight loss with ultrasonic application were 1.74wt%. This result showed that the removal rate of oligomer in the process of alkaline hydrolysis with ultrasonic higher than that of without ultrasonic application.tion.