• Title/Summary/Keyword: CuCa 2at%

Search Result 607, Processing Time 0.03 seconds

Mineralogy and Geochemistry of Green-colored Cr-bearing Sericite from Hydrothermal Alteration Zone of the Narim Gold Deposit, Korea (나림 금광상의 열수변질대에서 산출되는 녹색크롬-견운모의 광물학적 및 지구화학적 특징)

  • Lee, Hyun Koo;Lee, Chan Hee
    • Economic and Environmental Geology
    • /
    • v.30 no.4
    • /
    • pp.279-289
    • /
    • 1997
  • Dark to pale green-colored, Cr-bearing sericites from hydrothermal alteration zone of the Narim gold deposit were investigated mineralogically and geochemically. The alteration zone is composed mineralogically of quartz, carbonate minerals and green sericite with minor amounts of chlorite, barite and sulfide minerals (pyrite, sphalerite, galena). The zone is enriched in As (967 to 1520 ppm), Cu (31 to 289 ppm), Ni (1027 to 1205 ppm), Pb (0.20 to 1.24 wt.%) and Zn (1.03 to 1.07 wt. %) compared with fresh rocks such as granitic gneiss, porphyritic biotite granite and basic dyke. The Cr, probably the chromophore element, is highly enriched in the alteration zone (1140 to 1500 ppm), host granitic gneiss (1200 ppm) and porphyritic biotite granite (1200 ppm). Occurrence and grain size of sericite are diverse, but most of the Cr-bearing sericites (150 to $200{\mu}m$ long and 20 to $30{\mu}m$ wide) occur along the boundaries between ore veins and host rocks (especially basic dyke and granitic gneiss). X-ray diffraction data of the sericite show its monoclinic form with unit-cell parameters of $a=5.202{\AA}$, $b=8.994{\AA}$, $c=20.103{\AA}$, ${\beta}=95.746^{\circ}$ and $V=935.83{\AA}^3$, which are similar with the normal 2M1-type muscovite. Representative chemical formula of the sericite is ($K_{1.54}Ca_{0.03}Na_{0.01}$)($Al_{3.42}Mg_{0.38}Cr_{0.14}Fe_{0.06}V_{0.02}$)($Si_{6.69}Al_{1.31}$)$O_{20}(OH)_4$. The Cr content increases with decrease of the octahedral Al content, and ranges from 0.36 to 2.58 wt.%. DTA and TG curves of the sericite show endothermic peaks at $342^{\circ}$ to $510^{\circ}$, $716^{\circ}$ to $853^{\circ}$ and $1021^{\circ}C$, which are due to the expulsion of hydroxyl group. The total weight loss by heating is measured to be about 8.8 wt. %, especially at $730^{\circ}C$. Infrared absorption experiments of the sericite show broad absorption band due to the O-H bond stretching vibration near the $3625cm^{-1}$, coupled with the 825 and $750cm^{-1}$ doublet. The vibration bands related with the H-O-Al and Si-O-Al bonds occur at $1030cm^{-1}$ and 500 to $700cm^{-1}$, respectively. Based on paragonite content of the sericite, the formation temperature of the Narim gold deposit is calculated to be $220{\pm}10^{\circ}C$.

  • PDF

Effect of Dietary Supplementation of Dried-Citrus Pulp and Wheat Bran on Growth and Meat Quality in Horses (건조감귤박 및 소맥피를 급여한 말의 성장과 육질에 미치는 영향)

  • Chae, Hyun-Seok;Kim, Nam-Young;Cho, In-Chul;Cho, Sang-Rae;Cho, Won-Mo;Park, Yong-Sang;Oh, Shin-Ae;Jang, Aera;Seong, Pil-Nam;Ko, Moon-Suck
    • Journal of Animal Science and Technology
    • /
    • v.55 no.3
    • /
    • pp.219-227
    • /
    • 2013
  • This study was conducted to elucidate the characteristics of equine meat traits and to evaluate the utilization of dried-citrus pulp abundantly produced in Jeju Island as feed ingredient in the diet of finished meat horses. Treatment groups consisted of wheat bran (A) and the dried-pellet mixture of citrus pulp (20%) and wheat bran (80%) (B). Feeding of agricultural by-products were 2 times in a day at the level of 1.5% of body weights. Water and dried-grass forage was not restricted. The average daily gain was similar in both groups. Feed conversion of treatment B showed lower level than that of A. Carcass rate of B was relatively lower than that of A, but meat yield grade of B was higher than that of A. For meat color traits, $L^*$ of B was lighter than that of A, and $b^*$ of group B was lower than that of group A. From the analysis of physical characteristics of equine meats, shearing force had decreased in the treatment B but the levels of drip loss and water holding cavity had increased in the treatment B compared to A. The level of crude fat is lower in the treatment B than the treatment A. For the mineral contents, the treatment B showed higher levels of Ca, K, Mg, Cu and Mn than that of A. For the fatty acid contents, the treatment B showed increased levels of stearic acid, oleic acid, eicosenoic acid, and arachidonic acid compared to A. Consequently, these results suggested that dried-citrus pulp might be utilized as replacement material for equine forage. Please rewrite the whole abstract and should include all required information. Before resubmission, please check it again from a native colleague in your group.

Petrology of Host Body of Feldspar Deposits in Jechon Ganites (장석광상 모암인 제천반상화강암의 암석학적 특성)

  • Lee, Han-Yeang;Kim, Dai-Oap;Park, Joong-Kwon
    • Journal of the Korean earth science society
    • /
    • v.22 no.5
    • /
    • pp.405-414
    • /
    • 2001
  • Jecheon granite can be divided into two types; porphyritic granite (K-feldspar megacryst bearing) and medium-grained biotite granite. Porphyritic granite, host body of feldspar deposits, is 8${\sim}$11 km in diameter and about 80 $km^{2}$ in area. It mainly contains K-feldspar, plagioclase, biotite and quartz, and magnetite, zircon, sphene and apatite are accessary minerals. Enclosed minerals in K-feldspar megacryst with 3${\sim}$10 cm in diameter are hornblende, plagioclase, quartz, magnetite, apatite, sphene and zircon. Mafic enclaves mainly consisting of hornblende, plagioclase and quartz are frequently observed in porphrytic granite. Medium-grained biotite granite consists of K-feldspar, plagioclase, biotite and hornblende as main, and hematite, muscovite, apatite and zircon as accessary minerals. Core and rim An contents of plagioclase from porphyritic granite, medium biotite granite, K-feldspar megacryst, and mafic enclave are 36 and 21, 40 and 32, 37 and 32, and 43 and 36, respectively. $X_{Fe}$ values of hornblende are 0.57 at biotite granite, 0.51 at K-feldspar mehacryst and 0.45 at mafic enclave. $X_{Fe}$ values of biotite and hornblende are homogeneous without chemical zonation. K-feldspar megacryst shows end member of pure composition with exsolved thin lamellar pure albites. Characteristics of mineral compositions and petrography indicate porphyritic granite is igneous origin and medium-grained biotite granite comes from the same source of magma; biotite granite is initiated to solidly and from residual melt porphyritic granite can be formed. Possibly K-feldspar megacrysts are formde under H$_{2}$O undersaturation condition and near K-feldspar solidus curve temperature; growth rate is faster than nucleation rate. Mafic enclaves are thought to be mingled mafic magma in felsic magma, which is formed from compositional stratigraphy. Estimated equilibrium temperature and pressure for medium-grained biotite granite are about $800^{\circ}C$ and 4.83${\sim}$5.27 Kb, respectively.

  • PDF

Purification and Characterization of Endo-polygalacturonase Produced by Plant Pathogenic fungus, Botrytis cinerea (식물 병원진균 Botrytis cinerea가 생산하는 Endo-polygalacturonase의 순수정제와 특성)

  • Kim, Byung-Young;Lee, Tae-Ho;Rha, Eu-Gene;Chung, Young-Ryun;Lee, Chang-Won;Kim, Jae-Won
    • The Korean Journal of Mycology
    • /
    • v.25 no.4 s.83
    • /
    • pp.330-339
    • /
    • 1997
  • Botrytis cinerea T91-1 has shown to produce at least four different polygalacturonases in a liquid medium containing citrus pectin as a carbon source. One of the enzymes, its molecular weight was estimated as 37 kDa by denatured polyacrylamide gel electrophoresis, was purified by a series of procedures including acetone precipitation, ion exchange, heparin affinity, and reverse phase column chromatographies. By viscometric analysis, the enzyme was revealed as an endo-polygalacturonase. The enzyme activity was inhibited by divalent cations such as $Ca^{2+}$, $Co^{2+}$, and $Cu^{2+}$. Km and Vmax for polygalacturonic acid hydrolysis were 0.33 mg/ml and 28.6 nM/min, respectively. The optimum temperature for enzymatic activity was $55^{\circ}C$ and the enzyme showed optimal pH values between 4.0 and 4.5. The enzyme was stable up to 12 hours in the range of pH 4 to 7 and at the temperature below $30^{\circ}C$. Amino acid sequence from N-terminal up to 6 amino acids determined by Edman degradation showed little homology with polygalacturonases from fungi and plants.

  • PDF

Study on Chemical Characterization of PM2.5 based on Long-term Database (1990 ~ 2012) and Development of Chemical Species Profiles During Haze Days and Asian Dust Days in Yongin-Suwon Area (장기간 (1990 ~ 2012) 측정자료를 이용한 용인-수원지역에서의 PM2.5의 화학적 특성연구 및 헤이즈와 황사 현상 시 화학성분별 질량분율표의 개발)

  • Lim, Hyoji;Lee, Tae-Jung;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.31 no.3
    • /
    • pp.223-238
    • /
    • 2015
  • The $PM_{2.1}$ was collected by LVCI (low volume cascade impactor) during Group-A Period (September 1990 to December 2012) and the $PM_{2.5}$ was collected by HVAS (high volume air sampler) during Group-B Period (September 2009 to April 2012) at Kyung Hee University, Global Campus located on the boarder of Yongin and Suwon. The 8 water-soluble ions ($Na^+$, $NH_4{^+}$, $K^+$, $Mg^{2+}$, $Ca^{2+}$, $Cl^-$, $ NO_3{^-}$, and $SO_4{^{2-}}$) were analyzed by IC, and the 14 inorganic elements (Al, Mn, Si, Fe, Cu, Pb, Cr, Ni, V, Cd, Ba, Zn, Ti, Ag) were analyzed by XRF and ICP-AES after performing proper pre-treatments of each sample filter. The average total mass fractions of $SO_4{^{2-}}$, $NO_3{^-}$, and $NH_4{^+}$+ to $PM_{2.5}$ samples during Group-B Period were 0.39 in normal days, 0.44 in haze days, and 0.27 in Asian dust days, respectively; however, the average total mass fractions of Al, Fe, and Si to $PM_{2.5}$ mass were 0.043 in normal days, 0.021 in haze days, and 0.036 in Asian dust days, respectively. Especially the concentration of Pb was significantly decreased during Group-B Period rather than during Group-A Period, while Cr and Ni was increased during Group-B Period. In this study, we intensively compared the annual and seasonal patterns of major chemical species among normal days, haze days, and Asian dust days. Further we developed mass fraction profiles by collecting episode cases of haze days and Asian dust days, which were consisting of 22 chemical species. Those profiles are considered to be useful when applying various receptor models and establishing air quality management plans near future.

Relationship of mineral elements in sheep grazing in the highland agro-ecosystem

  • Fan, Qingshan;Wang, Zhaofeng;Chang, Shenghua;Peng, Zechen;Wanapat, Metha;Bowatte, Saman;Hou, Fujiang
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.33 no.1
    • /
    • pp.44-52
    • /
    • 2020
  • Objective: Minerals are one of the important nutrients for supporting the growth of sheep grazing in the highland, northwest of China. The experiment was conducted to investigate the relationship of both macro and micro minerals in sheep grazing in the highlands of six districts located in the Qilian Mountain of China. Methods: Samples of herbage (n = 240) and soil (n = 240) were collected at random in a "W" shape across the area designated for harvesting from 24 farms, where the sheep commonly graze in October (winter) for mineral analyses. In addition, serum samples were taken via jugular vein from 20 sheep per farm from 24 farms (n = 480 samples in total) for serum minerals analyses. Mean values of macro and micro minerals were statistically compared among districts and the correlations among soil-plant-animal were statistically analyzed and correlations were regressed, as well. Results: The results revealed that there were variations for both macro and micro minerals among districts. Statistical analysis of the correlation coefficients between herbage and sheep were significantly different for most of the minerals but not for P, Cu, and Se. Many correlation regression coefficients were found significantly different among minerals of herbage, soil, and sheep serum especially those of K, Na, Fe, Mn, and Zn (between herbage and sheep serum), and Fe and Mn (between herbage and soil), Na, Fe, Mn, and Zn (between soil and sheep serum), respectively. The regression coefficient equations derived under this experiment for prediction of Ca (R2 = 0.618), K (R2 = 0.803), Mg (R2 = 0.767), Na (R2 = 0.670), Fe (R2 = 0.865),Zn (R2 = 0.950), Mn (R2 = 0.936), and Se (R2 = 0.630), resulted in significant R2 values. Conclusion: It is inferred that the winter herbage minerals in all the districts were below the recommended levels for macro minerals which indicated there would be some mineral deficiencies in sheep grazing the herbage in these regions. Supplemental minerals may therefore play an important role in balancing the minerals available from the herbage in winter and would lead to increased productivity in sheep on the highland areas of China. These findings could be potentially applied to the other regions for improving the livestock productivity.

Cloning and Characterization of a Novel Mannanase from Paenibacillus sp. BME-14

  • Fu, Xiaoyu;Huang, Xiaoluo;Liu, Pengfu;Lin, Ling;Wu, Gaobing;Li, Chanjuan;Feng, Chunfang;Hong, Yuzhi
    • Journal of Microbiology and Biotechnology
    • /
    • v.20 no.3
    • /
    • pp.518-524
    • /
    • 2010
  • A mannanase gene (man26B) was obtained from a sea bacterium, Paenibacillus sp. BME-14, through the constructed genomic library and inverse PCR. The gene of man26B had an open reading frame of 1,428 bp that encoded a peptide of 475- amino acid residues with a calculated molecular mass of 53 kDa. Man26B possessed two domains, a carbohydrate binding module (CBM) belonging to family 6 and a family 26 catalytic domain (CD) of glycosyl hydrolases, which showed the highest homology to Cel44C of P. polymyxa (60% identity). The optimum pH and temperature for enzymatic activity of Man26B were 4.5 and $60^{\circ}C$, respectively. The activity of Man26B was not affected by $Mg^{2+}$ and $Co^{2+}$, but was inhibited by $Hg^{2+},\;Ca^{2+},\;Cu^{2+},\;Mn^{2+},\;K^+,\;Na^+$, and $\beta$-mercaptoethanol, and slightly enhanced by $Pb^{2+}$ and $Zn^{2+}$. EDTA did not affect the activity of Man26B, which indicates that it does not require divalent ions to function. Man26B showed a high specific activity for LBG and konjac glucomannan, with $K_m,\;V_{max}$, and $k_{cat}$ values of 3.80 mg/ml, 91.70 ${\mu}mol$/min/mg protein, and 77.08/s, respectively, being observed when LBG was the substrate. Furthermore, deletion of the CBM6 domain increased the enzyme stability while enabling it to retain 80% and 60% of its initial activity after treatment at $80^{\circ}C$ and $90^{\circ}C$ for 30 min, respectively. This finding will be useful in industrial applications of Man26B, because of the harsh circumstances associated with such processes.

Preparation of Freeze-dried Instant Spiced Toha-jeot (FIST) (동결.건조한 즉석토하젓의 제조)

  • 박복희;오봉윤
    • Food Science and Preservation
    • /
    • v.8 no.4
    • /
    • pp.419-426
    • /
    • 2001
  • This study was carried out to develope a convenient instant spiced Toha-jeot. Toha-jeot was manufactured by five samples; 8%, 10%, 13% 23% sodium chloride and a conventional type soy sauce. The Toha-jeot was refrigerated at 4$\pm$1$\^{C}$ for 3 months and then boiled glutinous rice, red pepper powder, chopped garlic and ginger were added, and the spiced Toha-jeot was fermented at 4$\pm$1$\^{C}$ for 2 months, was freeze-dried at a condition of 40$\^{C}$, vacuum 100∼200 millitor millitorr and then packed in vacuum. It is called freeze-dried instant spiced Toha-jeot (FIST). Changes in the components and quality of refrigerated spiced Toha-jeot (RST) and FIST were investigated for 30day. The moisture content of RST was 53.79∼58.91%. Among the mineral constituents of RST, Na and Ca were dominantly occupying. Water activity of FIST was 0.28-0.39 while that of RST was 0.87-0.92. TBA value of FIST was lower than that of RST. Acidity, VBN (volatile basic nitrogen) and TBA(thiobarbituric acid) of the FIST and RST increased slightly, whereas pH decreased. The major components of fatty acids in FIST and RST were analysed into a feater amount of linoleic acid (Cl8:2), palmitic acid (Cl6:1), oleic acid (Cl8:1), linolenic acid (Cl8:3), EPA (C2O:5) and stearic acid(Cl8:0). In sensory evaluation, the RST had higher scores in color and taste and the FIST in chewiness and flavor. The qualitative characteristics and sensory evaluation of FIST and RST were similar.

  • PDF

Component Analysis and Antioxidant Activity of Oenanthe javanica Extracts (돌미나리 추출물의 함유성분 분석과 항산화 활성)

  • Hwang, Seok-Jun;Park, Sung-Jin;Kim, Jong-Dai
    • Korean Journal of Food Science and Technology
    • /
    • v.45 no.2
    • /
    • pp.227-234
    • /
    • 2013
  • The purpose of this study was to determine the possibility of using Oenanthe javanica as a natural health food source. To accomplish this, its general and biological activities were measured. Its carbohydrate, crude protein, crude lipid, and ash contents were 44.7, 9.8, 8.9, and 27.8%, respectively. The K content was largest for minerals followed by Ca, P, and Mg, which means that Oenanthe javanica is an alkali material. The concentrations of total phenol and flavonoids of OJE were $88.9{\pm}0.46$ mg GAE/g, and $28.6{\pm}0.64$ mg QE/g, respectively. Gallic acid, catechin, chlorogenic acid, and caffeic acid in OJE as measured by using HPLC were $0.9{\pm}0.23$, $1.2{\pm}0.19$, $227.1{\pm}0.62$, and $4.0{\pm}0.35$ mg/g. The DPPH and ABTS radical scavenging activities of OJE were 72.2%, and 66.1%, respectively, at $1,000{\mu}g/mL$. The FRAP and reducing power of OJE were 0.79, and 0.41 absorbance units value respectively, at $1,000{\mu}g/mL$. OJE possessed significant antioxidant properties, which suggests its great potential as a functional ingredient for food applications.

Characteristics of the Number and the Mass Concentrations and the Elemental Compositions of PM10 in Jeju Area (제주지역 PM10의 수농도 및 질량농도와 원소성분 조성 특성)

  • Kang, Chang-Hee;Hu, Chul-Goo
    • Journal of Environmental Science International
    • /
    • v.23 no.3
    • /
    • pp.447-457
    • /
    • 2014
  • The number concentrations, the mass concentrations and the elemental concentrations of $PM_{10}$ have measured at Gosan site in Jeju, Korea, from March 2010 to December 2010. And the correlation and the factor analysis for the number, the mass and the elemental concentrations of $PM_{10}$ are performed to identify their relationships and sources. The average $PM_{10}$ number concentration is observed $246\;particles/cm^3$($35.7{\sim}1,017\;particles/cm^3$) and the average $PM_{10}$ mass concentration is shown $50.1{\mu}g/m^3$($16.7{\sim}441.4{\mu}g/m^3$) during this experimental period. The number concentrations are significantly decreased with increasing particle size, hence the concentrations for the smaller particles less than $2.5{\mu}m$($PM_{2.5}$) are contributed 99.6% to the total $PM_{10}$ number concentrations. The highest concentration of the 20 elements in $PM_{10}$ determined in this study is shown by S with a mean value of $1,497ng/m^3$ and the lowest concentration of them is found by Cd with a mean value of $0.57ng/m^3$. The elements in $PM_{10}$ are evidently classified into two group based on their concentrations: In group 1, including S>Na>Al>Fe>Ca>Mg>K, the elemental mean concentrations are higher than several hundred $ng/m^3$, on the other hand, the concentrations are lower than several ten $ng/m^3$ in group 2, including Zn>Mn>Ni>Ti>Cr>Co>Cu>Mo>Sr>Ba>V>Cd. The size-separated number concentrations are shown positively correlated with the mass concentrations in overall size ranges, although their correlation coefficients, which are monotonously increased or decreased with size range, are not high. The concentrations of the elements in group 1 are shown highly correlated with the mass concentrations, but the concentrations in group 2 are shown hardly correlated with the mass concentrations. The elements originated from natural sources have been predominantly related to the mass concentrations while the elements from anthropogenic sources have mainly affected on the number concentrations of $PM_{10}$.