• Korea-Australia Rheology Journal
• /
• v.19 no.1
• /
• pp.7-16
• /
• 2007

A dynamic Monte Carlo percolation grid simulation is used to predict the cure behaviour of thermoset materials. Molecules are distributed in a fixed grid and a probability of reaction is assigned to each pair of neighbouring units considering both reaction rates and diffusion. The concentration and network characteristics are predicted throughout the whole curing process and compared to experimental data for an epoxy-amine matrix.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2023.05a
• /
• pp.377-378
• /
• 2023

This study examined the effect of curing conditions on the compressive strength of dry mortar for floor. The compressive strength according to the relative humidity during curing was compared, and the influence of expansive additives on compressive strength under water curing was reviewed. As a result, low relative humidity conditions during curing was not effective in improving the compressive strength of dry mortar for floor, and it was judged that the continuous hydration reaction insufficient due to lack of the moisture supply. In order to improve compressive strength, high relative humidity maintenance was found to be an important factor. However, under water curing conditions, the compressive strength has decreased as a result of continuous volume expansion due to the use of the expansive additives.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2004.10a
• /
• pp.96-99
• /
• 2004

Silica fillers were coated by plasma polymer coatings of 1,3-diaminopropane, allylamine, pyrrole, 1,2-epoxy-5-hexene, allyl mercaptan and allyl alcohol using RF plasma (13.56 MHz). The coated fillers were then mixed with biphenyl epoxy, phenol novolac (curing agent) and/or triphenylphosphine (catalyst), and subjected to DSC analyses in order to elucidate the chemical reaction between functional moieties in the plasma polymer coatings and the epoxy resin. Only the samples with 1,3-diaminopropane and allylamine plasma polymer coated silica fillers showed heat of reaction peaks when they were mixed with biphenyl epoxy resin only, while these samples as well as the samples with 1,3-diaminopropane, allylamine and pyrrole plasma polymer coated silica fillers exhibited heat of reaction peaks when mixed with both biphenyl epoxy and phenol novolac (curing agent).

• Bulletin of the Korean Chemical Society
• /
• v.18 no.11
• /
• pp.1199-1203
• /
• 1997

The investigation of cure kinetics of biphenyl epoxy (4,4-diglycidyloxy-3,3,5,5-tetramethyl biphenyl)-xylok resin system with four different catalysts was performed by differential scanning calorimeter using an isothermal approach. All kinetic parameters of the curing reaction including the reaction order, activation energy and rate constant were calculated and reported. The results indicate that the curing reaction of the formulations using triphenylphosphine (TPP) and 1-benzyl-2-methylimidazole (1B2MI) as a catalyst proceeds through a first order kinetic mechanism, whereas that of the formulations using diazabicyloundecene (DBU) and tetraphenyl phosphonium tetraphenyl borate (TPP-TPB) proceeds by an autocatalytic kinetic mechanism. To describe the cure reaction in the latter stage, we have used the semiempirical relationship proposed by Chern and Poehlein. By combining an nth order kinetic model or an autocatalytic model with a diffusion factor, it is possible to predict the cure kinetics of each catalytic system over the whole range of conversion.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2006.05b
• /
• pp.545-548
• /
• 2006

This study has been carried out to examine the properties of concrete according to replacement ratio and curing method of fly ash, in order to increase utilization of it. As the result of experiments, the 7 days of early age strength presented around 20MPa, up to 20% of replacement ratio, which is almost the same strength as non-replacement. However, when the replacement ratio was 30%, the strength was decreased to 16MPa, as 20% reduction compared to the non-replacement condition. In 365 days of long term aging, the strength was 5% higher, up to 20% of the replacement ratio, due to the pozzolanic reaction of fly ash. When the replacement ratio was 30%, it presented similar strength development as the non-replacement condition. Steam curing and autoclave curing increased the short age strength, regardless of the replacement ratio of fly ash; however, they don't have an effect on increasing the 365 days of long term strength. Water curing showed high strength development after 28 days, 51.81MPa, which is around 30% higher than air curing, 38.9MPa, steam curing, 38.6MPa, and autoclave curing, 39MPa. Therefore, water curing was examined as one of the very effective curing methods for developing long term strength of concrete.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2019.11a
• /
• pp.73-74
• /
• 2019

In order to examine the chemical stabilization through DCG curing of cement paste exposed to high temperature environment, we produced a sample of 40% W/C cement paste and heated it for 180 minutes under the heating temperature of $800^{\circ}C$. The DCG curing time was 6, Three time conditions were divided into 12 and 18 hours. As a result of XRD analysis, Calcite ($CaCO_3$) was found in Theta 29.4, 40, and 46.5o. As the curing time increased, the peak of Calcite also increased, which is due to the increased reaction time with DCG. Therefore, Calcite produced through DCG curing seems to have stabilized chemically by filling the pores generated by heating.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.26 no.6
• /
• pp.28-33
• /
• 2022

In this study, the curing characteristics of commonly used Hydroxyl terminated polybutadiene(HTPB)-based solid propellant according to the curing temperature and Equivalent ratio change were investigated. In addition, the effect of curing reaction according to their ratio and content in the Triphenyl bismuth(TPB), Maleic anhydride(MA) and Magnesium oxide(MgO) catalyst systems was confirmed. Finally, moisture was added for each propellant mixing process to check the effect of moisture on propellant curing.

• Applied Chemistry for Engineering
• /
• v.5 no.4
• /
• pp.743-747
• /
• 1994

The catalytic effects of carboxylic acid and dibutyltin dilaurate(DBTL) on the curing rate of acrylic polyol with isocyanate prepolymer were investigated. In this work reaction of a biuret type aliphatic isocyanate with acrylic polyol follows the second order reaction in the thin film state. Carboxylic acid of acrylic polyol has a strong catalytic effect on the isocyanate groups and influences greatly on curing rate, also DBTL is more effective catalysis on acrylic polyol without carboxylic acid than with carboxylic acid.

• Korean Chemical Engineering Research
• /
• v.46 no.1
• /
• pp.200-204
• /
• 2008

The curing kinetics of diglycidyl ether of bisphenol F (DGEBF) with an asymmetric cycloaliphatic amine curing agent were examined by thermal analysis in both isothermal and dynamic curing conditions. From the residual curing of the samples partially cured in isothermal condition and from the dynamic curing with various heating rates, it was found that there exist two kinds of reactions such as at low temperature and at high temperature regions. It was thus also found that the cure parameters obtained from the isothermal curing kinetic model hardly estimate experimental results for a degree of cure larger than 0.6. The activation energies and frequency factors of these two kinds of reactions were obtained from the dynamic curing experiments with various heating rates. From the curing analysis, it was verified that the total cure kinetics for low degrees of cure is dominated by the cure reaction in the low temperature region.

• Journal of the Architectural Institute of Korea Structure & Construction
• /
• v.33 no.12
• /
• pp.63-70
• /
• 2017

When industrial by-products like slag and fly ash are using in concrete with cement, it improves strength and durability against external deterioration factors by densifying the structure through potential hydraulic and pozzolanic reaction. But it has been pointed out that high dependence on the quality variation and the curing condition using a admixure material for concrete. In this study, the characteristics of internal micropore structure according to curing condition were analyzed for pastes and mortar specimens under using blast furnace slag powder. As a result, the variation of compressive strength and the internal microstructure were observed according to curing conditions by binder type. Particularly, using blast furnace slag powder, decrease in compressive strength were clearly observed in indoor and carbonation curing compared with water curing. The pore structure analysis also clearly observed the decrease of the gel pore existing in the CSH hydrate layer and the increase of the capillary pore in indoor and carbonation curing compared with water curing condition.