• 제목/요약/키워드: Curing solution

검색결과 287건 처리시간 0.027초

에폭시 아크릴레이트 올리고머와 전도성 카본블랙을 이용한 감광성 저항 페이스트 조성 연구 (Study on the Compositions of Photosensitive Resistor Paste Using Epoxy Acrylate Oligomers and Conductive Carbonblack)

  • 박성대;강남기;임진규;김동국
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.421-421
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    • 2008
  • Generally, the polymer thick-film resistors for embedded organic or hybrid substrate are patterned by screen printing so that the accuracy of resistor pattern is not good and the tolerance of resistance is too high(${\pm}$20~30%). To reform these demerits, a method using Fodel$^{(R)}$ technology, which is the patterning method using a photosensitive resin to be developable by aqueous alkali-solution as a base polymer for thick-film pastes, was recently incorporated for the patterning of thermosetting thick-film resistor paste. Alkali-solution developable photosensitive resin system has a merit that the precise patterns can be obtained by UV exposure and aqueous development, so the essential point is to get the composition similar to PSR(photo solder resist) used for PCB process. In present research, we made the photopatternable resistor pastes using 8 kinds of epoxy acrylates and a conductive carbonblack (CDX-7055 Ultra), evaluated their developing performance, and then measured the resistance after final curing. To become developable by alkali-solution, epoxy acrylate oligomers with carboxyl group were prepared. Test coupons were fabricated by patterning copper foil on FR-4 CCL board, plating Ni/Au on the patterned copper electrode, applying the resistor paste on the board, exposing the applied paste to UV through Cr mask with resistor patterns, developing the exposed paste with aqueous alkali-solution (1wt% $Na_2CO_3$), drying the patterned paste at $80^{\circ}C$ oven, and then curing it at $200^{\circ}C$ during 1 hour. As a result, some test compositions couldn't be developed according to the kind of oligomer and, in the developed compositions, the measured resistance showed different results depending on the paste compositions though they had the same amount of carbonblack.

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PET/Co-PET해도사 직물의 Co-PET추출 조건에 관한 연구 (A Study on Extraction Condition of Co-PET from PET/Co-PET Sea-Island Type Microfiber Fabric)

  • 박명수;윤종호;조대현
    • 한국염색가공학회지
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    • 제13권2호
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    • pp.120-127
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    • 2001
  • In order to make a microfiber fabric with PET/Co-PET Sea-Island Type microfiber, the optimum condition of extraction and elimination of Co-PET from the mocrofiber was examined. At the same time, the physical property change of the fabric with respect to the change of the relative amount of the Co-PET in the microfiber was also examined to provide a directly applicable data set to the industry. The sample fabric used was warp 75/36(DTY) and weft 0.05d(PET/Co-PET, Sea Island Type Microfiber) twill fabric of 36 separated yarns+40/24(high shrinking yarn) with 130/48 ITY. The data set was made at various NaOH concentrations and steam temperatures with time as a main variable. The physical properties examined were the tensile properties. The results obtained were the tensile. The results obtained were 1. For a proper extraction of Co-PET (13.5%)from the microfiber with wet curing, it takes more than 5 min. in 8 and 12% of NaOH solutions but it takes only 3 min. in 18% of NaOH solution at 12$0^{\circ}C$. 2. For a proper extraction of Co-PET (13.5%) from the microfiber with wet curing, ti takes 3~5min. in 12 and 14% of NaOH solution and it takes less than 3 min. in 18% of NaOH solution at $130^\circ{C}$. 3. The increasing ratio of WT increased with increasing NaOH concentrations and the equilibrium point reached was 3 min. at $120^\circ{C}$. 4. The WT increasing ratio was greater in 14 and 18% NaOH solutions than in 8 and 12% of NaOH solutions at $130^\circ{C}$5. The RT ratio changes at $120^\circ{C}$ in 8 and 12% of NaOH solutions were indifferent from that at $130^\circ{C}$ in 12% of NaOH solution. However, the RT was apparently decreased with increasing NaOH concentration.

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PET/Co-PET 해도사 직물의 Co-PET 추출 조건에 관한 연구 (A Study on Extraction Condition of Co-PET from PET/Co-PET Sea-Island Type Microfiber Fabric)

  • 박명수;윤종호;조대현
    • 한국염색가공학회지
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    • 제13권2호
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    • pp.34-34
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    • 2001
  • In order to make a microfiber fabric with PET/Co-PET Sea-Island Type microfiber, the optimum condition of extraction and elimination of Co-PET from the microfiber was examined. At the same time, the physical property change of the fabric with respect to the change of the relative amount of the Co-PET in the microfiber was also examined to provide a directly applicable data set to the industry. The sample fabric used was warp 75/36(DTY) and weft 0.05d(PET/Co-PET, Sea Island Type Microfiber) twill fabric of 36 separated yarns+40/24(high shrinking yarn) with 130/48 ITY. The data set was made at various NaOH concentrations and steam temperatures with time as a main variable. The physical properties examined were the tensile properties. The results obtained were the tensile properties. The results obtained were 1. For a proper extraction of Co-PET (13.5%)from the microfiber with wet curing, it takes more than 5 min. in 8 and 12% of NaOH solutions but it takes only 3 min. in 18% of NaOH solution at 120℃. 2. For a proper extraction of Co-PET (13.5%) from the microfiber with wet curing, it takes 3∼5 min. in 12 and 14% of NaOH solution and it takes less than 3 min. in 18% of NaOH solution at 130℃. 3. The increasing ratio of WT increased with increasing NaOH concentrations and the equilibrium point reached was 3 min. at 120℃. 4. The WT increasing ratio was greater in 14 and 18% NaOH solutions than in 8 and 12% of NaOH solutions at 130℃. 5. The RT ratio changes at 120℃ in 8 and 12% of NaOH solutions were indifferent from that at 130℃ in 12% of NaOH solution. However, the RT was apparently decreased with increasing NaOH concentration.

Chitosan-Polyurethane 혼합용액으로 처리된 직물의 태 연구 -Epichlorohydrin에 의한 가교가 도입되는 경우- (Hand of the Fabrics treated with Chitosan-Polyurethane Mixture Solution - Case of Crosslinking by Epichlorohydrin -)

  • 곽정기;김종준;전동원
    • 한국의류산업학회지
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    • 제7권4호
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    • pp.445-451
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    • 2005
  • Up to the present, fabric finishing methods have been mainly employed for the application of chitosan. However, the coated chitosan acid salt is prone to be detached from the fabric during the laundering process. In order to improve the wash fastness, chitosan treated fabrics are being subjected to thermal curing. In this study, chemical crosslinking reaction by epichlorohydrin was introduced to improve the problem of the thermal curing. An improvement of the wash fastness is expected since the coated chitosan component on the fabric become insoluble by the introduction of the crosslinking. The demerit of the single chitosan treatment (inferior handle due to the excessive stiffness, etc.) was supplemented by the application of chitosan-polyurethane mixture solution. The mixture ratios were adjusted to 1 : 0, 1 : 0.25, 1 : 0.5, 1 : 1, and 1 : 2 for the chitosan/PU mixture. Physical and mechanical properties of the finished fabric specimens were measured using the Kawabata Evaluation System(KES), and hand values were calculated accordingly based on the translational formulas.

2차원 CFD를 활용한 시멘트 페이스트의 슬럼프 유동 모사 (Numerical Analysis on Flow of Cement Paste using 2D-CFD)

  • 윤태영
    • 한국도로학회논문집
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    • 제19권4호
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    • pp.19-25
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    • 2017
  • PURPOSES : In this paper, the flow of construction material was simulated using computational fluid dynamics in a 2D axisymmetric condition to evaluate the effect of initial or varying material properties on the final shape of a specimen. METHODS : The CFD model was verified by using a well-known analytical solution for a given test condition followed by performing a sensitivity analysis to evaluate the effect of material properties on the final shape of material. Varying dynamic viscosity and yield stress were also considered. RESULTS : The CFD model in a 2D axisymmetric condition agreed with the analytical solution for most yield stress conditions. Minor disagreements observed at high yield stress conditions indicate improper application of the pure shear assumption for the given material behavior. It was also observed that the variation of yield stress and dynamic viscosity during curing had a meaningful effect on the final shape of the specimen. CONCLUSIONS : It is concluded that CFD modeling in a 2D axisymmetric condition is good enough to evaluate fluidal characteristics of material. The model is able to consider varying yield stress and viscosity during curing. The 3D CFD-DEM coupled model may be required to consider the interaction of aggregates in fluid.

양모직물의 내구성 발수 및 발유가공(II) (Durable Water and Oil Repellent Finish of Wool Fabric(II))

  • 나도춘;정순량;박병기;정경락
    • 한국염색가공학회지
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    • 제10권4호
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    • pp.1-6
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    • 1998
  • It is important in the durable water and oil repellent finishing for wool fabric what kinds of water-repellent agents will be used. Water repellent agents and its concentration were aleady chosen in the previous paper, one of the crosslinking agents which has less damages(harsh handle or yellowing) to the treated fabrics was a low molecular weight urethane-based resins(eg. Elastron BN-11). In repellent finishing, fabrics were padded in a bath which contained aqueous solution of water-repellent agents, and crosslinking agents, and wetting agents, followed by drying and curing. The most suitable treating condition for excellent repellency and durability to dry-cleaning was as follows : Fabrics are padded at liquor pick-up ratio of 50%, with aqueous solution which contained $30g/\ell$ of water-repellent agents, and $1g/\ell$ of crosslinking agents, and 40g/s of wetting agents. And the padded fabrics were dried at $110^\circ{C}$ for 1 minute, and cured at $160^\circ{C}$ for 1 minute. For the fabrics, water and oil repellencies and durability to repeated dry-cleanings were observed. For enhancing the durability to dry-cleaning, the role of crosslinking agents was important for they bonds water-repellent agents and fibers to 3-dimensional net structure. Therefore, the most suitable drying and curing conditions should be selected according to the kinds of crosslinking agents.

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Micro-Structural Enhancement of XLPE Insulation Using Additive Diffusion Method

  • Park, Se-Eun;Shim, Sung-Ik;Cho, Dae-Hee;Youn, Bok-Hee
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.238-239
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    • 2005
  • With the aim of developing XLPE insulation for extra high voltage cable, we investigated the morphology of cross-linked polyethylene. We used a kind of base materials and additives, and controlled curing condition and amount of additives. The effect of addition of additives on morphology of XLPE such as lamellar density, orientation and additive layer were analyzed using TEM analysis. We applied this result to diffused additive amount was analyzed using FT-IR analysis, and the change of microstructure as the degree of additive diffusion was analyzed using TEM analysis.

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Development of eco-friendly concrete produced with Rice Husk Ash (RHA) based geopolymer

  • Annadurai, Shalini;Rathinam, Kumutha;Kanagarajan, Vijai
    • Advances in concrete construction
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    • 제9권2호
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    • pp.139-147
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    • 2020
  • This paper reports the effect of Rice Husk Ash (RHA) in geopolymer concrete on strength, durability and microstructural properties under ambient curing at a room temperature of 25℃ and 65±5% relative humidity. Rice husk was incinerated at 800℃ in a hot air oven. and ground in a ball mill to achieve the required fineness. RHA was partially added in 10, 15, 20, 25, 30 and 35 percentages to fly ash with 10% of GGBS to produce geopolymer concrete. Test results exhibit that the substitution of RHA in geopolymer concrete resulted in reduced strength properties during initial curing. In the initial stage, workability of GPC mixes was affected by RHA particles due to the presence of dormant particles in it. It is evident from the microstructural study that the presence of RHA particles densifies the matrix reducing porosity in concrete. This is due to the presence of RHA in geopolymer concrete, which affects the ratio of silica and alumina, resulting in polycondensation reactions products. This study suggests that incorporation of rice husk ash in geopolymer concrete is the solution for effective utilization of waste materials and prevention of environmental pollution due to the dumping of industrial waste and to produce eco-friendly concrete.

Utilization of Kota stone slurry powder and accelerators in concrete

  • Devi, Kiran;Saini, Babita;Aggarwal, Paratibha
    • Computers and Concrete
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    • 제23권3호
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    • pp.189-201
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    • 2019
  • Recent advances in the concrete technology are aiding in minimizing the use of conventional materials by substituting by-products of various industries and energy sources. A large amount of stone waste i.e., dust and slurry form both are being originated during natural stone processing and causing deadily effects on the environment. The disposal problem of stone waste can be resolved effectively by using waste in construction industries. In present work, Kota stone slurry powder, as a substitution of cement was used along with accelerators namely calcium nitrate and triethanolamine as additives, to study their impact on various properties of the concrete mixtures. Kota stone slurry powder (7.5%), calcium nitrate (1%) and triethanolamine (0.05%) were used separately as well in combination in different concrete mixtures. Mechanical Strength, modulus of elasticity and electrical resistivity of concrete specimens of different mix proportions under water curing were studied experimentally. The durability properties in terms of strength and electrical resistivity against sulphate and chloride solution attack at various curing ages were also studied experimentally. Results showed that accelerators and Kota stone slurry powder separately enhanced the mechanical strength and electrical resistivity; but, their combination decreased strength at all curing ages. The durability of concrete specimens was also affected under the exposure to chemical attack too. Kota stone slurry powder found to be the most effective material among all materials. Material characterization was also done to study the microstructural properties.

양생기간이 TiO2 나노튜브 보강 시멘트 페이스트의 광촉매 효과에 미치는 영향 (Effect of Curing Period on Photocatalytic Effect of TiO2 Nanotubes-reinforced Cement Paste)

  • 유준성;진다형;배성철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2021년도 가을 학술논문 발표대회
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    • pp.172-173
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    • 2021
  • With the development of nano-reinforcement technology and the increasing concern for environmental issues, TiO2 nanomaterials have received wide attention as an additive besides carbon nanomaterials that can be used to enhance the mechanical properties of cement-based materials. Also, TiO2-based materials can allow cement-baned materials with photocatalytic capability, providing a potentially effective approach to reduce environmental problems. In this work, compressive strength, splitting tensile strength, and degradation of methylene blue solution were used as target to assess the effect of TiO2 nanotubes on the mechanical strength and photocatalytic effect of hardened cement paste at different curing time. According to the strength results, the optimum amount of TiO2 was identified as 0.5% of the weight of cement. Meanwhile, the TiO2 nanotubes-reinforced specimen exhibited better photocatalytic effect in the early stage of curing.

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