• 제목/요약/키워드: Cu-Pc (copper-phthalocyanine)

검색결과 94건 처리시간 0.03초

CuPC PET의 기판온도에 따른 전기적 특성 연구 (Electrical Properties of CuPC FET with Varying Substrate Temperature)

  • 이호식;천민우;박용필
    • 한국정보통신학회논문지
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    • 제13권1호
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    • pp.110-114
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    • 2009
  • 최근에 유기물 전계효과 트랜지스터의 연구는 전자소자분야에서 널리 알려져 있다. 특히 본 연구에서는CuPc 물질을 기본으로 하여 소자를 제작하고, 또한 기판의 온도를 달리 하여 제작하였다. CuPc FET 소자는 top-contact 방식으로 제작하였으며, 기판의 온도는 상온과 $150^{\circ}C$로 달리 하였다. 또한 CuPc의 두께는 40nm로 하였고, 채널의 길이는 $50{\mu}m$, 폭은 3mm로 하였다. 제작된 소자를 이용하여 전압-전류 특성을 측정하였다.

A True Cholesteric Columnar Liquid Crystal

  • Cho, I-Whan;Lim, Young-Soo
    • Bulletin of the Korean Chemical Society
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    • 제9권2호
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    • pp.98-101
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    • 1988
  • A pure columnar cholesterogen based on the octasubstituted phthalocyanine $(PcH_2)$, S-(+)-2, 3, 9, 10, 16, 17, 23, 24-octakis[5-(dodecyloxy)-2-oxa-pentyl]-phthalocy anine(1a), is described. To evaluate a cholesteric character of 1a, the corresponding achiral $PcH_2$ 1b and the copper complex of chiral $PcH_2$ 1a (CuPc), S-(+)-2,3,9,10,16,17,23,24-octakis[4-(dodecyloxy)- 2-oxapentyl]-phthalocyanine(2a) were also prepared. The chiral 1a exhibited a typical cholesteric texture change in which the transition of platelet (blue phase) to fan-shape texture was observed (K-M-I), whereas the corresponding achiral 1b showed only a focal conic texture (K- M-I). This is the first instance of a pure columnar cholesterogen observed with discotic liquid crystal systems.

도너층 CuPc의 두께변화에 따른 광기전력 효율 특성

  • 김원종;최현민;최광진;김태완;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 추계학술대회 논문집
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    • pp.280-280
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    • 2009
  • In a structure of ITO/CuPc/Al, we have studied that the properties of photovoltaic efficiency of copper phthalocyanine(CuPc) in donor layer using simulation. As a rusult, we have confirmed that anode current density is decreased and anode voltage is increased as increasing the thickness of CuPc. Also, when the light intensities is 10 [$mW/cm^2$], the external quantum efficiency is better than the others at the best wavelength of visible spectrum..

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Efficient Organic Light-Emitting Diodes with a use of Hole-injection Buffer Layer

  • Kim, Sang-Keol;Chung, Dong-Hoe;Chung, Taek-Gyun;Kim, Tae-Wan
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.766-769
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    • 2002
  • We have seen the effects of hole-injection buffer layer in organic light-emitting diodes using copper phthalocyanine(CuPc), poly(vinylcarbazole)(PVK), and Poly(3,4-ethylenedioxythiophene):poly(styrene-sulfonate)(PEDOT:PSS) in a device structure of ITO/buffer/TPD/$Alq_3$/Al. Polymer PVK and PEDOT:PSS buffer layer was made using spin casting method and the CuPc layer was made using thermal evaporation. Current-voltage characteristics, luminance-voltage characteristics and efficiency of device were measured at room temperature with a thickness variation of buffer layer. We have obtained an improvement of the external quantum efficiency by a factor of two, four, and two and half when the CuPc, PVK, and PEDOT:PSS buffer layer are used, respectively. The enhancement of the efficiency is attributed to the improved balance of holes and elelctrons due to the use of hole-injection buffer layer. The CuPc and PEDOT:PSS layer functions as a hole-injection supporter and the PVK layer as a hole-blocking one.

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Carrier Gas Assisted Solvent Vapor Treatment for Surface Nanostructuring of Molecular Thin Films

  • Gong, Hye-Jin;Kim, Jin-Hyun;Yim, Sang-Gyu
    • Bulletin of the Korean Chemical Society
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    • 제33권3호
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    • pp.825-827
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    • 2012
  • In this study, the variation in surface morphology of copper phthalocyanine (CuPc) thin films treated with a flow of acetone vapor assisted by nitrogen carrier gas was investigated. The CuPc nanorods with similar dimensions were well dispersed throughout the whole film surfaces after ~20 min. of treatment. However, the electronic absorption spectra only changed slightly, which indicates that molecular stacking was not altered during treatment. This treating method is simple and more advantageous compared to other solvent treating technologies such as mixed solvent spray treatment using organic solvents and water since it requires relatively mild treating conditions and does not need the presence of water.

Photocurrent에 의한 유기발광소자의 발광효율특성 연구 (Photocurrent multiplication process in OLEDs)

  • 임은주;한우미;이정윤;차덕준;이용산;이기진
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 디스플레이 광소자 분야
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    • pp.77-80
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    • 2002
  • In order to enhence the photocurrent multiplication process, we controlled the irradiation light and the material of cathode layer of organic light emitting diodes (OLEDs). The structures of OLEDs were indium tin oxaide (ITO)/ copper(II) phthalocyanine (CuPc)/triphenyl-diamine (TPD)/ tris-(8-hydroxyquinoline)aluminum (Alq3)/ aluminum (Al). We found that OLEDs were changed by the photocurrent and free charge carrier multiplication process due to the irradiation of light. The rate of photocurrent was increased by the irradiation of red and blue light.

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유기 전계발광소자의 제작과 특성 연구 (Preparation and Properties of Organic Electroluminescent Devices)

  • 노준서;장호정
    • 마이크로전자및패키징학회지
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    • 제9권1호
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    • pp.9-13
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    • 2002
  • 최근, 효율적인 다층박막 구조로된 풀칼라 유기 전계발광소자 (organic electroluminescient device, OELD)의 시제품이 개발된바 있다. 본 연구에서는 ITO (indium tin oxide)/glass 투명기판위에 다층구조의 OELD 소자를 진공 열증착법으로 제작하였다. 사용된 저분자 유기화합물은 전자수송 및 주입층으로 $Alq_3$(trim-(8-hydroxyquinoline)aluminum)와 CTM (carrier transfer material) 물질을 사용하였고, 정공수송 덴 주입층으로는 TPD (triphenyl-diamine)와 CuPc (copper phthalocyanine)를 각각 증착하였다. 발광휘도는 임계전압 10 V 이상에서 급격히 증가하였으며, $A1/CTM/Alq_3$/TPD/1TO 구조로된 OELDs 소자의 경우- l7 V전압에서 430 cd/$m^2$의 휘도특성과 파장 512 nm의 녹색 발광을 나타내었다. 한편 $Li-A1/Alq_3$/TPD/CuPC/1TO 다층구조로된 소자의 발광파장은 508 nm 이며, 발광휘도는 17 V에서 650 cd/$m^2$의 값을 얻을 수 있었다. Li-Al 전극을 갖는 다층구조에서 발광휘도의 증가는 정공주입층인 CuPc의 적층으로 발광층에서 재결합 효율이 개선되었기 때문이며, 또한 Li-Al 전극의 경우 Al전극에 비해 낮은 일함수(work function)를 갖기 때문으로 판단된다.

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INVESTIGATIONS OF CONDUCTION MECHANISM OF ORGANIC MOLECULES USED AS BUFFER HOLE INJECTING LAYER IN OLEDS

  • Shekar, B. Chandar;Rhee, Shi-Woo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.966-969
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    • 2003
  • Thin film capacitors with Al-Polymer-Al sandwich structure were fabricated. The bottom and top aluminium (Al) electrodes were deposited by vacuum evaporation and copper phthalocyanine (CuPc), polyaniline-emeraldine base (Pani-EB) and cobalt phthalocyanine/polyaniline - emeraldine base (CoPc /Pani-EB) blend films (which can be used as buffer hole injection layer in OLEDs) were deposited by spin coating technique. X-ray diffractograms indicated amorphous nature of the polymer films whose thicknesses were measured by capacitance and Rutherford Backscattering Spectrometry (RBS) methods. AC conduction studies revealed that the conduction mechanism responsible in these films is variable range hopping of polarons. From D.C conduction studies, it is observed that, the nature of conduction is ohmic in the lower fields and at higher fields the dominating D.C conduction is of Poole-Frenkel type.

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Efficient Organic Light-emitting Diodes using Hole-injection Buffer Layer

  • Chung, Dong-Hoe;Kim, Sang-Keol;Lee, Joon-Yng;Hong, Jin-Woong;Cho, Hyun-Nam;Kim, Young-Sik;Kim, Tae-Wan
    • Journal of Information Display
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    • 제4권1호
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    • pp.29-33
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    • 2003
  • We have investigated the effects of hole-injection buffer layer in organic light-emitting diodes using copper phthalocyanine (CuPc), poly(vinylcarbazole)(PVK), and Poly(3,4-ethylene dioxythiophene):poly(styrenesulfonate) (PEDOT: PSS) in a device structure of $ITO/bufferr/TPD/Alq_3/Al$. Polymer PVK and PEDOT:PSS buffer layer were produced using the spin casting method where as the CuPc layer was produced using thermal evaporation. Current-voltage characteristics, luminance-voltage characteristics and efficiency of device were measured at room temperature at various a thickness of the buffer layer. We observed an improvement in the external quantum efficiency by a factor of two, four, and two and half when the CuPc, PVK, and PEDOT:PSS buffer layer were used, respectively. The enhancement of the efficiency is assumed to be attributed to the improved balance of holes and elelctrons resulting from the use of hole-injection buffer layer. The CuPc and PEDOT:PSS layer function as a hole-injection supporter and the PVK layer as a hole-blocking one.