• Title/Summary/Keyword: Cu-Fe

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Performances of Metallic (sole, composite) and Non-Metallic Anodes to Harness Power in Sediment Microbial Fuel Cells

  • Haque, Niamul;Cho, Daechul;Kwon, Sunghyun
    • Environmental Engineering Research
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    • v.19 no.4
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    • pp.363-367
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    • 2014
  • One chambered sediment microbial fuel cell (SMFC) was equipped with Fe, brass (Cu/Zn), Fe/Zn, Cu, Cu/carbon cloth and graphite felt anode. Graphite felt was used as common cathode. The SMFC was membrane-less and mediator-less as well. Order of anodic performance on the basis of power density was Fe/Zn ($6.90Wm^{-2}$) > Fe ($6.03Wm^{-2}$) > Cu/carbon cloth ($2.13Wm^{-2}$) > Cu ($1.13Wm^{-2}$) > brass ($Cu/Zn=0.24Wm^{-2}$) > graphite felt ($0.10Wm^{-2}$). Fe/Zn composite anode have twisted 6.73% more power than Fe alone, Cu/carbon cloth boosted power production by 65%, and brass (Cu/Zn) produced 65% less power than Cu alone. Graphite felt have shown the lowest electricity generation because of its poor galvanic potential. The estuarine sediment served as supplier of oxidants or electron producing microbial flora, which evoked electrons via a complicated direct microbial electron transfer mechanism or making biofilm, respectively. Oxidation reduction was kept to be stationary over time except at the very initial period (mostly for sediment positioning) at anodes. Based on these findings, cost effective and efficient anodic material can be suggested for better SMFC configurations and stimulate towards practical value and application.

Treatment of Wastewater Containing Cu(II)-EDTA Using Ferrate in Sequencing Batch Scale System (연속회분식 반응 장치에서 Ferrate를 이용한 Cu(II)-EDTA 함유 폐수 처리 연구)

  • Kim, Hyoung-Uk;Kim, Byeong-Kwon;Lee, Seung-Mok;Yang, Jae-Kyu;Kim, Hyun-Ook;Kwan, Jung-An;Im, Hang-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.7
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    • pp.729-734
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    • 2008
  • The higher valence state of iron i.e., Fe(VI) was employed for the treatment of Cu(II)-EDTA in the aqueous/waste waters. The ferrate(VI) was prepared through wet oxidation of Fe(III) by sodium hypochlorite. The purity of prepared Fe(VI) was above 93%. The stability of Fe(VI) solution decreased as solution pH decreased through self decomposition. The reduction of Fe(VI) was obtained by using the UV-Visible measurements. The dissociation of Cu(II)-EDTA complex through oxidation of EDTA using Fe(VI) and subsequent treatment of organic matter and metal ions by Fe(III) reduced from Fe(VI) in bench-scale of continuous flow reactor were studied. The removal efficiencies of copper were 69% and 79% in pH control basin and reactor, respectively, at 120 minutes as retention time. In addition, Cu(II)-EDTA in the reactor was decomplexated more than 80% after 120 minutes as retention time. From this work, a continuous treatment process for the wastewater containing metal and EDTA by employing Fe(VI) as muluti-functional agent was developed.

Soft Magnetic Property Depending on thickness of Free Layer in CoFe/Cu/CoFe/IrMn Spin Valve Film (CoFe/Cu/CoFe/IrMn 스핀밸브 박막의 자유층 두께 감소에 따른 연자성 자기저항 특성 연구)

  • Choi, Jong-Gu;Go, In-Suk;Gong, Yu-Mi;Kim, Min-Ho;Park, Young-Suk;Hwang, Do-Guwn;Lee, Sang-Suk
    • Journal of the Korean Magnetics Society
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    • v.19 no.2
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    • pp.52-56
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    • 2009
  • Interlayer coupling field, coercivity, magnetoresitance ratio, and magnetic sensitivity depending on the thickness of free CoFe layer for the CoFe/Cu/CoFe/IrMn multilayer are investigated. In case of CoFe layer of $30\;{\AA}$ thickness for the CoFe(t)/Cu($25\;{\AA}$)/CoFe($60\;{\AA}$)/IrMn($80\;{\AA}$) multilayer with ferromagnet/non-magnet/ferromagnet structure induced by IrMn layer, the lowest coercivity and the highest magnetic sensitivity, which is contained soft magnetic property, are observed. On the other side, in case of CoFe layer of $90\;{\AA}$ thickness, there are the highest coercivity and the lowest magnetic sensitivity. The fabricated CoFe($30\;{\AA}$)/Cu($25\;{\AA}$)/CoFe($60\;{\AA}$)]/IrMn($80\;{\AA}$) spin valve device with $2{\times}8{\mu}m^2$ patterning size are measured by two probe method, which is selected the sensing current as the longitudinal direction and the easy axis as the transversal direction. The measuring magntoresistance ratio and magnetic sensitivity of GMR-SV device having the soft magnetic property are 3.0% and 0.3%/Oe, respectively.

Magnetism of Fe Monolayers on Nonmagnetic fcc Transition Metal (Cu, Rh, Pd, and Ag) (001) Surfaces (면심입방 금속(Cu, Rh, Pd, Ag) (001) 표면 위의 철 단층의 자성)

  • Yun, Won-Seok;Cha, Gi-Beom;Rho, Tae-Hwan;Han, Dong-Ho;Hong, Soon-Cheol
    • Journal of the Korean Magnetics Society
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    • v.19 no.5
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    • pp.165-170
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    • 2009
  • It is well-known that a meta-stable fcc bulk Fe has an antiferromagnetic (AFM) ground state and could be synthesized by growing Fe on a proper fcc metal substrate. In this study magnetism of Fe monolayers on nonmagnetic fcc transition metal (Cu, Rh, Pd, and Ag) (001) surfaces has been investigated using the all-electron full-potential linearized augmented plane wave method. The Fe monolayers on Rh(001) and Pd(001) surfaces were calculated to be stabilized in an AFM state, whereas the Fe monlayers on Cu(001) and Ag(001) surfaces are stabilized in a ferromagnetic (FM) state. Noting that Cu and Ag have the smallest and largest lattice constants and the fcc bulk Fe with a larger lattice constant is getting stabilized in a ferromagnetic state, it is unexpectable and interesting. The calculated magnetic moments of the Fe atoms on Cu, Rh, Pd, and Ag(001) surfaces are 2.811, 2.945, 2.987, and 2.990 $_{{\mu}B}$ in FM states and 2.624, 2.879, 2.922, and 3.001 $_{{\mu}B}$ in AFM states.

Performance of Nanosized Fe3O4 and CuO Supported on Graphene as Anode Materials for Lithium Ion Batteries (그래핀에 담지된 Fe3O4와 CuO 나노입자의 리튬이차전지 음극성능)

  • Jeong, Jae-Hun;Jung, Dong-Won;Han, Sang-Wook;Kim, Kwang-Hyun;Oh, Eun-Suok
    • Journal of the Korean Electrochemical Society
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    • v.14 no.4
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    • pp.239-244
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    • 2011
  • In this study, $Fe_3O_4$/graphene and CuO/graphene composites were synthesized by the polyol reduction method using ethylene glycol, and their performances as the anodes of lithium ion batteries were evaluated. The physical characteristics of the synthesized composites were analyzed by SEM, XRD, and TGA. In addition, their electrochemical properties were examined by the electrochemical analysis techniques such as charge/discharge performance, cyclic voltammetry, and AC impedance spectroscopy. The cells composed of $Fe_3O_4$/graphene and CuO/graphene composites showed better performance than the graphene electrode, due to the dispersion of nanosized $Fe_3O_4$ or CuO on the surface of graphene and the formation of good electrical network in the electrode. Their composites kept the reversible capacity more than 600 mAh/g even after the charging/discharging of 30 cycles.

Glass Formation and Ion Dissolution of P2O5-K2O-FeO-CuO Glasses (P2O5-K2O-FeO-CuO계 유리형성 및 이온용출)

  • Kang, Won-Ho;Kim, Ki-Min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.2
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    • pp.604-607
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    • 2010
  • The glass formation and the dissolution property in $P_2O_5-K_2O$-FeO-CuO system were studied. In the batch process, the content of P2O5 was fixed at 60mol% and the other elements were varied from 10~40mol%. The prepared glasses were soaked in the D.I. water up to 13hr and the dissolution properties were investigated with the solutions sampled every 2 hr. The result shows that the $P_2O_5$ was leached out firstly from Phosphate glass system and then Cu and Fe ions were observed according to atmosphere change in solution. ICP shows that the dissolution amount in Phosphate was depended on the glass structure and the highest dissolution amount of CuO and FeO ions was observed when the 10mol% $K_2O$ was added in batch process.

Fabrication of Nanostructured $5Cu_{0.6}Fe_{0.4}-Al_2O_3$ Composite by Pulsed Current Activated Sintering from Mechanically Synthesized Powder (기계적으로 합성한 분말로부터 펄스전류 활성 소결에 의한 나노구조 $5Cu_{0.6}Fe_{0.4}-Al_2O_3$ 복합재료제조)

  • Park, Na-Ra;Song, Jun-Young;Nam, Kee-Seok;Shon, In-Jin
    • Journal of the Korean Society for Heat Treatment
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    • v.22 no.3
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    • pp.149-154
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    • 2009
  • Dense $5Cu_{0.6}Fe_{0.4}-Al_2O_3$ composite was consolidated from mechanically synthesized powders by pulsed current activated sintering method within 1 min. $5Cu_{0.6}Fe_{0.4}-Al_2O_3$ powder was synthesized from 3CuO and 2FeAI using the high energy ball milling. Dense $5Cu_{0.6}Fe_{0.4}-Al_2O_3$ with relative density of up to 95% was produced under simultaneous application of a 80 MPa pressure and the pulsed current. Mechanical properties and grain size of the composite were investigated.

Effect of Silicon Content over Fe-Cu-Si/C Based Composite Anode for Lithium Ion Battery

  • Doh, Chil-Hoon;Shin, Hye-Min;Kim, Dong-Hun;Chung, Young-Dong;Moon, Seong-In;Jin, Bong-Soo;Kim, Hyun-Soo;Kim, Ki-Won;Oh, Dae-Hee;Veluchamy, Angathevar
    • Bulletin of the Korean Chemical Society
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    • v.29 no.2
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    • pp.309-312
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    • 2008
  • Two different anode composite materials comprising of Fe, Cu and Si prepared using high energy ball milling (HEBM) were explored for their capacity and cycling behaviors. Prepared powder composites in the ratio Cu:Fe:Si = 1:1:2.5 and 1:1:3.5 were characterized through X-Ray diffraction (XRD) and scanning electron microscope (SEM). Nevertheless, the XRD shows absence of any new alloy/compound formation upon ball milling, the elements present in Cu(1)Fe(1)Si(2.5)/Graphite composite along with insito generated Li2O demonstrate a superior anodic behavior and delivers a reversible capacity of 340 mAh/g with a high coulombic efficiency (98%). The higher silicon content Cu(1)Fe(1)Si(3.5) along with graphite could not sustain capacity with cycling possibly due to ineffective buffer action of the anode constituents.

Variations of The Heavy Metal Contents in Human Hairs According to of Hair Coloring Manipulation (모발(毛髮)의 염색처리(染色處理)에 따른 중금속(重金屬) 함량(含量)의 변화(變化))

  • Joung, Yeon;Sung, Su-Kwang
    • Journal of Fashion Business
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    • v.4 no.1
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    • pp.25-32
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    • 2000
  • The purpose of this study was to suggest the knowlege and scientific information of the damage according to the heavy metal exposure level of hair coloring manipulations. The study was investigated variations of the heavy metal contents(Pb, Zn, Cu, Mn, Fe, Ni) in hairdye and human hairs by 1 and 2 times of hair coloring manipulations. The results were as follows; 1. Mean heavy metal contents in colorant of hairdye were 0.250ppm(Pb), 33.650ppm(Zn), 0.800ppm(Cu), 0.675ppm(Mn), 31.050ppm(Fe), 1.700ppm(Ni). In oxidant of hairdye, It were 0.225ppm(Pb), 35.450ppm(Zn), 0.575ppm(Cu), 0.075ppm(Mn), 16.600ppm(Fe), 1.500ppm(Ni). 2. Mean heavy metal contents were 2.950ppm(Pb), 29.000ppm(Zn), 9.400ppm(Cu), 1.075ppm(Mn), 40.775ppm(Fe), 1.950ppm(Ni) in virgin hairs, 3.025ppm(Pb), 40.250ppm(Zn), 9.650ppm(Cu), 1.350ppm(Mn), 42.900ppm(Fe), 2.200ppm(Ni) in 1 time of coloring hairs, 3.350ppm(Pb), 51.650ppm(Zn), 10.950ppm(Cu), 1.475ppm(Mn), 44.350ppm(Fe), 2.225ppm(Ni) in 2 times of coloring hairs.

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Enhanced Giant Magnetoelectric Effect in Laminate Composites of FeCuNbSiB/FeNi/PZT

  • Wen, Yumei;Wang, Dong;Li, Ping
    • Journal of Magnetics
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    • v.16 no.4
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    • pp.398-402
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    • 2011
  • A novel laminate composite of FeCuNbSiB/FeNi /PZT is proposed, where FeCuNbSiB has a permeability of around 100000, which is much larger than that of FeNi. The high-permeability FeCuNbSiB was laminated with piezomagnetic FeNi rather than attached to its ends. It is expected that the effect produced by the high permeability will act on the whole of the piezomagnetic layer. While a FeNi layer was laminated with a FeCuNbSiB layer, the strong demagnetization produced by the latter was expected to be imposed on the FeNi layer as well as the applied fields. The distribution of applied fields was altered by the high-permeability material (both bias and ac field) and the field variation positively contributed to the ME effect in piezomagnetic/piezoelectric composites. Thus the ME voltage coefficient along with the field sensitivity were improved.