• Title/Summary/Keyword: Cu alloys

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Microstructure and Mechanical Properties of Solution Treatment and Sr-Modification of Al-12%Si-1.5%Cu Alloy

  • Surin, Prayoon;Wong on, Jessada;Eidhed, Krittee
    • International Journal of Advanced Culture Technology
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    • v.3 no.2
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    • pp.132-137
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    • 2015
  • The purpose of this paper was to investigate the effects of solution treatment time and Sr-modification on the microstructure and property of the Al-Si piston alloy. It was found that as-cast microstructures of unmodified and Sr-modified Al-Si alloys consisted of a coarse acicular plate of eutectic Si, $Cu_3NiAl_6$ and $Mg_2Si$ phases in the ${\alpha}$-Al matrix but different in size and morphology. Both size and inter-particle spacing of Si particles were significantly changed by increasing of the solution treatment time. After a short solution treatment, the coarse acicular plate of the eutectic Si appears to be fragmented. Fully modified microstructure of Sr-modified alloy can reduce the solution treatment time to shorter compared to unmodified alloy. The maximum of a peak hardness value is found in the very short solution treatment of both Al-Si piston alloys. Compared to 10 h solution treatment, the solution treatment of 2-4 h is sufficient to achieve appropriate microstructures and hardness. The short solution treatment is very useful to increase the productivity and to reduce the manufacturing cost of the Al-Si piston alloys.

Synthesis of Si alloys as the negative electrode material for lithium ion battery (고용량 리튬이온 전지용 음극 활물질로서 실리콘 합금 제조)

  • Lee, Heon-Young;Jang, Serk-Won;Lee, Sung-Man
    • Journal of Industrial Technology
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    • v.21 no.B
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    • pp.31-35
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    • 2001
  • The phase forming ability and formation enthalpies(${\Delta}H$) of Si-M(M = Ti, Cu, Ni, Zr) compound alloys were predicted by Miedema's model. The silicon compound alloys were synthesized by mechanical alloying and then characterized for the phase formation by X -ray diffraction. The electrochemical properties as the anode materials for lithium ion batteries were investigated using a galvanostatic method. It appears that the electrochemical characteristics of Si-M alloys can be predicted from the thermodynamic criteria for the phase formation using the Miedema's model.

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Variability in mechanical properties and microstructure characterization of CuAlBe shape memory alloys for vibration mitigation

  • Casciati, Fabio;van der Eijk, Casper
    • Smart Structures and Systems
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    • v.4 no.2
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    • pp.103-121
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    • 2008
  • Shape memory alloys (SMA) have been emphasized, studied and understood in the controlled world of the laboratory. Any attempt to implement one of these alloys in engineered products requires a jump from the controlled world of the laboratory to the actual environment of the application. The first step is to move from single grain specimens to multigrain samples. One works with a material for which any stock is different from that previously available. This paper reviews the milestones in the familiarization process the authors had to overcome during their cooperation within a project funded by the European Union. The main items cover transformation temperatures, thermal treatment and properties understanding.

Ni added Si-Al Alloys with Enhanced Li+ Storage Performance for Lithium-Ion Batteries

  • Umirov, Nurzhan;Seo, Deok-Ho;Jung, Kyu-Nam;Kim, Hyang-Yeon;Kim, Sung-Soo
    • Journal of Electrochemical Science and Technology
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    • v.10 no.1
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    • pp.82-88
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    • 2019
  • Here, we report on nanocrystalline Si-Al-M (M = Fe, Cu, Ni, Zr) alloys for use as an anode for lithium-ion batteries, which were fabricated via a melt-spinning method. Based on the XRD and TEM analyses, it was found that the Si-Al-M alloys consist of nanocrystalline Si grains surrounded by an amorphous matrix phase. Among the Si-Al-M alloys with different metal composition, Ni-incorporated Si-Al-M alloy electrode retained the high discharge capacity of 2492 mAh/g and exhibited improved cyclability. The superior $Li^+$ storage performance of Si-Al-M alloy with Ni component is mainly responsible for the incorporated Ni, which induces the formation of ductile and conductive inactive matrix with crystalline Al phase, in addition to the grain size reduction of active Si phase.

Plasticity of Amorphous Alloys: 2. Inhomogeneous Deformation (비정질 합금의 소성 2: 불균일변형)

  • Park, Kyoung-Won;Lee, Chang-Myeon;Lee, Jae-Chul
    • Korean Journal of Metals and Materials
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    • v.47 no.11
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    • pp.773-785
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    • 2009
  • Studies of a number of Cu-Zr amorphous alloys have demonstrated that those exhibiting greater plastic strain during homogeneous deformation at room temperature show lower global plasticity associated with inhomogeneous deformation in a typical compression test. Using a combination of experiments and molecular dynamics simulations, we clarify this seeming paradox between the homogeneous and inhomogeneous deformation by exploring the microstructural aspects in view of the structural disordering, disorder-induced softening, and shear localization and relate these findings to the global plasticity of bulk amorphous alloys. Additional analyses were conducted to derive a simple structural parameter that allows the prediction of the global plasticity of bulk amorphous alloys.

A Study on the Nano-Deformation Characteristics of Grain-Size Controlled Rheology Material Surfaces for Surface Crack Prediction (표면크랙 예측을 위한 결정립 제어 레오로지 소재 표면의 나노 변형특성에 관한 연구)

  • 윤성원;김현일;강충길
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.355-358
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    • 2004
  • In this study, the deformation characteristics of grain-size controlled rheology materials surfaces were investigated as a part of the research on the surface crack prediction in semi-solid formed automobile components. The microstructure of rheology Al-Si alloys consists of primary and eutectic regions. In eutectic regions the crack initiation begins with initial fracture of the eutectic silicon particles and inside other intermetallic phases. Nano-deformation characteristics in the eutectic and primary region of semi-solid aluminum alloys (356 alloy and 319 alloy) were investigated through the nanoindentation/scratch experiments and the AFM observation.

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The factors of dimensional change of Fe-Cu-C sintered objects

  • Fujinaga, Masashi;Suzuki, Yoshitomo
    • Journal of Powder Materials
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    • v.5 no.4
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    • pp.299-302
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    • 1998
  • Dimensional accuracy is one of the most important issues in the production of sintered parts. The iron-copper-carbon system is commonly used alloys in sintered structural parts production. The dimensional control of these alloys, however, is not easy because of their complex sintering behavior. This study is an effort to clarify the influence of common factors on dimensional change of Fe-Cu-C sintered structural parts. We determined the effect of such various parameters as chemical composition, particle diameter, compact density, sintering temperature and sintering time on dimensional changes. Consequently, we obtained a useful formula to predict the final dimension in function of these parameters. The effect of typical impurities in copper powder on the dimensional change of sintered parts has also been described.

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POSSIBILITY OF PARTIAL MELTING SOLDERING PROCESS WITH OFF EUTECTIC LEAD FREE SOLDER ALLOYS

  • Kang, Choon-Sik;Ha, Jun-Seok;Park, Jae-Yong;Jung, Jae-Pil
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.791-797
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    • 2002
  • This paper introduces the partial melting process for solder application and characterization of its feasibility using Sn-Ag, and Sn-Cu solder alloys. ill order to show that the liquid phase in the semi-liquid state maintains the similar wettability as single-phase liquid, the wetting balance tests are conducted with varying temperatures and compositions. Also, as a new soldering technology, the microstructural and mechanical test were investigated. The results from this research indicate that the partial melting can yield satisfactory sider joints as long as the liquid phase acquires sufficient chemical activity. At a condition where the partial melting is effective, a direct correlation between the wettability and the surface tension is found to exist.

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Effect of Melting and Pouring Conditions on Structures of Leaded Tin Bronze Castings (연청동주물(鉛靑銅鑄物)의 조직(組織)에 미치는 용해(熔解) 및 주입조건(鑄入條件)의 영향(影響)에 관한 연구(硏究))

  • Lee, W.W.;Choi, C.O.
    • Journal of Korea Foundry Society
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    • v.7 no.1
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    • pp.45-52
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    • 1987
  • The effects of melting and casting conditions on cast structures of Cu-Sn-Pb alloys were studied. Specimens were prepared at different pouring temperatures of $1100^{\circ}C$ to $1260^{\circ}C$ with use of various kind of molds, green sand mold, $CO_2$ sand mold, shell mold, furan sand mold and metallic mold. (1) The transition of equiaxed to columnar structure greatly influenced by adding elements and mold binders. (2) The change of equiaxed structure according to pouring temperatures were expressed by separation theory. Lower pouring temperature and rapid cooling rate increase hardness and it's further increase was shown in the region of columnar structure. (3) Proper controls of pouring temperature, cooling rate and mold binder were important factors to improve wear properties of Cu-Sn-Pb alloys castings.

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The Magnetization Behavior of Amorphous Fe84-zNb7B8+xCu1 (x0, 1, 4) Alloys

  • Kim, Kyeong-Sup;Moon, Young-Mo;Lee, Jae-Bong;Yu, Seong-Cho;Lim, Woo-Young
    • Journal of Magnetics
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    • v.4 no.1
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    • pp.10-12
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    • 1999
  • We report the salient features of the magnetic properties of amorphous$ Fe_{84-x}Nb_7B_{8+x}Cu_1$ (x=0, 1, 4) alloys. The study of dc-magnetization properties and the ac-susceptibility was carried out. The temperature dependence of the magnetization follows the predictions of spin wave excitations with long wavelengths. Especially, the addition of boron modifies the magnetic properties: the spin wave stiffness increases from 56.8 to 65.7 meV$\AA$2 and Curie temperature increases from 298 K to 352 K. This result indicates a magnetic hardening of the exchange interaction by higher exchange energy. Thus, the substitution of iron by boron favours the increase of magnetic order in this system.

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