• 접착 및 계면
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• 제7권4호
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• pp.45-52
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• 2006

Five low molar ratio urea-formaldehyde (LUF) resins were synthesized in this study. The effects of molar ratio, free formaldehyde content, and catalysts on the curing characteristics of LUF resins were studied by measuring its free formaldehyde content, pH value change after catalysts added, curing rate, and pot life, observing its cured appearance, and analyzing its thermal behavior. The results indicate that: 1) The LUF resin with lower molar ratio than 1.0 can still cure; 2) Free formaldehyde content is not the main factor in affecting curing rate of LUF resin; 3) Compared with ammonium chloride as a traditional catalyst, persulfate salts markedly accelerate the curing rate of LUF resin, and result in the different appearance; 4) the addition of sodium chloride to catalysts can accelerate the curing rate of LUF resin, but the effect is moderate.

• 한국응용과학기술학회지
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• 제18권1호
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• pp.40-48
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• 2001

Curing reaction was carried out with the acrylic resin (ACR) [n-butyl acrylate/atyrene/2-hydroxyethyl methacrylate/acetoacetoxyethyl methacrylate (AAEM)] synthesized before and a curing agent, hexamethoxymethylmelamine (HMMM). With rotational rheometer, the effect of catalysts on curing rate of acrylic resin/melamine was examined. Among the four catalysts used, p-toluene sulfonic acid showed the highest reactivity, and the optimum amount of catalyst was 0.5 phr. It was observed that in the ACR/HMMM curing reaction, gelation point was lowered with the increasing the amount of AAEM and HMMM in the ACR.

• 접착 및 계면
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• 제2권3호
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• pp.16-24
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• 2001

포름알데히드/페놀의 몰비에 따른 레졸과 노블락 수지의 경화거동을 FT-IR 분석법으로 연구하였다. 일정한 경화온도(레졸 수지: $130^{\circ}C$, $160^{\circ}C$, $180^{\circ}C$, 노블락 수지: $160^{\circ}C$, $170^{\circ}C$, $180^{\circ}C$)에서 경화시간(3, 5, 7, 10, 20, 60분)에 따른 경화 정도를 비교하였다. 경화정도(conversion, ${\alpha}$)는 경화되지 않은 수지의 FT-IR 스펙트라 $3300cm^{-1}$에 나타나는 OH 피크의 면적을 기준으로 각각 주어진 경화시간의 OH 피크 면적 비율로 구하였다. 그 결과 포름알데히드/페놀의 몰비와 경화 온도가 증가함에 따라서 레졸과 노블락 수지의 초기 경화는 증가하였다. 특정한 경화 온도에서 integral method 분석에 의한 결과 포름알데히드/페놀의 몰비가 증가함에 따라서 레졸과 노블락 수지의 초기 경화는 증가하였다.

• 한국재료학회:학술대회논문집
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• 한국재료학회 1994년도 추계 학술발표 강연 및 논문 개요집
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• pp.125-126
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• 1994

The chemorheological changes and kinetics during curing reaction of an silica filled epoxy system (DGEBA with curing agent Polyxoypropylenediamine) were investigated. This study concentrates on the influence of silica on the reaction kinetics and rheological behavior of the eopxy system. The concentration of the filler was varied 0~200phr. Curing behavior of the silica filled epoxy system was measured at various heating rates with DSC. Conversion was also measured by integrating the obtained DSC curve and Kinetic parameters measured by using the nonlinear regression method. DSC experiments showed that the presence of silica was found to accelerate the progress of the curing reaction and of reduce the heat of reaction compared with that of unfilled epoxy systems . Rheological experiments were conducted on a Physica by using a disposable parallel plate fixture. Material properites were measured such as the elastic modulus(G′), the loss modulus(G"), the loss tangent(tan $\delta$), and the viscosity was at the initial stahe, and the more the silica filler was added, and the lower the gel temperature was in the epoxy system. In this study it is concluded that the curing of the silica filled epoxy system was found to be accelerated, as silica was added to the epoxy compound.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.738-741
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• 2001

We carried out aminolyses of various rigid polyurethane foams (PUFs) using diethylene triamine and studied application of the aminolysis products as hardners of epoxy resins. Diglycidyl ether of bisphenol A was used for the study on the curing behavior of epoxy resin with the aminolysis product employing differential scanning calorimeter. Curing reaction of the epoxy resin is generally known to be autocatalytic second order reaction. We found that the curing reaction of the epoxy resin with the aminolysis product of rigid PUF did not show autocatalytic characteristics but followed the n-th order kinetics. The activation energy of the curing reaction of the epoxy resin with the aminolysis product of rigid PUF made from sugar based polyol was slightly lower than that of the epoxy resin with aminolysis product of rigid with made from amine based polyol.

• Advances in concrete construction
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• 제11권4호
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• pp.347-356
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• 2021

To address the limitation of the commonly used steam curing of reactive powder concrete (SC-RPC) in engineering, a preparation technology of normal curing reactive powder concrete (NC-RPC) is proposed. In this study, an experimental comparative research on the mechanical properties of NC-RPC and SC-RPC under uniaxial tension is conducted. Under the premise of giving full play to the ultra-high performance of RPC, the paper tries to explore whether normal curing can replace steam curing. The results show that various mechanical indexes of NC-RPC (e.g., tensile strength, ultimate tensile strain, elastic modulus and deformation performance) could basically reach the mechanical index values in steam curing at 28d age, some performance is even better at a longer age. So it affirms the feasibility of normal curing. In this paper, the influence of normal curing age on the tensile properties of RPC is discussed, and the relationship between each index and age is introduced in detail. Based on the experimental data, the tensile mechanism of RPC is analyzed theoretically, and two kinds of tensile constitutive models for RPC are proposed, one is curvilinear model, and another one is polygonal line model. The validity of the two models is further verified by the test results of others.

• 접착 및 계면
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• 제12권1호
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• pp.34-42
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• 2011

자동차용 도장시스템으로 새롭게 대두되고 있는 roll coating process는 비친환경적이면서도 생산성이 떨어지는 기존의 습식도장공정을 완전 대체할 수 있는 기술로 알려져 있다. Pre-painted 강판 시스템에서 도막 유연성 및 강도 등의 구현을 위하여 경화거동뿐만 아니라 내식성 및 성형가공성, 유변학적 거동 등의 평가가 매우 중요하다. 본 연구에서는 pre-painted system에 적용하기 위하여 polyester 수지를 수산화기 및 분자량 변성을 통하여 합성한 후, 경화거동 및 딥드로잉, 인장력, 유변특성 등을 평가하였다. 40 (mg KOH-/mol)정도의 수산화기를 갖는 N-0375-40 system이 유연성 및 도막강도, 경화거동 등의 가장 우수한 물성을 나타내었다.

• 폴리머
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• 제39권2호
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• pp.256-260
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• 2015

우레탄 아크릴레이트에 montmorillonite(MMT)를 첨가한 UV 경화형 나노복합체 제조 시 사용하는 광개시제의 종류에 따른 기계적 성질 및 내흡수성을 조사하였다. 1 wt%의 MMT가 첨가될 경우 가장 우수한 인장강도와 내흡수성을 나타내었으며, 광개시제의 경우 기존의 benzyldimethylketal 계열 광개시제와 bisacyl phosphine oxide 계열의 광개시제를 함께 사용할 경우 3 wt%의 MMT 함량에서도 사용된 UV 램프의 방출 파장대인 340~450 nm에서의 광흡수가 강화되어 나노복합체의 경화거동에 보다 효과적인 것으로 확인되었다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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• pp.1013-1016
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• 2003

This paper is to evaluate practically the techniques and materials of repair for RC elements with fire damages as well as to investigate the structural behavior of RC beams according to pre- or post-repair after fire-damages. For this purpose, normal concrete flexural specimens were exposed to high temperatures by the ISO 834 specification. After natural cooling and post-fire-curing in a natural environment for 2 months, the specimens were repaired with polymer cement mortar for 1 month curing.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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• pp.481-484
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• 2004

This study was performed to analyze effect of cyclic load during CFS curing on the behavior of RC beam strengthened with CFS. In the experiment, five different beginning times of cyclic load and two different strengthening amounts of CFS were chosen for experiment parameters. From the experimental results, it could be known that the cyclic load during CFS curing might give detrimental effects to the CFS strengthening effects compared to without cyclic load cases.