• Title/Summary/Keyword: Cure property

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Cure Properties in Photopolymer for Stereolithography according to Variance of Laser Beam Size (레이저빔 크기변화에 따른 광조형수지의 경화특성)

  • 이은덕;심재형;백인환
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.2
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    • pp.76-84
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    • 2003
  • Stereolithography is the technique using a laser beam to cure a liquid resin, a photopolymer, with three dimensional computer-aided design (CAD) data. The build parameters of stereolithography such as beam size, scan velocity. hatch spacing, layer thickness and etc. are determined by the accuracy of prototype, the build time and the cured properties of the resin. In particular, beam size is important processing parameter fur the other parameters. Therefore, this study observed the cured property to beam size. For this purpose, according to hatch spacing and beam size, the cure width and depth were measured on single cured line. Also, the cure width and depth were measured at single cured layer As a result of experiments. cure depth which varied from 0.23mm to 0.34mm was directly proportioned to beam radius. on the other hand, cure width which varied from 0.42mm to 1.07mm was inversely proportioned to beam radius. Surface roughness varied from 1.12 to 2.23 m for the ratio of hatch spacing to beam radius.

Effects of Carbon Black Content and Vulcanization Type on Cure Characteristics and Dynamic Mechanical Property of Styrene-Butadiene Rubber Compound

  • Changwoon Nah;Kim, Wan-Doo;Lee, Seag
    • Macromolecular Research
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    • v.9 no.3
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    • pp.157-163
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    • 2001
  • The influences of carbon black loading and cure type on the cure characteristics including kinetics and dynamic mechanical properties were investigated for a styrene-butadiene rubber (SBR). The rate constants of accelerated sulfur vulcanization reaction at three different temperatures were determined using a cure rheometer, and they were compared with those from the direct measurement of sulfur concentration. The strain softening behavior under dynamic deformation, known as the Payne effect was also discussed depending on the carbon black loading and cure type.

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Cure Characteristics, Mechanical Property and Ozone Resistance of Natural Rubber/Bromo Isobutylene Isoprene Rubber Blend

  • Choi, Im Cheol;Lee, Won-Ki;Park, Chan Young
    • Elastomers and Composites
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    • v.53 no.3
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    • pp.168-174
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    • 2018
  • Natural rubber (NR) and bromo-isobutylene-isoprene rubber (BIIR) were compounded with other formulation chemicals through polymer blending via a mechanical mixing method. After rubber vulcanization by hot-press compression molding, the cure characteristics, mechanical properties, and ozone resistance of the NR/BIIR blends were measured. As the BIIR content increased, the maximum torque of the blends decreased, while the optimum cure time and scorch time tended to increase. Furthermore, the hardness of the blends increased with increasing BIIR content, reaching the maximum value at 75 wt% BIIR, and decreased with a further increase in the BIIR loading. The tensile strength and elongation at break decreased with an increase in the BIIR content, reaching the minimum value at 75 wt% BIIR, and increased with a further increase in the BIIR content. In the ozone resistance test, cracks were not generated when the BIIR content was more than 75 wt%.

Dielectric Cure Monitoring for Glass/Polyester Prepreg Composites (유리섬유/폴리에스터 복합재료를 위한 유전 경화 모니터링)

  • Kim, Hyoung-Geun;Kim, Jin-Kook;Lee, Dai-Gil
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.797-803
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    • 2001
  • The on-line cure monitoring of fiber reinforced thermosetting resin matrix composite material was performed for the better quality and productivity during manufacturing. Since the dissipation factor measured by dielectrometry method is dependent on the degree of cure and temperature of resin, in this study, a new method to obtain the degree of cure during on-line cure monitoring for glass/polyester composites was developed by employing a combination function of the temperature and the dissipation factor. Two sensor signals from a K-type thermocouple and an interdigitated dielectric sensor were processed during curing process under various cure cycles. The DSC (Differential Scanning Calorimetry) data was also used for the reference of degree of cure.

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Study of Cure Properties in Photopolymer for Stereolithography using Various Laser Bean Size (레이저빔 직경변화에 대한 광경화성 수지의 경화특성 고찰)

  • 이은덕;김준안;백인환
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2001.04a
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    • pp.1089-1092
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    • 2001
  • In the stereolithography process, build parameters are laser power, scan velocity, scan width, bean diameter, layer thickness and so on. These values are determined according to product accuracy and build time. Build time can be reduced by improving of scan velocity, laser power, layer thickness, hatching space and so on. But variation of these parameters influence part accuracy, surface roughness, strength. This paper observed cure properties in various beam diameter. In order to examine these, relationships of scan velocity and cure depth, scan velocity and cure width according to various beam diameter in one scan line are measured. And cure thickness is measured according to beam diameter and scan velocity in scan surface of one layer. For reduction of build time, beam diameter and scan velocity is proposed in stereolithography process.

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Effect of the Laser Beam Size on the Cure Properties of a Photopolymer in Stereolithography

  • Sim, Jae-Hyung;Lee, Eun-Dok;Kweon, Hyeog-Jun
    • International Journal of Precision Engineering and Manufacturing
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    • v.8 no.4
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    • pp.50-55
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    • 2007
  • Stereolithography (SLA) is a technique using a laser beam to cure a photopolymer liquid resin with three-dimensional computer-aided design (CAD) data, The accuracy of the prototype, the build time, and the cured properties of the resins are controlled by the SLA process parameters such as the size of the laser beam, scan velocity, hatch spacing, and layer thickness, In particular, the size of the laser beam is the most important parameter in SLA, This study investigated the curing properties of photopolymers as a function of the laser beam size, The cure width and depth were measured either on a single cure line or at a single cure layer for various hatch spacings and laser beam sizes, The cure depth ranged from 0.23 to 0.34 mm and was directly proportional to the beam radius, whereas the cure width ranged from 0.42 to 1.07 mm and was inversely proportional to the beam radius, The resulting surface roughness ranged from 1.12 to $2.23{\mu}m$ for a ratio of hatch spacing to beam radius in the range 0.5-2.0 at a beam radius of 0.17 mm and a scan velocity of 125 mm/sec.

Study on Cure Monitoring for Epoxy Resin Using Fiber Optic Sensor System (광섬유 센서를 이용한 에폭시 수지의 경화도 측정)

  • Kim, J.B.;Byun, J.H.;Lee, C.H.;Lee, S.K.;Um, M.K.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.04a
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    • pp.37-41
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    • 2005
  • The curing of thermoset resin is accompanied with the changes in chemical and physical properties. The cure monitoring techniques can be designed by tracing these property changes. This paper presents the cure monitoring technique with fiber optic sensors to detect the change of refractive index during the polymerization process of engineering epoxy resin. The fiber optic sensor system was developed to measure the reflection coefficient at the interface between the fiber optic and the resin. The correlation between the sensor output and the degree of cure was performed following Lorentz-Lorenz law. The isothermal data from the sensors are compared with the data from differential scanning calorimeter.

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Interpretation on the Four-Properties of the Traditional Korean Drugs by the Effects on the Autonomic Nervous System (자율신경계를 통한 한약약성의 해석)

  • Kim, Ho-Cheol;Park, Chan-Woong
    • The Journal of Korean Medicine
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    • v.18 no.2
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    • pp.148-154
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    • 1997
  • In the pharmacology of traditional Korean medicine, each drug has its own specific characters. The different characters of drugs are employed to treat diseases, rectify the hyperactivity or hypoactivity of yin or yang, and help the body restore its normal physiological functions, consequently curing the diseases and restoring health. The various characters and functions of these drugs concerning medical treatment include drugs' properties, flavours, actions of lifting, lowering, floating and sinking, channel tropism, toxicity, etc. Among these theories, theory of properties and flavours of drugs provides the basis for drug analysis and application. 'Property' refers to the cold, hot, warm or cool nature of a drug. These properties of drugs are so sorted out according to the different actions of the drugs on the human body and thier therapeutic effects. Drugs which cure heat syndrome(yang syndrome) have a cold or cool property, whereas drugs which cure cold syndrome (yin syndrome) have hot or warm property Drugs of cold and cool-natured and drugs of warm and hot natures are of opposite properties. A cold-natured drug is different from a cool-natured on only in degree, and so is a warm-natured drug from a hot-natured drug. Most of the cool- or cold- natured drugs have the effects of clearing heat, purging fire, removing toxic substances, and nourishing yin, and are uese to cure heat syndromes. On the contrary, drugs of warm or hot nature usually have the effects of dispersing cold, warming up the interior, supporting yang, and treating collapse, and are therefore used to treat cold syndromes. We thought that the property of drug may be related to the autonomic nervous system in western medicine. In other words, drugs of warm or hot nature increase heart rate or acts like sympathomimetics, and drugs of cool or cold nature decrease heart rate or acts like para sympathomimetics . According to this hypothesis, we administrated some drugs to isolated rat right atrium in magnus tube. But there is no correlation between 'property' in traditional Korean medicine and autonomic nervous system in western medicine.

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Effect of Various Cross-linking Types on the Physical Properties in Carbon Black-Filled Natural Rubber Compound (천연고무 배합물에서 가교형태 변화가 물성에 미치는 영향)

  • Park, Byung-Ho;Jung, Il-Gouen;Park, Sung-Soo
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.63-70
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    • 2001
  • The objective of this study was to investigate the effect of cure type on the processing and physical properties under conditions of similar stress-strain properties. On the carbon black filled natural rubber(NR) based compound, the induction time decreased, but the cure rate became fast with increasing loading of sulfur donor agent. Tensile strength was little affected on the curing type. However, elongation generally decreased with increasing accelerator. Effect of cure type on the blow-out properties was followings: CV

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A Study of the Effect of Degree of Cure on the Physical Properties of Rubber Compounds (가교정도에 따른 고무복합체의 물리적 특성에 관한 연구)

  • Kim, Hyeon-Jae;Kaang, Shin-Young;Nah, Chang-Woon
    • Elastomers and Composites
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    • v.33 no.4
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    • pp.281-289
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    • 1998
  • Tensile properties including Young's modulus and tear strength were measured for four different rubber compounds; natural rubber(NR), styrene-butadiene copolymer(SBR), ethylene-propylene diene monomer (EPDM), and brominated isobutylene-p-methyl-styrene copolymer(BIMS) as a function of temperature and degree of cure. To see the effect of over cure, a measurement was made of the tensile strength and swelling behavior of the over-cured rubber compounds. Young's modulus, E, was found to have linear dependency on the degree of cure for all rubber compounds. EPDM and BIMS showed the highest and lowest slopes, respectively. The slope of NR and SBR lay between EPDM and BIMS. Tear strength, Gc, decreased in the order of NR>BIMS>SBR>EPDM. As the cure time was extended the degree of cure of NR and SBR decreased, while that of BIMS increased. EPDM showed little change in the degree of cure.

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