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Mechanical Degradation of Polystyrene by Mastication (II). Basic Studies on Recovery of Waste Polystyrene (Mastication에 依한 Polystyrene의 機械的 分裂 (第2報). 廢 Polystyrene 樹脂의 再生利用에 關한 基礎的 硏究)

  • Ki-Hyun Chung;Kook Joong Kim;Sang Dae Kim
    • Journal of the Korean Chemical Society
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    • v.19 no.5
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    • pp.386-393
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    • 1975
  • Polystyrene and polystyrene blended with SBR were subjected to the mechanical degradation by roll mastication. The results obtained are as follows. 1. For the polystyrene which is blended with SBR, the overall shape of the molecular weight distribution curve moves from the higher molecular weight portion to the lower molecular weight portion, becomes narrower in breadth, and its peak becomes higher as the degradation proceeds. The final molecular weight distribution exhibits a relative uniformity. This is due to the fact that only the polymer molecules with the high molecular weight consisted in original polystyrene are degraded mechanically and produced the polymer molecules with the low molecular weight. 2. The scission number of polystyrene chains increases with mastication time, and the number of degraded polymer chains produced when the polymer is masticated for 100 minutes at 140, 150 and $160^{\circ}C$ are $2.36{\times}10^{20},\;1.76{\times}10^{20}\;and\;1.52{\times}10^{20}$, respectively. 3. The rate of the degradation of polystyrene decreases with the mastication temperature. The activation energy is found to have the negative value, -8.7 kcal/mole. Therefore it is indicated that the mechanical degradation is a chemical process of which the activation energy is supplied mechanically.

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Forecasting of Car Distribution Considering the Population Aging (인구 고령화를 고려한 승용차 보급예측 연구)

  • Kim, Hyunwoo;Lee, Du-Heon;Yang, Junseok
    • Korean Journal of Construction Engineering and Management
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    • v.15 no.5
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    • pp.31-39
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    • 2014
  • It has been a long time since cars had become important means of transportation in human life. Since 1970s, cars have been increasing steadily because of rising individual income and changing lifestyle toward leisure and convenience. The number of cars is just 1.8 per thousand populations in 1970s, however, in 2012, it has increased to 291.15. Forecasting the demand for cars would be useful to plan, construction or management in the field of motor industry, road building and establishing facilities. Our study predicts the demand of cars through estimating the growth curve model. Especially, we include ageing variables to forecasting identifying the effect of ageing on the demand of cars. The main findings are as follows. In 2045, the number of cars is expected to reach 486.8 per thousand populations with passing a primary saturation point at early 2020s. Also, due to effect of ageing, the predicted demand of cars is about 10% lower than in case of which if ageing effect not exist.

Development of a Stability Formula for Tetrapod by Using M5' Model Tree (M5' Model Tree를 이용한 Tetrapod 안정식 개발)

  • Kim, Seung-Woo;Suh, Kyung-Duck
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.25 no.3
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    • pp.138-146
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    • 2013
  • Tetrapod, one of the famous armor blocks for rubble mound breakwaters, has been widely used in the world. In order to evaluate the required weight of Tetrapod, many researchers have proposed various stability formulas. Since the stability formulas were proposed by curve-fitting the experimental data, some uncertainties are included in the formulas. The main uncertainties are associated with experimental data, derivation of the formula, and variability of the design variables. In this study, a new stability formula is developed by using M5' model tree, which reduces the uncertainty in the derivation of the formula. The index of agreement is used to evaluate the performance of the developed formula. The index of agreement for the new formula is higher by about 0.1 than the previous formula. The performance of the previous formula was not good when the predicted stability number is greater than about 3.0. However. the new formula is accurate regardless of the magnitude of stability number. As a result, the new formula performs better than the previous formula, while expressed in the form of a tree but still in an explicit form.

Multi-View Video System using Single Encoder and Decoder (단일 엔코더 및 디코더를 이용하는 다시점 비디오 시스템)

  • Kim Hak-Soo;Kim Yoon;Kim Man-Bae
    • Journal of Broadcast Engineering
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    • v.11 no.1 s.30
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    • pp.116-129
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    • 2006
  • The progress of data transmission technology through the Internet has spread a variety of realistic contents. One of such contents is multi-view video that is acquired from multiple camera sensors. In general, the multi-view video processing requires encoders and decoders as many as the number of cameras, and thus the processing complexity results in difficulties of practical implementation. To solve for this problem, this paper considers a simple multi-view system utilizing a single encoder and a single decoder. In the encoder side, input multi-view YUV sequences are combined on GOP units by a video mixer. Then, the mixed sequence is compressed by a single H.264/AVC encoder. The decoding is composed of a single decoder and a scheduler controling the decoding process. The goal of the scheduler is to assign approximately identical number of decoded frames to each view sequence by estimating the decoder utilization of a Gap and subsequently applying frame skip algorithms. Furthermore, in the frame skip, efficient frame selection algorithms are studied for H.264/AVC baseline and main profiles based upon a cost function that is related to perceived video quality. Our proposed method has been performed on various multi-view test sequences adopted by MPEG 3DAV. Experimental results show that approximately identical decoder utilization is achieved for each view sequence so that each view sequence is fairly displayed. As well, the performance of the proposed method is examined in terms of bit-rate and PSNR using a rate-distortion curve.

Fishing Experiment for Development of Unused Fishery Resources on the Deep Sea Bed of Korean East Sea (동해구 심해 미이용 자원의 어획 시험 연구)

  • Lee, Byoung-Gee;Lee, Ju-Hee;Shin, Hyeong-Il
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.22 no.4
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    • pp.61-70
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    • 1986
  • In accordance with a rapid growth of demani on aquatic animals, researches of the unused fishery resources On the deep sea b~d in the Korean Waters has been and will be required. The authors carried out a series of fishing experiments to investigate the available resources and to find the effective fishing method on the deep sea bed of the Korean East Sea. In the experiments, 19 kinds of traps which are different from each other in shape, mesh size and entrance diameter were used. The fishing experiments w~r;; carried out in four areas of 20Dm, 600.'11, 800m and 1000.'11 deep respectively, by the Pusan 402 (30:) GT) and the Pusan 403 (279GT), the training ships of National Fisheries University of Pusan, during August, 1986. The catc~ were analyzed with the size, the depth and the construction of traps. The results obtained can be summarized as follows: 1. Main species of the catch w~re pink shrimp, Pandalus bolelis, a kind of welks, Buccimum striatissimum and a kind of larg~ crabs. Chiono8cetes japonicus and the another species were few. 2. The CPUE value (expressed by the number of catch per trap in this paper) of pink shrimp was the highest in the depth of 20J-n around, and the value in the depth of 600.'11 or more decreased gradually with an increase of the depth. But, the value of Buccimum straitissimum was much higher in the depth of 6:J:)!1I or more than that in the depth of 200m around. On the other hand, the value of Chion:Jecetes japonjcus was very low in general. 3. The iniividual body size of the catch differed with the depth. Pink shrimps caught in the depth of 200m around were smaller than those in the depth of 600.'11 or more. In contrast with this, Baccimum striatissim:t.m caught in the depth of 200m around were larger than those in the depth of 600.'11 or more. 4. Depending on the selection curve in Ishida's method for the mesh size of trap webbing, the carapace length of pink shrimp and the shell length of Buccimum striatissimum which are equivalent to 100% relative catching efficiency can be estimated about 3.5cm and 6.5cm or so respectively. 5. The number of catch of pink shrimp and Buccimum striatissimum by the 60.'1'1.'11 entrance diameter of trap were less than that by the 90mm, 120mm and 150mm, even thogh the diffierence am~r, g 9:Jmm, 120.'11.'11 and 150:1'.'11 are not so large.

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A study on the Household consumption of Tap Water and the Decreasing Rate of lpcd by the increase in the Number of Residents in Seoul (서울시 가정에서의 수돗물 사용량과 거주인수 증가에 따른 1인 1일 사용량의 감소변화에 관한 연구)

  • Kim, Kap-Soo;Yang, Ji-Hee;Hwang, Seong-Hwan
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.1
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    • pp.89-97
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    • 2007
  • This study analyzed the lpcd of 25 districts in Seoul using random samples of residents in Seoul selected by computer selecting system. By classifying these samples according to the type of houses(tenement houses, apartment houses and detached houses), the type of districts, the effects of the number of residents in a house and the type of the houses on tap water use are analyzed. From these samples, the consumption of tap water per capita day(lpcd) in Seoul can be estimated statistically. It is also observed that the lpcd decreases as the flat-dwellers increase. As the dwellers increase from 1 to 2, from 2 to 3, from 3 to 4 and from 4 to 5, lpcd has decreased by 47.6%, 20.8%, 16.9%, and 9.0%, respectively. The regression curve, which fits the tendency of decrease well, is represented by an power function. And the estimated linear regression equation shows that the average decreasing rate of lpcd as flat dwellers increasing is 12%.

Analysis of the Inequalities in Healthcare Service Usage Considering Healthcare Service Needs (의료필요를 고려한 의료이용의 형평성 분석)

  • Lee, Yong-Jae;Lee, Hyun-Ok;Kim, Hyung-Eick
    • The Journal of the Korea Contents Association
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    • v.17 no.11
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    • pp.435-445
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    • 2017
  • This study was conducted to overcome the limitations of prior research on the equity of medical care performed by identifying simple differences in the use of medical care or using limited medical needs and medical utilization indicators. Specifically, we used activity limits, chronic diseases, and subjective health status as medical needs, and used outpatient, inpatient, and emergency services as medical uses. In addition, we used concentration index, concentration curve, and Le Grand factor to analyze the equity of medical use considering medical needs. The main results are as follows. First, the amount of medical care for the low-income class is higher than that of the high-income class when considering the concentration of medical use. In particular, the number of hospitalization days for low-income households and hospitalization fees were higher than the fees of outpatient medical consultation and emergency room usage. Second, medical needs were concentrated in the low income class. In other words, low-income group is not as healthy as the high-income group. Third, the Le Grand factor was calculated in order to confirm the fairness of the medical uses considering the medical needs. Even if medical needs are taken into consideration, the high-income earners will have a large amount of medical care. In addition, when considering the limitation of activity and the number of chronic diseases, the medical use of the high income class was more frequent. However, when the subjective health condition and the chronic illness were considered, medical use of the low income class was more frequent. This may be due to the underestimation of the medical needs of the low-income earners by neglecting their own health status and perception of chronic diseases.

Spawning Time and Early Growth of Pacific Cod (Gadus macrocephalus) in Jinhae Bay, Korea (진해만 대구의 부화일 및 초기 성장에 관한 연구)

  • Gwak, Woo-Seok;Choi, Byung-Eon;Lee, So-Gwang
    • Korean Journal of Ichthyology
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    • v.24 no.2
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    • pp.110-117
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    • 2012
  • Hatching date and early growth of Pacific cod Gadus macrocephalus were estimated by examination of otolith microstructure of Pacific cod juveniles collected in Jinhae Bay of Korea from May to June, 2008. Water temperature during the main spawning time ranged from 7 to $9^{\circ}C$ according to the geographic distribution of temperature measured from November to May between 2006 and 2009. The spawners were collected from December to February between 2006 and 2008, and the gonadosomatic index of spawners was larger in females than in males, showing a peak in January. Total length of juveniles ranged from 37.5 to 94.9 mm ($63.2{\pm}11.0mm$; mean${\pm}$SD). The number of daily growth increments in juvenile otoliths were on average $102{\pm}15$ in May 17 samples, $119{\pm}16$ in May 29 ones and $116{\pm}18$ in June 3 ones. Hatching dates estimated from the number of daily growth increments ranged from late December to mid-March, showing the peak between late January and mid-February. Daily growth in total length (TL, mm) can be adjusted to the Gompertz curve: $TL_t=123.2{\exp}\{-{\exp}[-0.0165(t-81.8)]\}$ ($r^2$=0.93, n=273).

Isolation and Identification of Major Microbial Groups during Baikkimchi Fermentation (백김치 발효중 주요 미생물 군집의 분리 및 동정)

  • 소명환;김영배
    • The Korean Journal of Food And Nutrition
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    • v.10 no.3
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    • pp.350-359
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    • 1997
  • The changes in pH, acid contents and microbial counts were investigated during fermentation of Baikkimchi, a kind of Kimchi without red pepper, and the major microbial groups were also isolated and identified. Immediately after the preparation of Baikkimchi(pH 6.15, acid contents 0.03%), its major microbial group was Gram negative rods, and was composed of Pseudomonas(55%), Enterobacter(40%) and Erwinia(5%). After 2 days of fermentation at 15$^{\circ}C$, the most predominant microbial group was changed to lactic acid bacteria. Lactic acid bacteria showed 1st, 2nd and 3rd stationary phase on its growth curve in 4, 12 and 50 days of fermentation, respectively. At the 2nd stationary phase of lactic acid bacteria(pH 3.51, acid contents 0.59%), the group was composed of Lactobacillus bavaricus(55%), Leuconostoc mesenteroides subsp. mesenteroides(42.5%) and Leuconostoc paramesenteroides(2.5%), while at the 3rd stationary phase(pH 3.40, acid contents 1.10%), that was Lactobacillus plantarum(65%) and Lactobacillus brevis(35%). The physiological and biochemical characteristics identified as Leuconostoc mesenteroides subsp. mesenteroides, Leuconostoc paramesenteroides, Lactobacillus plantarum and Lactobacillus brevis showed good agreement with the current taxonomic system, but those identified as Lactobacillus bavaricus showed some disagreements. The number of yeast was decreased wit the increase in the number of lactic acid bacteria. Yeast showed stationary phase in 30 days between the 2nd and 3rd stationary phase of lactic acid bacteria, and the group was composed of only gunus Saccharomyces.

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Calibration of Portable Particulate Mattere-Monitoring Device using Web Query and Machine Learning

  • Loh, Byoung Gook;Choi, Gi Heung
    • Safety and Health at Work
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    • v.10 no.4
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    • pp.452-460
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    • 2019
  • Background: Monitoring and control of PM2.5 are being recognized as key to address health issues attributed to PM2.5. Availability of low-cost PM2.5 sensors made it possible to introduce a number of portable PM2.5 monitors based on light scattering to the consumer market at an affordable price. Accuracy of light scatteringe-based PM2.5 monitors significantly depends on the method of calibration. Static calibration curve is used as the most popular calibration method for low-cost PM2.5 sensors particularly because of ease of application. Drawback in this approach is, however, the lack of accuracy. Methods: This study discussed the calibration of a low-cost PM2.5-monitoring device (PMD) to improve the accuracy and reliability for practical use. The proposed method is based on construction of the PM2.5 sensor network using Message Queuing Telemetry Transport (MQTT) protocol and web query of reference measurement data available at government-authorized PM monitoring station (GAMS) in the republic of Korea. Four machine learning (ML) algorithms such as support vector machine, k-nearest neighbors, random forest, and extreme gradient boosting were used as regression models to calibrate the PMD measurements of PM2.5. Performance of each ML algorithm was evaluated using stratified K-fold cross-validation, and a linear regression model was used as a reference. Results: Based on the performance of ML algorithms used, regression of the output of the PMD to PM2.5 concentrations data available from the GAMS through web query was effective. The extreme gradient boosting algorithm showed the best performance with a mean coefficient of determination (R2) of 0.78 and standard error of 5.0 ㎍/㎥, corresponding to 8% increase in R2 and 12% decrease in root mean square error in comparison with the linear regression model. Minimum 100 hours of calibration period was found required to calibrate the PMD to its full capacity. Calibration method proposed poses a limitation on the location of the PMD being in the vicinity of the GAMS. As the number of the PMD participating in the sensor network increases, however, calibrated PMDs can be used as reference devices to nearby PMDs that require calibration, forming a calibration chain through MQTT protocol. Conclusions: Calibration of a low-cost PMD, which is based on construction of PM2.5 sensor network using MQTT protocol and web query of reference measurement data available at a GAMS, significantly improves the accuracy and reliability of a PMD, thereby making practical use of the low-cost PMD possible.