• 공업화학
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• 제7권5호
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• pp.963-969
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• 1996

에폭시 수지를 접착제의 base resin으로 이용하기 위해 DGEBA/dicy계의 경화특성을 조사하였다. dicy는 상온에서 저장안정성이 우수하여 일액형 접착제의 경화제로서 유용하다. 그러나 고온에서 경화시 열분해될 우려가 있으므로 경화온도를 낮추기 위해 diuron을 경화촉진제로 사용하였다. Epoxy/dicy계에서 dicy의 사용량이 증가함에 따라 경화반응열이 증가하였으며, 경화 후 수지의 유리전이온도($T_g$)도 증가하는 것으로 관찰되었다. Diuron을 경화촉진제로 사용함으로써 약 $40^{\circ}C$정도 낮은 온도에서 경화반응이 진행되었으며, 수지의 유리전이온도는 감소되었다. 경화반응의 속도론적 고찰은 Kamal이 제안한 자촉매반응의 모델식으로 해석하였으며, diuron의 경화촉진 효과를 확인할 수 있었다.

• 한국산학기술학회논문지
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• 제10권7호
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• pp.1661-1667
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• 2009

TGA 열분석법을 이용하여 LCD 백라이트 램프 홀더용으로 사용되는 실리콘 고무성형품샘플에 대하여 서로 다른 몇 가지 온도에서의 등온 후가교 특성을 연구하였다. 특히 실제 사용 환경에서의 내열조건과 관련된 후가교 특성 및 적정 후가교 조건에 대하여 촛점을 맞추어 연구하였고 시간-온도중첩원리를 응용하는 촉진 실험법의 적용 가능성을 알아보았다. LCD 램프홀더용의 실리콘 재료의 실제 사용 환경을 고려할 때, 휘발성 물질의 배출에 의한 중량감소가 처음 시작되는 온도인 Ti가 가장 중요한 고려 요인이며, 이를 고려하여 도출되는 후가교 조건은 $250^{\circ}C$, 2시간이 적절한 것으로 생각되었다. 시간-온도 중첩원리와 실험적으로 결정된 이동인자는 Arrhenius식을 잘 만족함을 보여 주었으며 이로부터 후가교과정은 활성화에너지 108.25kJ/mol의 값을 가지는 단일 메커니즘으로 진행됨을 알 수 있었다.

• 한국의류산업학회지
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• 제7권4호
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• pp.394-400
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• 2005

The purpose of this study is to investigate historical background which uses and characteristics of Korean traditional incense and how to use it in clothes. Incense was at first introduced to Korea in the period of King Nulji of Shilla dynasty. First introduction to this nation, incense was already regarded as divine. It was then developed with five main uses, tribute, fragrance, purification, anti bacteria, and cure. Incense used by fragrance and anti-bacteria in clothes. It make emit a fragrance from the clothes or decorate clothes with ornaments. Incense was also to prevent clothes or books from being damaged by insects and maintain them over a long period. It used one of the factor for beauty of costume.

• JSTS:Journal of Semiconductor Technology and Science
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• 제3권3호
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• pp.122-131
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• 2003

In this study, some characteristics of conductive and non-conductive adhesive inter-connections are derived, based on data from literature and own projects. Assembly of flip chip on flex is taken as a carrier. Potential failure mechanisms of adhesive interconnections reported in literature are reviewed. Some methods that can be used to evaluate the quality of adhesive interconnections and to evaluate their aging behavior are given. Possible finite element simulation approaches are introduced and the required critical materials properties are summarized. Response to temperature and moisture, resistance to reflow soldering and resistance to rapid change in temperature and humidity are elaborated. The effect of post cure during accelerated testing is discussed. This study shows that only a combined approach using finite element simulations, and use of appropriate experimental evaluation methods can result in revealing, understanding and quantifying the complex degradation mechanisms of adhesive interconnections during aging.

• Elastomers and Composites
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• 제50권3호
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• pp.159-166
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• 2015

Silica which is used for reinforcing filler in tire industry is widely known as eco-friendly material exerting $CO_2$ reduction effect through decrease of rolling resistance and improvement of wet grip. Generally silica is classified as a highly polar filler because it contains a large number of silanol (Si-OH) group on its surface. And also silica gives a lower reinforcing effect than carbon black due to its poorer rubber-filler interaction. Therefore silica is treated with silane coupling agent or activator, then following the conventional rubber blend method, vulcanized sheets were prepared using a hot press, and cure characteristics, mechanical properties and abrasion resistance of the test specimens were investigated. It was found that with an increase in the silane coupling agent content the tensile strength, 300% modulus and abrasion resistance increased while Mooney viscosity decreased and crosslink density slightly increased with an increase of activator.

• Composites Research
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• 제23권4호
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• pp.21-27
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• 2010

대부분의 구조물 파괴는 피로에 의해서 발생한다. 따라서 지금까지 모드 혼합비가 피로 특성에 어떤 영향을 미치는지에 대한 수많은 연구가 수행되어 오고 있다. 하지만 대부분의 연구가 금속/금속 계면이나 복합재료 층간 분리에 관한 연구이다. 따라서 본 연구에서는 이종재료인 복합재료/금속 계면의 피로 특성에 대한 기초 자료를 얻고자 하였다. 이를 위하여 복합재료와 탄소강을 동시 경화법을 이용하여 접합한 SLB(single leg bending) 시편을 이용하여 피로 실험을 수행하였다. 특히, 피로 특성에 모드 혼합비$(G_{II}/G_T)$가 어떠한 영향을 미치는지에 대해 알아보고자 하였다. 전체적으로 모드 II 하중 성분 이 많을수록 균열진전속도가 빨라진다는 결과를 얻었다.

• Restorative Dentistry and Endodontics
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• 제25권1호
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• pp.123-132
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• 2000

To overcome problems of conventional glass ionomers, resin components have been added to glass ionomers. On a continuum between glass ionomers and composites are a variety of blends, employing different proportions of acid-base and free radical reactions to bring about cure. Popular groups defined between the ends are resin-modified glass-ionomers(RMGIs), polyacid-modified composite resins(Compomers) and ionomer modified resins. These groups show different clinical properties, and in selecting these materials for a restoration, one should sufficiently understand these different setting properties. In this study, some difference in the setting characteristics of different groups of hybrid ionomers were examined. Two RMGIs (Fuji2 LC,GC / Vitremer, 3M), three Compomers (Dyract AP, Dentsply / F2000, 3M / Elan, Kerr) were involved in this study. The identification of the setting characteristics of different groups was achieved by a two-stage study. First, thermal analysis was performed by a differential scanning calorimeter, and then the hardness of each group at different depth and time were measured by a micro-hardness tester. Thermal analysis was performed to identify the inorganic filler content and to record the heat change during setting process. The setting process was progressed for each material by chemical set mode and light-cured mode. In the hardness test, samples of materials were prepared with a 6mm-diameter metal ring, and the hardness was measured at the top, and 1mm, 2.5mm, 4mm below at just after a 40 second-cure, and after 10 minutes, 24 hours, and 7 days. Statistical analysis was performed by Mann-Whitney rank sum test to assess significant differences between set modes and types of materials, and by ANOVA and T-test to evaluate the statistical meanings of data at different times and depths of each materials. Followings are findings and conclusions derived from this study. Thermal analysis; 1. Compomers show no evidence of chemical setting while RMGIs exhibit heat output during the process of chemical setting. 2. Heat of cure of RMGIs exceed Compomers. 3. The net heat output of RMGIs through light-cured mode is higher than through chemically set mode. Hardness test; 1. Initial hardness of RMGIs immediately after light cure is relatively low, but the hardness increases as time goes by. On the contrary, Comomers do not show evident increase of the hardness following time. 2. Compomers show a marked decrease of setting degree as the depth of the material increases. In RMGIs, the setting degree at different depths does not significantly differ.

• Elastomers and Composites
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• 제36권1호
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• pp.37-43
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• 2001

실리카와 카본블랙으로 보강된 SBR 배합물의 가황 특성과 bound rubber 함량 그리고 가황물의 물성에 보강제의 조성비가 미치는 영향을 연구하였다. 고무 배합물의 보강제 총 함량은 80.0 phr 이다. Bound rubber 함량은 실리카 함랑비가 증가할수록 증가하였고 점도 역시 증가하였는데, 특히 실리카 함량이 60.0 phr 이상일 때는 점도의 증가폭이 두드러지게 높아졌다. 가황시간은 실리카 함량이 증가할수록 느려졌고 가황 속도도 느려졌다. 실리카 함량비가 증가할수록 델타 토크가 증가함에도 불구하고 모둘러스는 감소하는 경향을 보였다. $60^{\circ}C$에서의 tan ${\delta}$ 값은 실리카 함량이 증가할수록 감소하였다.

• Elastomers and Composites
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• 제52권2호
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• pp.105-113
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• 2017

The curing behavior, mechanical properties, hot-air aging resistance, abrasion properties,thermal properties, etc., of EVM/EPM/APP (ammonium polyphosphate)/DPER (dipentaerythritol)/EG (expandable graphite) and EVM/EPM/ATH (aluminium trihydroxide) flame retarding systems in ethylene vinyl acetate rubber (EVM) blends with EPM (ethylene propylene rubber) were sequentially examined. For both flame retarding systems, the torque values increased with the content of EPM rubber and with the vulcanization time. As the content of EPM rubber increased, the scorch time became shorter, whereas the optimum cure time followed an increasing trend. For the EVM/EPM/APP/DPER/EG flameretarding system, as the content of EPM rubber increased, the hardness did not change,whereas the tensile strength and elongation at break decreased. A hot-air aging resistance test at $150^{\circ}C$ showed that the heat resistance decreased with the EPM content regardless of the kinds and contents of flame retardants. As the EPM content increased, the abrasion rate became higher and the abrasion resistance of the EVM/EPM/APP/DPER/EG flame retarding systems exceeded that of the EVM/EPM/ATH flame retarding counterparts. In comparison with the EVM/EPM/ATH flame retarding systems, the thermal stability of the EVM/EPM/APP/DPER/EG flame retarding system showed an increasing tendency.

• 근관절건강학회지
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• 제2권2호
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• pp.168-184
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• 1995

This deductive-survey study was undertaken in order to examine if there were relationship between causal perceptions, expectation for the cure and compliance. The sampling method was a non-probability, purposive sampling technique. The participants of this study was 195 volunteers 1) who have been diagnosed as having chronic arthritis and 2) who were at the rheumatis center of one university hospital in Seoul between September 18th to September 25th 1989. This instruments used for this study were the compliance scale developed by Choi and causal perception scale developed by the researcher. Analysis of data was done using pass analysis, Pearson correlation coefficient. The result of study were as follow : Hypothesis 1 : "It's correlated that causal perception, expectation for cure and compliance" was accepted. (F=4.85, p< .05) Hypothesis 2 : "It's correlated that causal perception, expectation for cure and with depression" was partially accepted. Total age group-worry and anxiety (r=.1580, p<.001) After 40-function of immunity (r=.1731, p<.05) warry and anxiety (r=.1730, p<.001). In the relationship between general characteristics and the variables, age group correlated with compliance and causal perception.